The ∼1100 Ma Sturgeon Falls paleosol revisited: Implications for Mesoproterozoic weathering environments and atmospheric CO2 levels

During the active rifting stage of the ∼1100 Ma Midcontinental Rift in North America, alluvial sediments were deposited intermittently between basalt flows on the north and south shores of present day Lake Superior. At times of depositional quiescence, paleosols developed in both areas on the alluvial sediments and on the antecedent basalt. New results from the Sturgeon Falls paleosol in Michigan characterizing the weathering processes at the time of its formation indicate moderate maturity, high degrees of hydrolysis and leaching, and a low degree of salinization. Geochemical provenance indices indicate a homogeneous source for the paleosols, and in contrast to earlier work, there is little evidence for K metasomatism. As a result, atmospheric CO₂ levels of 4–6× pre-industrial atmospheric levels were calculated using a mass-balance model. This result is consistent with previous calculations from nearly contemporaneous paleosols from the other side of the Keweenawan Rift and from the ∼100 Ma younger Sheigra paleosol in Scotland. The calculated CO₂ values are also consistent with the calculated weathering environment proxies that indicate weak to moderate weathering at this time frame and suggest that the higher greenhouse gas loads indicated by Paleoproterozoic paleosols had dissipated by the mid-late Mesoproterozoic.     

Preferential flow and segregation of porewater solutes in Wetland sediment

Sediment macropores (with effective diameters larger than 100 μm) comprise 11% of the bulk sediment volume in a tidal freshwater wetland vegetated withPeltandra virginica. In order to determine effects of macroporous sediment structure on solute transport, we conducted a solute tracer experiment in the sediment. The effective transport volume (θ_eff, the volume of sediment through which solute was transported normalized to sediment bulk volume) was 0.15 cm³ cm^?3, which is considerably smaller than the total pore space that is potentially available for transport (porosity of sediment is 0.63 cm³ cm^?3). A mean transport time of 13 d was required to flush preferential flow paths inPeltandra hummocks; hydrologic turnover of the volumetrically dominant matrix pores (0.53 cm³ cm^?3) was apparently much slower. Based on porewater sampler design and hydrological principles, we suggest that N₂-purged tension solution samplers and diffusion equilibrators preferentially sample porewater from macropore and matrix domains, respectively. Dissolved ammonium and orthophosphate concentrations were three-fold higher in matrix pores compared to macropores, which is consistent with our finding that more rapid hydrological flushing occurred in macropores compared to matrix pores. Further evaluation of porewater sampler designs in macroporous sediment is needed to improve studies of hydrologic transport and biogeochemical cycling in wetlands.     

An isopycnal view of the Nordic Seas hydrography with focus on properties of the Lofoten Basin

Few basins in the world exhibit such a wide range of water properties as those of the Nordic Seas with cold freshwaters from the Arctic in the western basins and warm saline waters from the Atlantic in the eastern basins. In this study we present a 50-year hydrographic climatology of the Nordic Seas in terms of depth and temperature patterns on four upper ocean specific volume anomaly surfaces. This approach allows us to better distinguish between change due to variations along such surfaces and change due to depth variations of the stratified water column. Depth variations indicate changes in the mass field while property variations along isopycnals give insight into isopycnal advection and mixing, as well as diapycnal processes. We find that the warmest waters on each surface are found in the north, close to where the isopycnal outcrops, a clear indication of downward mixing of the warmer, more saline waters on shallower isopycnals due to convective cooling at the surface. These saline waters come from the Norwegian Atlantic Slope Current by means of a very high level of eddy activity in the Lofoten Basin.The isopycnal analyses further show that the principal water mass boundary between the waters of Arctic origin in the west and Atlantic waters in the east aligns quite tightly with the Jan Mayen, Mohn, Knipovich Ridge system suggesting little cross-ridge exchange. Instead, the main routes of exchange between the eastern and western basins appear to be limited to the northern and southern ends of ridge system: Atlantic waters into the Greenland Sea in the Fram St and Artic waters into the southern Norwegian Sea just north of the Iceland-Faroe Ridge.Analysis of a representative isopycnal in the main pycnocline shows it to be stable over time with only small variations with season (except where it outcrops in winter in the Greenland and Iceland Seas). However, two very cold winters, 1968–1969, led to greater than average heat losses across the entire Lofoten Basin that eroded away much of the Lofoten eddy and induced the greatest temperature anomaly in the entire 50-year record. Interannual variations in isopycnal layer temperature correlate with the NAO index such that waters in the Iceland Sea become warmer than average with warming air temperatures and conversely in the Lofoten Basin.