The ∼1100 Ma Sturgeon Falls paleosol revisited: Implications for Mesoproterozoic weathering environments and atmospheric CO2 levels

During the active rifting stage of the ∼1100 Ma Midcontinental Rift in North America, alluvial sediments were deposited intermittently between basalt flows on the north and south shores of present day Lake Superior. At times of depositional quiescence, paleosols developed in both areas on the alluvial sediments and on the antecedent basalt. New results from the Sturgeon Falls paleosol in Michigan characterizing the weathering processes at the time of its formation indicate moderate maturity, high degrees of hydrolysis and leaching, and a low degree of salinization. Geochemical provenance indices indicate a homogeneous source for the paleosols, and in contrast to earlier work, there is little evidence for K metasomatism. As a result, atmospheric CO₂ levels of 4–6× pre-industrial atmospheric levels were calculated using a mass-balance model. This result is consistent with previous calculations from nearly contemporaneous paleosols from the other side of the Keweenawan Rift and from the ∼100 Ma younger Sheigra paleosol in Scotland. The calculated CO₂ values are also consistent with the calculated weathering environment proxies that indicate weak to moderate weathering at this time frame and suggest that the higher greenhouse gas loads indicated by Paleoproterozoic paleosols had dissipated by the mid-late Mesoproterozoic.     

In Situ Vertical Circulation Column: Containment System for Small-Scale DNAPL Field Experiments

The in situ vertical circulation column (ISVCC) is a cylindrical containment system consisting of an instrumented steel cylinder used for experimental ground water studies in sandy aquifers. Vertical flow is imposed inside the ISVCC. Although vertical wells are an option, the ISVCC installed in the Borden Aquifer is instrumented with horizontal wells and monitoring ports to avoid creating vertical preferential flow paths. The cylinder was driven downward into the aquifer using a small backhoe equipped with a vibrating plate. The ISVCC penetrates the 2.3-m-thic sand aquifer and is keyed 20 cm into the underlying clay aquitard. The cylinder was installed inside a 2 m X 2 m steel sheet pile enclosure so that the enclosed segment of aquifer could be conveniently dewatered and then excavated to allow installation of the horizontal wells. The dispersivity of the column was comparable to literature values for long sand-packed laboratory columns.
Pure phase DNAPL (tetrachloroethene and 1,1,1-trichloroethane) was slowly pumped into two ports in the center of the column. Following this DNAPL injection, an aqueous solution of vitamin B₁₂ and reduced titanium was circulated through the column to promote degradation of the solvents. Processes observed in the ISVCC included DNAPL distribution, dissolution, and degradation, and geochemical evolution of the aquifer.
The ISVCC provides a convenient means for testing in situ technologies in the experimental stage or for selection of proven technologies to find the most effective at a specific site. It is inexpensive, easy to install, and maximizes control over flow distribution in a heterogeneous aquifer. Its application will be restricted where low hydraulic conductivity beds are present in the aquifer.     

Upper Cretaceous bottom current deposits,north-east Greenland

Reported ancient bottom current deposits in deep marine settings are scarce and most of them remain contentious. This study describes sedimentological, ichnological and petrographical characteristics of a drill core that covers ca 10 Myr of Upper Cretaceous stratigraphy at Hold with Hope, north-east Greenland. The core is divided into four facies associations, which are interpreted to reflect deposition from bottom currents, turbidity flows and hemipelagic settling in slope and/or near slope environments. The evidence for bottom current influence is three-fold. Firstly, pervasive indications of winnowing such as marine bioclast-rich lags and outsized clasts on ‘mud on mud’ contacts are suggestive of low-sediment concentration flows capable of transporting up to pebble-sized clasts. Common Mn–Fe–Mg rich carbonate matrix cements and various types of hiatal chemogenic lag deposits showing glauconite, apatite and carbonate clasts also point to condensation, prolonged exposure at the sediment–water interface and recurrent phases of sea-floor erosion. Secondly, such deposits can show indicators for tidal processes such as double mud-drapes, tangential bottom sets in dune-scale cross-bedding and cyclic rhythmites. Thirdly, inverse to normal grading at various scales is common in fully marine, commonly seafloor-derived sediments. Ichnological data indicate considerable taxonomic variability in the bottom current deposits, but recurrent fabrics are characteristically dominated by morphologically simple burrows such as Thalassinoides and Planolites, with secondary Phycosiphon, Nereites, Zoophycos and/or Chondrites. In general, opportunistic taxa are common whereas mature composite ichnofabrics are rare. The omission surfaces are locally burrowed with stiffground to firmground trace fossil suites. The results contribute to establishing sedimentological, ichnological and mineralogical criteria for recognition of bottom current deposits as well as to the understanding of the Late Cretaceous palaeoenvironmental evolution of the Arctic region.     

A deterministic approach to the prediction of free field ground motion and response spectra from stick-slip earthquakes

Theoretical and experimental results from computational physics and non-linear rock mechanics have been merged in order to obtain a deterministic model of a stick-slip earthquake. The model has been exercised to uncover the dependence of peak ground motion and response spectra on fault length, rupture velocity and dynamic stress drop during rupture. A particular method for generating a design spectrum has been tested against results from the model. Utilization of this deterministic technique seems especially appropriate when design information is required at sites located near the epicentre.     

Low-Cost On-Site Treatment of Landfill Leachate Using Infiltration Beds: Preliminary Field Trial

A small-scale field experiment was carried out to demonstrate the effectiveness of using septic system -type infiltration beds for on-site treatment of landfill leachate. Using an infiltration bed with a 3-m-thick vadose zone of medium sand, and loaded at a rate 01 18 cm/day, a treatment efficiency of >99 percent was obtained for Fe, 94 percent for NH₄⁺, and 54 percent for dissolved organic carbon (DOC). Attenuation occurred during one- to two-day residency in the aerobic vadose zone (pore gas O₂ > 12 percent by volume) as a result of oxidation reactions that caused nitrification of NH₄⁺, convened Fe²⁺ to Fe³⁺ allowing subsequent precipitation of sparingly soluble Fe oxyhydroxide minerals, and biodegraded DOC. Attenuation of an aerobically degradable trace volatile organic compound (dichlorobenzene) was also noted, although other less degradable compounds (trichloroethylene and tetrachloroethylene) persisted.
Fe mineral precipitation caused a discontinuous hardpan layer to occur in the zone immediately below the infiltration pipes. However, this layer did not become impermeable or continuous enough to significantly impede infiltration during the 82-day experiment.
Advantages of this technology for leachate treatment are that it is low cost, it is simple to construct and operate. and treatment occurs on-site, avoiding the cost of transporting leachate off-site for treatment.     

Wind environment in the Lee of Kauai Island,Hawaii during trade wind conditions: weather setting for the Helios Mishap

On 26 June 2003 (approximately 1030 local time) the Helios ultralight aircraft broke apart off the west coast of Kauai Island, Hawaii as it was climbing out of the Kauai wind shadow. Following the aircraft mishap, a study was carried out to understand the conditions on the day of the crash and to better characterize the wind in the lee of Kauai. As part of this effort, both aircraft measurements and numerical modelling studies were carried out. Measurements and models showed the trade wind flow was enhanced around the island creating a region of wind shear surrounding the leeside calm zone. This wind shear region was found to be vertically oriented along the south side but tilted northward with height along the northern side of the calm zone. Several other factors on the day of the crash were investigated including water vapour gradients, diurnal Island heating, and gravity waves but their possible influences on the crash could not be confirmed. While the numerical model captured the general features of the Kauai leeside winds, the orientation of the calm zone was north of the observed one.