Canadian Shield brine from the Con Mine, Yellowknife, NT, Canada: Noble gas evidence for an evaporated Palaeozoic seawater origin mixed with glacial meltwater and Holocene recharge

Dissolved noble gas concentrations were measured in high salinity (270 g/L) Ca(Na)-Cl groundwaters from the Con Mine, Yellowknife, Canada in an effort to discriminate between two possible origins, as either a brine generated by evaporative enrichment in a Paleozoic inland sea, or marine water concentrated by freezing during glacial times. Major ion and isotope geochemistry indicate that brines from the deepest level remain relatively undisturbed by mixing with modern water introduced by mining. Mixing calculations are used to quantify fractions of brine, glacial meltwater and modern water. From this, noble gas concentrations were corrected for excess air with Ne and normalized to 100% brine solution. Over-pressuring of helium and argon in the brine provide age constraints based on the accumulation of geogenic ⁴He and ⁴⁰Ar. Radiogenic age calculations together with the local geological history suggest brine emplacement during early Palaeozoic time, likely during the Devonian when evaporitic inland seas existed in this region. The concentrations of the atmospherically derived noble gases in the brine fraction (Kr = 1.4E-8, Xe = 8.5E-10 cc_STP/cc_H2O) are close to atmospheric equilibrium for brine at 25 °C (Kr = 7.3E-9, Xe = 8.0E-10 cc_STP/cc_H2O), but are far lower than would be expected for closed-system concentration of seawater by freezing (Kr = 2.8E-6, Xe = 4.2E-7 cc_STP/cc_H2O). Thus, despite the complicated mixing history of the brine, the atmospheric and geogenic noble gases provide strong evidence for an origin as air-equilibrated brine from evaporated Paleozoic seawater, which infiltrated via density displacement through existing fractures and faults into the Canadian Shield.     

Contamination level of mercury in red meat products from cetaceans available from South Korea markets

Levels of total mercury (T-Hg) were surveyed in red meat (n=73) and liver (n=3) from toothed whales, dolphins and porpoises (odontocetes) sold for human consumption in the coastal cities of South Korea. High concentrations of T-Hg were found in the liver products of finless porpoises (18.7 and 156 microg/wet g) and common dolphins (13.2 microg/wet g). The T-Hg concentrations in red meat products were highest in the false killer whale (9.66+/-12.3 microg/wet g, n=9), bottlenose dolphin (10.6+/-12.6 microg/wet g, n=3) and killer whale (13.3 microg/wet g, n=1), and lowest in Cuvier's beaked whale and the harbour porpoise (0.4-0.5 microg/wet g). Thus, most of the products that originated from odontocetes exceeded the safety limit of 0.5 microg/wet g for T-Hg set by the South Korean health authorities for the fishery industry. Pregnant women and other vulnerable sectors of the population living in South Korea should therefore limit their consumption of odontocete products.     

Impacts on agriculture following the 1991 eruption of Vulcan Hudson, Patagonia: lessons for recovery

Large explosive eruptions have the potential to distribute heavy ashfalls across large areas, resulting in physical and chemical impacts on agriculture, and economic and psycho-social impacts on rural communities. This study investigates how affected agriculture and rural communities have adapted, absorbed and mitigated impacts following a range of ashfall thicknesses (>2 m?C<1 mm) from the 12?C15 August 1991 eruption of Vulcan Hudson, one of the largest eruptions of the twentieth century. An estimated 1 million livestock died after the eruption due to pasture burial by ashfall and ongoing suppression of vegetation recovery. Horticulturalists suffered ongoing damage to crops from wind-blown ash and changes to soil properties increased irrigation and cultivation requirements. Real or perceived impacts on human health and impacts on farm productivity from the ashfall resulted in evacuation of farms and small towns in the short term. Long-term farm abandonment occurred in areas of heavy ashfall (upper Ibáñez valley) and highly stressed farming systems, even where ashfall was relatively thin (<50 mm), such as the Argentine steppe. The mono-agricultural system of sheep farming in the steppe region had few options other than destocking, proving less resilient than the diverse high-intensity horticultural and pastoral mix in irrigated valleys, which allowed more rapid adaption through diversification of production. Farms with natural advantages and greater investment in capital improvements led to greater damage potential initially (at least in cost terms), but ultimately provided a greater capacity for response and recovery. Better soils, climate and significantly greater access to technological improvements such as cultivation tools, irrigation and wind breaks were advantageous, such as at Chile Chico (Chile), Los Antiguos and Perito Moreno (Argentina). Cultivation increased chemical and physical soil fertility, especially when used in combination with fertilisation and irrigation. Appropriate use of seeds and cropping techniques within the new soil and growing conditions was important. Government agencies had a vital role in the dissemination of information for appropriate farm management responses, ash chemistry analysis, evacuations and welfare, and in the longer term to provide technical and credit assistance to facilitate recovery.     

