Diverse protolith ages for the Mindoro and Romblon Metamorphics (Philippines): Evidence from single zircon U–Pb dating

Within the north‐eastern part of the Palawan Continental Terrane, which forms the south‐western part of the Philippine archipelago, several metamorphic complexes are exposed that are considered to be rifted parts of the Asian margin in South‐East China. The protolith age(s) and correlations of these complexes are contentious. The largest metamorphic complex of the Palawan Continental Terrane comprises the Mindoro Metamorphics. The north‐eastern part of this metamorphic complex has recently been found to be composed of protoliths of Late Carboniferous to Late Permian protolith age. However, meta‐sediments exposed at the westernmost tip and close to the southern boundary of the exposure of the Mindoro Metamorphics contain detrital zircons and with U–Pb ages, determined by LA–ICP–MS, in the range 22–56 Ma. In addition, zircons as young as 112 Ma were found in a sample of the Romblon Metamorphics in Tablas. As the youngest detrital zircons provide an upper age limit for the time of deposition in meta‐sediments, these results suggest that the Mindoro and Romblon Metamorphics comprise protoliths of variable age: Late Carboniferous to Late Permian in NE Mindoro; Eocene or later in NW Mindoro; Miocene at the southern margin of the Mindoro metamorphics; and Cretaceous or later on Tablas. The presence of non‐metamorphic sediments of Late Eocene to Early Oligocene age in Mindoro (Lasala Formation), which are older than the youngest metasediments, suggests that metamorphism of the young meta‐sediments of Mindoro is the result of the collision of the Palawan Continental terrane with the Philippine Mobile Belt in Late Miocene. Similarities of the age spectra of zircons from the Eocene to Miocene metamorphics with the Eocene to Early Miocene Lasala Formation suggest that the protoliths of the young metamorphics may be equivalents of the Lasala Formation or were recycled from the Lasala Formation.     

Determination of Selenium in Marine Aquatic Products by Hydride Generation-atomic Fluorescence Spectrometry （HG-AFS）

A method for the analysis of selenium in marine aquatic products by HG-AFS has been investigated. The method is based on the reduction of inorganic selenium to volatile SeH2 which is bubbled out by carrier gas of pure argon, and then swept to Ar-H2 flame quarts atomizer to measure its fluorescence intensity. The hydride generation, transportation, atomization and some instrumental parameters were studied by a kind of orthogonal design. The optimum conditions selected are as follows： reactive acidity, 20% HC1; the amount of NaBH4, 4.9mL; gas flow of argon, 600mLmin^-1; atomizing temperature, 200 ℃ ; negative high voltage, - 300V; light current, 100 mA; integral time, 7s. The detection limit of the presented method is 0.072μgL^-1 for selenium. The calibration curve shows a satisfactory line inthe concentration range from 0.000 to 1.000μgL^-1 Se. The recovery is 95.8%-102.2%.     

Deep-sea submersible survey in the Suruga, Sagami and Japan Trenches: preliminary results of the 1985 Kaiko cruise, Leg 2

Nine submersible dives were made in three trenches off central Japan, between 2990 and 5900 m of water depth. Our observations confirm the interpretation that Daiichi-Kashima Seamount is a Cretaceous guyot formed on the Pacific plate that has traveled into the Japan Trench. We also confirmed the previous interpretation of a large normal fault that splits the seamount in two halves, the lower one being now subducting beneath the Japan margin. Compressional deformation was identified within the lower part of the inner slope in front of the seamount. The pattern of deformation that affects Quaternary sediments is in agreement with the present kinematics of the convergence between the Pacific plate and Japan. Deep-water (5700 m) clam colonies are associated with advection of fluids, driven by the subduction-related overpressures. In the northern slope of the Boso Canyon, along the Sagami Trough system (Philippine Sea plate-Japan boundary), the deformation affecting a thick upper Miocene to lower Pliocene sequence indicates two directions of shortening: a N175°E direction which is consistent with the present relative motion along the Sagami Trough (N285–N300°E) and a N30°E direction which could be related to a more northerly direction of convergence that occured during the early Quaternary and earlier.     

