Isolation and pharmacological activities of bromophenols from Rhodomela confervoides

Four bromophenols were isolated from the extract of marine red alga,Rhodomela confervoides by column chromatography and HPLC methods. By means of spectroscopic methods inclding IR, MS, 1D, and 2D-NMR techniques, their structures were elucidated as (1) 3-bromo-4,5-dihydroxy benzoic acid methyl ester; (2) bis (2,3-dibromo-4,5-dihydroxybenzyl) ether; (3) 3,4-dibromo-5-(methoxymethyl)-1,2-benzenediol and (4) 3-bromo-4,5-dihydroxy-benzaldehyde. Compound 1 was first isolated from the algae in nature, and 1, 4 were found to have selective cytotoxic activities against KB, Bel 7402 and A549 cells, 2 showed powerful antibacterial activities againstStaphylococcus aurens andPseudomonas aeruginosa. Supported by National “863” Program (No. 2004AA625030, 2001AA620503), Quingdao marine sciences project (No. 04-2-NN-26) and Key Knowledge Innovative Project of the Chinese Academy of Sciences (KZCX3-SW-215).     

准噶尔盆地四棵树凹陷侏罗系烃源岩特征及油源分析

侏罗系是四棵树凹陷油气勘探的重要目的层,进一步查明侏罗系油气来源,落实生烃中心,对今后勘探选区选带十分重要。本文在对侏罗系烃源岩有机质丰度、类型、成熟度以及埋藏史和生烃潜力分析的基础上,开展了原油分类、油源对比及油气运移分析研究。结果表明,下侏罗统八道湾组主要发育湖相泥岩和河沼—三角洲相煤系两类烃源岩,有机质类型较好,丰度较高,主体处于低成熟—成熟阶段,局部演化程度高,生气潜力大;八道湾组具晚期快速埋藏生烃特点,四棵树凹陷主体以生油为主;生物标志化合物特征及其指纹对比发现,中侏罗统头屯河组含A、B两类原油,A类原油主要源自八道湾组中段湖相泥岩,生油母质以低等水生生物为主,B类原油的生油母质主要为高等植物,应主要来自八道湾组上、下段煤系地层;据三环萜烷/五环三萜烷和重排甾烷/规则甾烷反映出的运移效应推断,卡因迪克构造带以南至西湖构造之间存在八道湾组烃源岩的生油中心,是卡6井区和西湖1井头屯河组原油的主要供烃区,该区域是今后侏罗系勘探的有利区带。     

THE DIVERGENCE-CONVERGENCE EFFECT OF SURFACE CURRENT AND ITS ACTION ON THE BOHAI SEA

The action of the wind field and the influence of topography can cause divergence or convergence of surface current. The existence of the divergence-convergence effect is proved and the dynamical significance of the divergent or convergent state and its link with many marine phenomena are pointed out. Divergence fields of surface current in the Bohai Sea in winter and summer are obtained by numerical modelling describing the divergence-convergence character of seasonally wind-driven current. The relation between the effect and seasonal marine phenomena is discussed. Study on the divergence-convergence effect of surface current (DCESC)can be an indirect method for testing the calculated results.     

一次“高影响天气”的弱降雪过程的数值研究

该文对2001年12月7日下午北京的一次弱降雪天气过程进行了诊断分析和数值模拟研究。诊断结果表明：北京地区由于受500 hPa小槽东移及850 hPa东移小高压后部带来的来自东海和南海的偏南暖湿气流共同影响,造成降雪。数值模拟结果显示：MM5模式对这次降雪过程具有较好的模拟能力,不仅模拟出了北京地区的降雪量,而且对这次过程大尺度背景场的演变、触发机制和水汽源有很好的表述。利用诊断分析和数值模拟结果,对这次弱降雪过程引起交通大阻塞的可能因素进行了探讨,说明建立城市预警系统的迫切性。     

