Sr isotope excursion across the Precambrian–Cambrian boundary in the Three Gorges area, South China

The Precambrian/Cambrian (PC/C) boundary is one of the most important intervals for the evolution of life. However, the scarcity of well-preserved outcrops across the boundary leaves an obstacle in decoding surface environmental changes and patterns of biological evolution.In south China, strata through the PC/C boundary are almost continuously exposed and contain many fossils, suitable for study of environmental and biological change across the PC/C boundary. We undertook deep drilling at four sites in the Three Gorges area to obtain continuous and fresh samples without surface alteration and oxidation. ⁸⁷Sr/⁸⁶Sr ratios of the fresh carbonate rocks, selected based on microscopic observation and geochemical signatures of Mn/Sr and Rb/Sr ratios, aluminum and silica contents, and δ¹³C and δ¹⁸O values, were measured with multiple collector-inductively coupled plasma–mass spectrometric techniques.The chemostratigraphy of ⁸⁷Sr/⁸⁶Sr ratios of the drilled samples displays a smooth curve and a large positive anomaly just below the PC/C boundary between the upper part of Baimatuo Member of the Dengying Formation and the lower part of the Yanjiahe Formation. The combination of chemostratigraphies of δ¹³C and ⁸⁷Sr/⁸⁶Sr indicates that the ⁸⁷Sr/⁸⁶Sr excursions preceded the δ¹³C negative excursion, and suggests that global regression or formation of the Gondwana supercontinent, possibly together with a high atmospheric pCO₂, caused biological depression.     

Carbon isotope chemostratigraphy of a Precambrian/Cambrian boundary section in the Three Gorge area, South China: Prominent global-scale isotope excursions just before the Cambrian Explosion

Carbon isotope chemostratigraphy has been used for worldwide correlation of Precambrian/Cambrian (Pc/C) boundary sections, and has elucidated significant change of the carbon cycle during the rapid diversification of skeletal metazoa (i.e. the Cambrian Explosion). Nevertheless, the standard δ¹³C curve of the Early Cambrian has been poorly established mainly due to the lack of a continuous stratigraphic record. Here we report high-resolution δ¹³C chemostratigraphy of a drill core sample across the Pc/C boundary in the Three Gorge area, South China. This section extends from an uppermost Ediacaran dolostone (Dengying Fm.), through a lowermost Early Cambrian muddy limestone (Yanjiahe Fm.) to a middle Early Cambrian calcareous black shale (Shuijingtuo Fm.). As a result, we have identified two positive and two negative isotope excursions within this interval. Near the Pc/C boundary, the δ¹³C_carb increases moderately from 0 to + 2‰ (positive excursion 1: P1), and then drops dramatically down to − 7‰ (negative excursion 1: N1). Subsequently, the δ¹³C_carb increases continuously up to about + 5‰ at the upper part of the Nemakit–Daldynian stage. After this positive excursion, δ¹³C_carb sharply decreases down to about − 9‰ (N2) just below the basal Tommotian unconformity. These continuous patterns of the δ¹³C shift are irrespective of lithotype, suggesting a primary origin of the record. Moreover, the obtained δ¹³C profile, except for the sharp excursion N2, is comparable to records of other sections within and outside of the Yangtze Platform. Hence, we conclude that the general feature of our δ¹³C profile best represents the global change in seawater chemistry. The minimum δ¹³C of the N1 (− 7‰) is slightly lower than carbon input from the mantle, thus implying an enhanced flux of ¹³C-depleted carbon just across the Pc/C boundary. Hence, the ocean at that time probably became anoxic, which may have affected the survival of sessile or benthic Ediacaran biota. The subsequent δ¹³C rise up to + 5‰ (P2) indicates an increase of primary productivity or an enhanced rate of organic carbon burial, which should have resulted in lowering pCO₂ and following global cooling. This scenario accounts for the cause of the global-scale sea-level fall at the base of the Tommotian stage. The subsequent, very short-term, and exceptionally low δ¹³C (− 9‰) in N2 could have been associated with the release of methane from gas hydrates due to the sea-level fall. The inferred dramatic environmental changes (i.e., ocean anoxia, increasing productivity, global cooling and subsequent sea-level fall with methane release) appear to coincide with or occur just before the Cambrian Explosion. This may indicate synchronism between the environmental changes and rapid diversification of skeletal metazoa.     