High-pressure recovery of olivine: implications for creep mechanisms and creep activation volume

High-temperature and high-pressure recovery experiments were made on experimentally deformed olivines at temperatures of 1613–1788 K and pressures of 0.1 MPa to 2.0 GPa. In the high-pressure experiments, a piston cylinder apparatus was used with BN and NaCl powder as the pressure medium, and the hydrostatic condition of the pressure was checked by test runs with low dislocation density samples. No dislocation multiplication was observed. The kinetics of the dislocation annihilation process were examined by different initial dislocation density runs and shown to be of second order, i.e.

$\text{d}\text{ρ}\text{d}\text{t}\text{= ?p}{}^2\text{K}{}_0\text{exp}\text{[?(}\text{E}{}^1\text{+PV}{}^1\text{RT}\text{]}$

where ρ is the dislocation density, k₀ is a constant, $\text{E}{}^1\text{and}\text{V}{}^1$ are the activation energy and volume respectively, and P, R and T are pressure, gas constant and temperature, respectively. Activation energy and volume were estimated from the temperature and pressure dependence of the dislocation annihilation rate as $\text{E}{}^1\text{=389±59}\text{kJ mol}{}^{\mathrm{?1}}$ and $\text{V}{}^1\text{=14±2}\text{cm}{}^3\text{mol}{}^{\mathrm{?1}}$, respectively.The diffusion constants relevant to the dislocation annihilation process were estimated from a theoretical relation k=αD where $\text{k=k}{}_0\text{exp}\text{[?(E}{}^1\text{+ PV}{}^1\text{)/RT], D}$ is the diffusion constant and α is a non-dimensional constant of ca. 300. The results agree well with the self-diffusion constant of oxygen in olivine. This suggests that the dislocation annihilation is rate-controlled by the (oxygen) diffusion-controlled dislocation climb.The mechanisms of creep in olivine and dry dunite are examined by using the experimental data of static recovery. It is suggested that the creep of dry dunite is rate-controlled by recovery at cell walls or at grain boundaries which is rate-controlled by oxygen diffusion. Creep activation volume is estimated to be 16±3 cm³ mol^?1.     

Altitude variation of ultraviolet oxygen night airglow

Night airglow of oxygen 130.4 and 135.6 nm emissions was measured by a spectrophotometer aborad an S520 sounding rocket, launched at 19:50 JST (10:50 UT) on 14 February, 1982 from Kagoshima, Japan. The altitude variation of the emissions was obtained from 110 to 266 km at zenith angles of 35.5°±4°. The emission intensity around 260 km was about 160R and is roughly compatible with model calculations taking account of O⁺+e ^– radiative recombination as well as O⁺–O^– mutual neutralization. Some excess of about 50R, compared to the model calculation, was observed around 200 km. Possible explanations of the excess are: (i) remnant oxygen ions during the transition period from day to night and (ii) diffuse radiation from the background sky. Model calculations taking account of remnant oxygen ions were also performed by adding an excess electron density to the original density profile. However, it was found that an unreasonably large electron density is required around 200 km (5×10⁵ cm^–3) to produce the observed intensity. It is also probable that some contribution from the background sky is present in the observed intensity.     

Structural design of buried pipelines for severe earthquakes

In order to realistically assess the seismic risk of a pipeline system, the accurate estimate of the pipe strains which depend upon structural details, pipe material, properties of the surrounding soil, the nature of the propagating wave, etc. is critical. Emphasis in this study, therefore has been placed on the analysis of a structural strain for several types of piping elements unique to the buried pipeline and also the provision of a simplified design formula which can be used practically. The purpose of this study is (a) to define the slippage factor in order to estimate the decrease in pipe strain resulting from the slippage effect, (b) to propose a simplified method to evaluate the plastic deformation of the pipeline for severe earthquakes, and (c) to derive a practical design formula for the structural strains of bent pipes.     