风水复合侵蚀研究进展与展望

风水复合侵蚀是干旱,半干旱区一种常见的土壤侵蚀类型,是风水两相外营力相互耦合驱动下发生的地表物质再分配过程。在辨析风水复合侵蚀类型的基础上,将风水复合侵蚀影响因子归结为侵蚀动力因子、土壤抗蚀性因子与干扰因子,并分析了影响因子间的互馈关系;从全球尺度、区域尺度和局地尺度,总结了风水复合侵蚀在空间尺度上的差异;评述了风水共同侵蚀过程中侵蚀力与侵蚀能量的叠加效应,风水交替侵蚀过程中侵蚀力与侵蚀能量的交替性特征,以及下垫面和干扰因子对风水复合侵蚀的响应;阐述了风力与水力侵蚀在总侵蚀量中的贡献比率与两者叠加所产生的耦合效应;认为风水复合侵蚀实验研究是认识风水复合侵蚀过程与机理的基础,应将风水复合侵蚀过程段研究扩展到全过程研究,同时加强下垫面在风水复合侵蚀中的响应机制以及水蚀与风蚀间的抑制效应研究,以期达到全面客观地认识风水复合侵蚀过程与机制的目的。     

云南地区房屋建筑的震害矩阵

自1992年4月23日云南孟连西中缅交界6.7、6.9级地震始,地震部门对云南地区的破坏性地震进行了现场灾害调查和经济损失评估。1992~2003年,云南地区共发生50次破坏性地震,积累了丰富的震害资料。本文根据云南地区的主要建筑结构,统计分析了50次地震不同烈度区的破坏比、损失比和震害指数,给出了房屋建筑的震害矩阵。     

中子活化测井原位测定氟化钙含量技术及应用

在萤石矿勘探工作中,因为萤石性脆,在钻探过程中易破淬,岩(矿)芯采取率难以达到要求。当萤石与硬岩石共存时,因选择性磨损,以及萤石分布不均匀等原因,使矿芯分析结果失去了代表性。中子活化测井工作的目的,是在钻孔中原位测定CaF_2含量,以弥补钻探取芯分析资料的不足,提高地质工作质量。根据方法原理,研究了适应连续测井方式及定点测量方式的技术条件和资料解释方法。对萤石矿可达到三定(定矿层、定位置、定厚度)和计算CaF_2含量的目的,工作效率可达到常规测井水平,含量测定精度、灵敏度和准确度均可满足萤石矿地质普查、勘探的要求。     

多时间序列求关联维D_2

在利用Ｇ．Ｐ．法由单一时间序列计算关联维Ｄ_２的基础上，引入矩阵范数，提出了多时间序列数据联合计算关联维Ｄ_２的算法。这一算法是Ｇ．Ｐ．法的推广。验算结果表明这一算法正确、可行，能提高计算结果的可靠性。     

LAST GLACIATION AND MAXIMUM GLACIATION IN THE QINGHAI-XIZANG (TIBET) PLATEAU: A CONTROVERSY TO M. KUHLE,S ICE SHEET HYPOTHESIS

Since the late 1950's, many Chinese scientists have explored the remains of the Quaternary glaciation in the Qinghai-Xizang (Tibet) Plateau and its surrounding mountains. In the main, 3-4 glaciations have been recognized. The largest one occurred in the Late Middle Pleistocene with piedmont glaciers, ice caps and trellis valley glaciers in many high peak regions. But here is no evidence of a unified ice sheet covering the whole plateau as described by M. Kuhle. Due to the further uplifting of the Himalayas and Qinghai-Xizang Plateau the climate became progressively drier, diminishing the extension of glaciers during the Late Pleistocene. The elevation of the snow line during the Last Glaciation was about 4,000 m on the south, east and northeast edges of the plateau and ascended to 5500 m on the hinder northwest of the plateau. The thermal effect of the big plateau massif, the sharp increase of aridity from the southeast rim to the northwest inland area and the abrupt decrease of precipitation during the     

近百年全球平均气温年际变率中的QBO长期变化特征

应用奇异谱分析(SSA)方法和奇异交叉谱分析(SCSA)方法，对全球及南北半球近100多年(1856～1997年)逐月地面气温距平序列中的准两年周期振荡(QBO)的长期演变特征进行诊断分析。结果表明:全球平均气温序列蕴含显著的QBO分量，它们与全球气候系统中其他各个子系统所隐含的QBO信号具有各种耦合对应关系，尤其突出地表现在Nino区海温和以SLP序列为代表的全球大气环流系统中QBO信号的耦合对应关系上。而平均气温的QBO的年代际特征及其变率的阶段性，不但表现在振幅上，而且其位相亦很明显。上述特征在全球、两半球具有明显的差异。