Internal structures and U–Pb ages of zircons from a tuff layer in the Meishucunian formation, Yunnan Province, South China

The Precambrian/Cambrian (PC/C) boundary is one of the most important intervals for the evolution of life, represented by prominent biological evolution from the first appearance of soft-bodied animals from the late Neoproterozoic to the sudden diversification of animals with mineralized skeletons in the Cambrian. In South China several areas contain many fossils and are well exposed, suitable for the investigation of PC/C boundary. However, geochronological relationships are still poorly known because of lack of combined detailed investigations of internal structures of zircons and in-situ U–Pb dating.We focus on the internal structure of zircons from a tuff layer within Bed 5 in the Meishucun section on which we undertook cathodoluminescence (CL) imaging and in-situ U–Pb dating with LA-ICP-MS and nano-SIMS. Over 600 zircons from the tuff layer were classified into three types based on their CL images: oscillatory rims, inherited cores and dull structures. U–Pb dating of the internal structure of the zircons by LA-ICP-MS clearly shows a distinct unimodal age population dependent on the structure: 531 ± 17 Ma for the oscillatory rims and 515 Ma for the dull structures. The clear oscillatory zonation, the prismatic morphology, and their occurrence indicate that the oscillatory rims were formed from felsic magmatism, and that the U–Pb nano-SIMS age of 536.5 ± 2.5 Ma records the depositional age of the tuff. Our results indicate that the PC/C boundary is situated below Bed 5, and therefore the bottom of Zone 1 (Marker A) is more appropriate for the PC/C boundary than is the top of Zone 1 (Marker B). The age of a positive anomaly (P2) in the early Cambrian is estimated to be ca. 536 Ma.     

Metamorphic zoning and thermal structure of the Dabie ultrahigh- pressure–high-pressure terrane, central China

The ultrahigh- and high-pressure (UHP–HP) metamorphic belt of the Dabie Mountains, central China, formed by the Triassic continental subduction and collision, is divided into four metamorphic zones; from south to north, the greenschist facies zone, epidote amphibolite to amphibolite facies zone, quartz eclogite zone, and coesite eclogite zone, based on metabasite mineral assemblages. Most of the coesite-bearing eclogites consist mainly of garnet and omphacite with homogeneous compositions and have partially undergone hydration reactions to form clinopyroxene + plagioclase + calcic amphibole symplectites during amphibolite facies overprinting. However, the least altered eclogites sometimes contain garnet and omphacite that preserve compositional zoning patterns which may have originated during their growth at peak temperature conditions of ∼ 750 °C, suggesting a short duration of UHP metamorphic conditions and/or consequent rapid cooling during exhumation. Systematic investigation on peak metamorphic temperatures of coesite eclogite have revealed that, contrary to the general trend of metamorphic grade in the southern Dabie unit, the coesite eclogite zone shows rather flat thermal structure (T = 600 ± 50 °C) with the highest temperature reaching up to 850 °C and no northward increase in metamorphic temperature, which is opposed to the previous interpretations. This feature, along with the preservation of compositional zonation, implies complicated differential movement of each eclogite mass during UHP metamorphism and the return from the deeper subduction zone at mantle depths to the surface.     