Research on the seismotectonics of the January 17, 1995 HanshinM7.2 earthquake

Based on the geological tectonics, aftershock activity, earthquake surface rupture and peak ground motion, the geometric and dynamic characteristics of seismogenic tectonics about the 1995 Hanshin earthquake are analysed. Nojima fault and Rokko fault have the same trending direction, but opposite dips. Their rising and falling plates are in symmetrically diagonal distribution. The two faults can be defined as thrust-strike slip faults and constitute a pivotal strike-slip fault. The earthquake just occurred at the pivot, which is the seismotectonics for the earthquake to develop and occur. The pivotal movement along a strike-slip fault often leads to the occurrence of large earthquakes, whose dynamic process can be demonstrated by the stress analysis on the torsion of a beam with rectangle section. The displacement of earthquake surface rupture, aftershock density and peak acceleration change in a certain range of epicentral distance just similar as the shear stress changes from the center to the sides in the rectangle section. The distribution characteristics of the heaviest damage areas are also discussed in the article from the aspects of special geological tectonics and seismotectonic condition. The result obtained from the article can be applied not only to realizing the potencial earthquake sources in middle-long time, but also to build reasonably the prediction model about earthquake hazard.     

Dissolved Organic Matter in Oceanic Waters

The amount of information on oceanic dissolved organic matter (DOM) has increased dramatically in the last decade thanks to the advances in chemical characterization. This information has supported the development of some novel and important ideas for DOM dynamics in the ocean. Consequently, we have a better understanding of the importance of DOM in oceanic biogeochemical cycles. Here we review studies published mainly during 1995–2001, synthesize them and discuss unsolved problems and future challenges. The measurement, distribution and turnover of dissolved organic carbon (DOC) are presented as the bulk dynamics of the oceanic DOM. The size spectrum, elemental composition, and chemical compositions at molecular and functional group levels are described. The mechanisms proposed for the survival of biomolecules in DOM are discussed. This revised version was published online in July 2006 with corrections to the Cover Date.     

Fundamental analysis of deep sea mooring line in static equilibrium

The integrated equations of deep sea mooring lines in static equilibrium under consideration of gravity force and line elongation are obtained. The most useful forms of the equations for designing deep sea mooring system are those in which horizontal displacement and horizontal and vertical components of tension are obtained as functions of line length, water depth, critical tension and unit weight of line.When the dynamic simulation of a buoy system is carried out, line tensions acting on the buoy should be represented as a linear function of displacement. Therefore the linearisation method is introduced by use of linearisation coefficient matrix. Translation formulae for the matrix from two to three dimensions is also presented.The influence of line elongation on the horizontal component of tension in a taut mooring condition is important, therefore the elongation of stretched deep sea mooring line must be considered carefully. Also, the scaling law under consideration of line elongation in static equilibrium, which is necessary in estimation from a small sized experiment, is discussed.     

Distribution of coliform bacteria in the coastal water

Distribution of coliform bacteria was surveyed monthly during July-1968 through December-1969 in Shimizu Harbor and Orido Bay. Among three significant rivers flowing into the coastal region, the water of Tomoe River was most microbiologically polluted. Throughout the period of investigation horizontal distribution of the bacterial density was highest at the estuary of the Tomoe River, and its density decreased toward Shimizu Harbor and Orido Bay.It was shown that the bacterial density decreased from surface to deeper layer. High density of bacteria was observed in bottom deposits at winter. The bacterial distribution might be disturbed by current caused by geographical features.Various types of coliform group were isolated in the surveyed areas. All types ofE. coli, E. freundii, A. aerogenes and Irregular appeared in the area of estuaries, and only limited types occurred in offshore.Bacterial number increased from upper stream toward the mouth of each river. The bacterial density differed from river to river. In the rivers flowing through the city the bacterial density changed with water temperature, whereas in the river running through agricultual district it might be affected with the rainfall.