Estimation for ammonia emissions at county level in China from 2013 to 2018

Science China Earth Sciences - Ammonia (NH3) can interact with other trace chemicals in the atmosphere, significantly impacting atmospheric chemistry and global climate change. China is a largely...     

库车前陆冲断带盐下深层压力特征及其油气勘探意义

库车前陆冲断带盐下深层气藏埋深大, 普遍发育超压。通过收集大量盐下深层压力实测数据, 开展压力分布规律研究, 揭示其与气藏的形成及分布之间的联系。结果表明, 库车前陆冲断带盐下深层压力分布为85~127 MPa, 压力系数分布为1.5~1.9, 为超压特征。平面上, 地层压力和压力系数分布表现为南北分带、东西分段的特征。侏罗系烃源岩距白垩系巴什基奇克组砂岩顶部为1 500~4 000 m之间, 平均为3 000 m, 源储压差在70 MPa以上, 超压流体为天然气强充注成藏提供动力条件, 是形成高效气藏的必要条件。平面上, 盐下深层大气藏(田)的分布与超压分布区叠置;纵向上, 气藏群位于超压集中发育的封闭楔形冲断体内, 成排成带分布。     

催化极谱法同时测定化探样品中的钨、钼

样品经碱熔分解,热水浸取,干扰元素铁、锰、钴、镍等形成氢氧化物沉淀与钨、钼分离。分取清液,在硫酸-苦杏仁酸-氯酸钠-辛可宁底液中,钨和钼均能产生灵敏的极谱催化波,峰电位分别为-0.76V和-0.25V(对饱和甘汞电极而言),固定试液体积,混合底液用针管一次加入,节省了稀释、定容、混匀的步骤,在JP4000型示波极谱仪上一次扫描同时测定钨和钼的峰电流,以峰高为纵坐标、含量为横坐标绘制工作曲线,直接计算出样品中钨、钼的含量,方法检出限(以三倍标准偏差计算)钨0.21μg/g,钼0.17μg/g,测定体系中,钨、钼分别在0.02~10.0μg范围内成良好的线性关系。     

燕山地区宣龙坳陷高于庄组-雾迷山组沉积相与地球化学特征

通过对野外剖面的观察和测量,根据剖面岩性及古生物等相标志,结合室内薄片资料的研究,认为燕山地区宣龙坳陷中元古界高于庄组—雾迷山组主要发育-套海相碳酸盐岩,局部夹少量海相碎屑岩,韵律性和旋回性明显,叠层石形态丰富.可划分为海相碳酸盐岩台地和生物礁2个相带,进一步可细分为潮坪和障积-黏结礁2种亚相以及潮上带、潮间带、潮下带...     

河南省制造业创新能力及其与先进省份的比较

采取《中国创新指数研究报告No.1》所提供的创新指数评估方法和评估数据,并通过与先进省份对比,分析了河南省制造业综合创新能力及构成,探讨了河南省制造业创新能力分企业类型状态,研究了河南省制造业创新能力与区域综合创新能力的关系,发现河南制造业创新能力虽然位居中部前列,但具有显著的结构二元性,在管理创新、规模经济和合作创新等方面积累了良好的优势,而体现自主创新的基础创新能力则严重不足,这种不足与全省综合创新能力整体上和结构上的落后密切相关。     

水热法合成黄铁矿微观形貌和结构的观测与表征

模拟热液型金矿床中黄铁矿生成的地质条件,采用硫酸亚铁(FeSO4)和硫代乙酰胺(CH3CSNH2)为铁源和硫源,在Fe/S比为1∶3、温度180~200 ℃、加热时间24 h条件下考察黄铁矿的结晶情况。用SEM扫描电镜观察在不同水热条件下合成黄铁矿的形态及成分;用多晶X射线衍射仪(XRD)确定了产物物相组成;用透射电子显微镜(TEM)观测表征了黄铁矿晶体的形态和结构。结果表明：在200 ℃时黄铁矿为粒状,粒度较均匀,粒径1 μm左右。在180 ℃时黄铁矿除有尺寸在1 μm左右粒状黄铁矿外,还有不规则带状黄铁矿晶体,带宽为200 nm左右。认为水热条件中,随着结晶温度的逐步升高,黄铁矿的形貌逐步由不规则形状向规则形状的转变。所以在实验温度较高阶段,形成规则的粒状形貌;在低温阶段,则会出现不规则带状形貌。     

http://www.sciencedirect.com/science/article/pii/S167498711200151X

The unconformity surface at the bottom of the Paleogene is one of the most important migration pathways in the Sikeshu Sag of the Junggar Basin,which consists of three layers：upper coarse clastic rock,lower weathering crust and leached zone.The upper coarse clastic rock is characterized by higher density and lower SDT and gamma-ray logging parameters,while the lower weathering crust displays opposite features.The transport coefficient of the unconformity surface is controlled by its position in respect to the basal sandstone; it is higher in the ramp region but lower in the adjacent uplifted and sag areas.The content of saturated hydrocarbons increases with the decrease of the content of nonhydrocarbons and asphaltenes.The content of benzo[c] carbazole decreases as the content of benzo[a]carbazole and [alkyl carbazole]/[alkyl ＋ benzo carbazole] increases.This suggests that the unconformity surface is an efficient medium for the transportation of hydrocarbons.     

Deep-Seated Slope Failures Induced by Inappropriate Cutting in China

Given insufficient geological investigation and inadequate interpretation of geological settings, remedial works for localized cut slope collapses may induce large-scale failures and cause remarkable damage, as well as economical loss. A number of recent reports have addressed individual large-scale failures due to inappropriate cutting, but the systematic classification of failure patterns has received less attention. In this study, a re-profiling triggered landslide is described in detail. The deep slip surface is located by field measurements; then, the stability of the slope before and after cutting is assessed with the limit equilibrium method. Three types of slopes prone to deep-seated failures are introduced: the loose deposits type, the ancient landslide type, and the deep adverse discontinuities type. The mechanism of each failure pattern is illustrated with a case study. The stability analyses indicate that inappropriate slope profiling may greatly reduce the factor of safety (FS) of a slope. Recommendations are given for mitigating the deep-seated landslide induced by inappropriate cutting, and a case history of successful measures is presented.     

Experimental studies of groundwater pipe flow network characteristics in gravelly soil slopes

Piping flow networks have often been identified in hydrogeological field studies of gravelly soil slopes in the southern part of China. The present experimental studies have shown that under long-term groundwater seepage, piping flow networks gradually develop in the slope. Factors affecting the development of flow pipe seepage network included the grain size distribution, the degree of soil compaction, and soil depth. Piping seepage networks favorably form if the content of the gravel was high, the soil cohesion was low, the degree of the soil compaction was low, or the soil depth was shallow. Due to the enhanced permeability associated with the presence of flow pipe seepage network in gravelly soil slopes, groundwater can be effectively drained away. This can beneficially prevent the rise of groundwater level in the slope during raining seasons, hence reducing pore water pressure along the potential failure surface and increasing slope stability. Once the flow pipe seepage network was disturbed or damaged, the water level in the upper portion of the slope experienced a great rise, hence reducing the slope stability. Therefore, slope toe excavation and excessive loading at the slope crest should be avoided for slopes with well-developed flow pipe seepage network in order to preserve it.