Three-year investigations into sperm whale-fall ecosystems in Japan

We report the first study of sperm whale‐fall ecosystems, based on mass sinking of whale carcasses at shelf depths in the northwest Pacific. We conducted three observations over a 2‐year period on replicate sperm‐whale carcasses implanted at depths of 219–254 m off the southern part of Japan from July 2003 to August 2005. The study was made possible by a mass stranding of sperm whales in January 2002, and the subsequent sinking of 12 carcasses in the waters off Cape Nomamisaki. Dense aggregations of unique chemosynthesis‐based fauna had formed around the whale carcasses after 18 months (July 2003). The mytilid mussel Adipicola pacifica was the most abundant macrofaunal species and covered most of the exposed bone surfaces. The general composition of the fauna was similar to that of deep‐water reducing habitats, but none of the species appearing in this study has been found at hydrothermal vents, cold seeps or deep‐water whale falls. A new species of lancelet, which was the first record of the subphylum Cephalochordata from reducing environments, a new species of Osedax; a rarely encountered benthic ctenophore, and a rare gastropod species were discovered at this sperm whale‐fall site. Benthic communities were similar across all the carcasses studied, although the body sizes of the whales were very different. The succession of epifaunal communities was relatively rapid and the sulphophilic stage was considerably shorter than that of other known whale falls.     

Mechanism for enhanced diffusivity in the deep-sea perpetual salt fountain

The mechanism of enhanced diffusivity occurring in the deep-sea perpetual salt fountain has been investigated experimentally and numerically. Some factors which possibly contribute to the enhanced diffusivity were found to be the pipe oscillation with ocean waves and its baffled wall surface. Field experiments in the ocean (Onagawa Bay of Miyagi, Japan) and numerical simulations were performed to study and confirm the dynamics of the flow and heat transport with enhanced diffusivity occurring in upwelling deep-sea water. The agreement between the field experimental data and the numerical solutions of an oscillating-wall boundary condition imposed on the baffled pipe is encouraging, and it indicates the baffled pipe surface subject to the oscillatory motion leads to the enhanced diffusivity. The buoyancy force and then upwelling velocity can be greatly increased by the enhanced diffusivity. The dominant mechanism is the occurrence of complicated vortices and vortex shedding leading to efficient mixing and enhanced diffusion.     

Heat budget of air passing through a hot tunnel in northeastern Japan

Summary A geothermal and meteorological observation was carried out inside a hot tunnel (named Torigoe tunnel) penetrating through a volcanic zone in northeastern Japan, just after it has been penetrated. Rock wall surface temperature, some thermal properties of rock samples, temperature profile in slender pits drilled into the rock body, temperature of water flowing on the floor and the meteorological elements of air passing through the tunnel are contained in the observation.Introducing the coefficient of heat transfer determined from the Reynolds analogy for turbulent forced convection in a circular tube, the heat budget of the air-tunnel system is investigated with those observed data. The results show that the net sensible heat of 58.61 kW is drawn out from the tunnel by air passing through it and seems to be overcompensated by the net heat supply of 67.21 kW from the rock wall to air, while for the net latent heat removal of 101.56 kW by air the apparent undercompensation of 80.01 kW is found from the water flowing on the floor. Consideration is carried out on such excess and deficiency of heat supplies.

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Zusammenfassung In einem heißen Tunnel (dem Torigoe-Tunnel), der durch vulkanisches Gebiet im nordöstlichen Japan verläuft, wurden unmittelbar nach Tunneldurchstoß geothermische und meteorologische Untersuchungen durchgeführt. Die Temperatur der Gesteinsoberfläche, spezifische thermische Eigenschaften der Gesteinsproben, das Temperaturprofil von dünnen Bohrkernen, als auch die Temperatur des Wassers am Tunnelgrund und meteorologische Daten der Durchzugsluft werden in dieser Untersuchung berücksichtigt.Durch Einführung des durch die Reynolds-Analogie determinierten Wärmeaustauschkoeffizienten für turbulente, erzwungene Konvektion in einer kreisförmigen Röhre wird der Wärmehaushalt der Luft im Tunnelsystem unter Heranziehung der angeführten Daten untersucht. Die Resultate zeigen, daß 58.61 kW fühlbare Wärme dem Tunnel durch die Luft entzogen werden, die jedoch durch eine Zufuhr von 67.21 kW von der Felswand an die Luft abgegebener fühlbarer Wärme überkompensiert zu werden scheint, während der dauernden latenten Wärmeabfuhr durch die Luft von 101.56 kW eine Unterkompensierung von 80.01 kW durch das am Tunnelgrund fließende Wasser gegenübersteht. Die Folgen dieses Überschusses bzw. Defizites werden genauer diskutiert.

