Regional appraisal of the fluoride occurrence in groundwaters of Andhra Pradesh

Fluoride (F^?) is essential for normal bone growth, but higher concentration in the drinking water causes health problems which are reported in many states of India. Andhra Pradesh is one of the states which suffer from excess fluoride in groundwater particularly in the hard rock terrain. In this context, a study was conducted in Andhra Pradesh based on chemical analysis of water samples from hydrograph net work stations (dug wells) and exploratory bore wells. The concentration of fluoride in groundwaters ranges from traces to 9.75 mg/l. The occurrence of fluoride is mostly sporadic, uneven and varies with depth. The highly affected districts include Nalgonda and Warangal in Telangana region, Prakasam in coastal region, Anantapur and Kurnool in Rayalaseema region. In certain areas of Nalgonda district, 85% of wells have fluoride more than permissible limit (> 1.5 mg/l) for drinking water. High F^? is present in all the geological formations, predominantly in granitic aquifers, compared to the other formations. The average value of fluoride is high in the deeper zone (1.10 mg/L), compared to the shallow zone (0.69 mg/L). The fluoride-rich minerals present are the main sources for fluoride concentrations in groundwater. Residence time, evapotranspiration and weathering processes are some of the other supplementary factors for high fluoride concentrations in groundwater. Long-term data of hydrograph net work stations (dug wells) reveal that fluoride concentrations do not show any marked change of trend with respect to time. The concentration of fluoride is found to increase with increase of Na⁺and HCO ₃ ^? , and decrease with increase of Ca²⁺. Sodium bicarbonate waters are more effective in releasing fluoride from minerals into groundwater. High fluoride waters are of Na⁺ type. The paper presents a brief account of the study and its results.     

Trace elements in ferromanganese nodules from the central indian ocean basin

Thirty-three bulk ferromanganese nodules from the sediment–water interface of siliceous sediment domain from the Central Indian Ocean Basin were analyzed for 50 elements including 6 new (Be, As, Se, Sn, Sb, and Bi) using inductively coupled plasma–mass spectrometer. The Mn/Fe ratio and triangular plot (Fe-Mn-{Cu+Ni+Co?×?10}) suggest that ferromanganese nodules are of hydrogenetic, early diagenetic, and diagenetic origin. In the ferromanganese nodules, Mo, Sb, Bi, and As are highly enriched ～320, 160, 90, and 50 times compared with upper continental crust, respectively. A majority of the elements such as Be, Sc, Ti, V, Co, As, Se, Sr, Y, Zr, Nb, Sn, rare earth elements (REEs), Pb, Bi, P, Th, U, Hf, and Ta are associated with Fe, whereas, Cu, Ni, Zn, Mo, Li, Ga, Sb, Mg, and Cs are associated with Mn in the ferromanganese nodules. Redox proxies such as U/Th (0.14) and Mo/Mn (0.0019) ratio in the ferromanganese nodules suggest their formation under oxic conditions.     

Seismic source zoning and maximum credible earthquake prognosis of the Greater Kashmir Territory,NW Himalaya

We present the seismic source zoning of the tectonically active Greater Kashmir territory of the Northwestern Himalaya and seismicity analysis (Gutenberg-Richter parameters) and maximum credible earthquake (m _max) estimation of each zone. The earthquake catalogue used in the analysis is an extensive one compiled from various sources which spans from 1907 to 2012. Five seismogenic zones were delineated, viz. Hazara-Kashmir Syntaxis, Karakorum Seismic Zone, Kohistan Seismic Zone, Nanga Parbat Syntaxis, and SE-Kashmir Seismic Zone. Then, the seismicity analysis and maximum credible earthquake estimation were carried out for each zone. The low b value (<1.0) indicates a higher stress regime in all the zones except Nanga Parbat Syntaxis Seismic Zone and SE-Kashmir Seismic Zone. The m _max was estimated following three different methodologies, the fault parameter approach, convergence rates using geodetic measurements, and the probabilistic approach using the earthquake catalogue and is estimated to be M _w 7.7, M _w 8.5, and M _w 8.1, respectively. The maximum credible earthquake (m _max) estimated for each zone shows that Hazara Kashmir Syntaxis Seismic Zone has the highest m _max of M _w 8.1 (±0.36), which is espoused by the historical 1555 Kashmir earthquake of M _w 7.6 as well as the recent 8 October 2005 Kashmir earthquake of M _w 7.6. The variation in the estimated m _max by the above discussed methodologies is obvious, as the definition and interpretation of the m _max change with the method. Interestingly, historical archives (～900 years) do not speak of a great earthquake in this region, which is attributed to the complex and unique tectonic and geologic setup of the Kashmir Himalaya. The convergence is this part of the Himalaya is distributed not only along the main boundary faults but also along the various active out-of-sequence faults as compared to the Central Himalaya, where it is mainly adjusted along the main boundary fault.