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With 5 Figures     

An experimental investigation of heulandite-laumontite equilibrium at 1000 to 2000 bar P fluid

The univariant reaction governing the upper stability of heulandite (CaAl₂Si₇O₁₈·6H₂O), heulandite=laumontite+3 quartz+2H₂O (1), has been bracketed through reversal experiments at: 155±6° C, 1000 bar; 175±6° C, 1500 bar; and 180±8° C, 2000 bar. Reversals were established by determining the growth of one assemblage at the expense of the other, using both XRD and SEM studies. The standard molal entropy of heulandite is estimated to be 783.7±16 J mol^–1 K^–1 from the experimental brackets. Predicted standard molal Gibbs free energy and enthalpy of formation of heulandite are –9722.3±6.3 kJ mol^–1 and –10524.3±9.6 kJ mol^–1, respectively. The reaction (1), together with the reaction, stilbite=laumontite+3 quartz+3 H₂O, defines an invariant point at which a third reaction, stilbite=heulandite+ H₂O, meets. By combining the present experimental data with past work, this invariant point is located at approximately 600 bar and 140° C. Heulandite, which is stable between the stability fields of stilbite and laumontite, can occur only at pressures higher than that of the invariant point, for = P _total.These results are consistent with natural parageneses in low-grade metamorphic rocks recrystallized in equilibrium with an aqueous phase in which is very close to unity.     

Possible depth limit for underplating by a seamount

The Cazadero metabasite allochthon is located within the central melange belt of the northern California Coast Ranges, U.S.A. It composed mainly of pillowed and massive mafic flows, hyaloclastite and minor pelagic sediments. It is about 3 × 15 km² in extent, and is in fault contact with Late Mesozoic fore-arc flysch deposits of the Great Valley sequence. Three metamorphic zones were mapped in the allochthon, as follows-in order of increasing metamorphic grade: the lawsonite, the pumpellyite and the epidote zone. Ca---Na pyroxenes are ubiquitous; they were used to estimate the P-T path, together with the oxygen isotope geothermometry of Taylor and Coleman. The result shows a bending point in the P-T path for blueschist facies metamorphism of the Cazadero allochthon. At shallow depths, lower grade metamorphism proceeded under predominant pressure-increase from 4 to 7 kbar at nearly constant T of about 150–200 °C, whereas after passing the bending point higher-grade metamorphism occurred with increasing temperature from 200 to 350 °C at nearly constant P of about 7–8 kbar.

The bending point reflects the depth of transfer of underplating materials from the oceanic lithosphere and its overlying sediments to the hanging wall plate. Either seamount volcanics and pelagic sediments, or mixed packages of fragmented oceanic crust with trench-fill turbidites, were subducted beneath the North American plate. They were subjected to early lawsonite- and pumpellyite-zone metamorphism with very low geothermal gradient. We infer that when they reached about 20 km depth, underplating occurred and the metamorphosed rocks became part of the hanging wall. Heat conduction from the overlying hydrated mantle wedge caused a temperature increase at nearly constant depth. The earlier recrystallized seamount volcanics and pelagic sediments were then metamorphosed at a much higher geothermal gradient. The Cazadero allochthon has suffered extremely high P/T subduction zone metamorphism and it preserves very well the record of Cretaceous subduction-underplating processes.     

Characteristic heat transfer coefficients near the ground at night during strong winds

Based on theoretical radiative cooling values and observed temperature changes with time near the surface during the night, the bulk heat transfer coefficient C _H is estimated from standard meteorological observations obtained from stations representative of open rural, small town and large urban areas, for nights with clear skies and relatively strong winds. It is shown that C _H is smaller than the drag coefficient C _M, and that C _H/C _M over urban areas is smaller than that over open countryside.