Numerical simulations of the Lyman α forest – a comparison of gadget-2 and enzo

We compare simulations of the Lyman α forest performed with two different hydrodynamical codes, gadget-2 and enzo . A comparison of the dark matter power spectrum for simulations run with identical initial conditions show differences of 1–3 per cent at the scales relevant for quantitative studies of the Lyman α forest. This allows a meaningful comparison of the effect of the different implementations of the hydrodynamic part of the two codes. Using the same cooling and heating algorithm in both codes, the differences in the temperature and the density probability distribution function are of the order of 10 per cent. The differences are comparable to the effects of box size and resolution on these statistics. When self-converged results for each code are taken into account, the differences in the flux power spectrum – the statistics most widely used for estimating the matter power spectrum and cosmological parameters from Lyman α forest data – are about 5 per cent. This is again comparable to the effects of box size and resolution. Numerical uncertainties due to a particular implementation of solving the hydrodynamic or gravitational equations appear therefore to contribute only moderately to the error budget in estimates of the flux power spectrum from numerical simulations. We further find that the differences in the flux power spectrum for enzo simulations run with and without adaptive mesh refinement are also of the order of 5 per cent or smaller. The latter require 10 times less CPU time making the CPU time requirement similar to that of a version of gadget-2 that is optimized for Lyman α forest simulations.     

Contrasting punctuated zircon growth in two syn-erupted rhyolite magmas from Tarawera volcano: Insights to crystal diversity in magmatic systems

Two mineralogically and chemically distinct rhyolite magmas (T1 and T3) were syn-erupted from the same conduit system during the 21.9 ka basalt intrusion-triggered Okareka eruption from Tarawera volcano, New Zealand. High spatial resolution U–Th disequilibrium dating of zircon crystals at the ~ 3–5 μm scale reveals a protracted yet discontinuous zircon crystallization history within the magmatic system. Both magma types contain zircon whose interiors predate the eruption by up to 200 ka. The dominant age peak in the T1 magma is ~ 30 ka with subordinate peaks at ~ 45, ~ 75, and ~ 100 ka, whereas the T3 magma has a dominant zircon interior age peak at ~ 90 ka with smaller modes at ~ 35 and ~ 150 ka. These patterns are consistent with isolated pockets of crystallization throughout the evolution of the system. Crystal rim analyses yield ages ranging from within error of the eruption age to at least ~ 90 ka prior to eruption, highlighting that zircon crystallization frequently stalled long before the eruption. Continuous depth profiling from crystal rims inward demonstrates protracted growth histories for individual crystals (up to ~ 100 ka) that were punctuated by asynchronous hiatuses of up to 30 ka in duration. Disparate zircon growth histories can result from localized thermal perturbations caused by mafic intrusions into a silicic reservoir. The crystal age heterogeneity at hand-sample scale requires considerable crystal transport and mixing. We propose that crystal mixing was achieved through buoyancy instabilities caused by mafic magma flow through crystal mush. A terminal pre-eruptive rejuvenation event was capable of mobilizing voluminous melts that erupted, but was too short (< 10²–10³ years) to result in extensive zircon growth. The contrasting, punctuated zircon histories argue against closed-system fractional crystallization models for silicic magmatism that require protracted cooling times following a mostly liquid starting condition.     

A Test of Central Place Theory Using Shuttle Imaging Radar (SIR‐A) of China's North Central Plain

Abstract

This study utilizes radar imagery to test the application of Walter Christaller's central‐place theory on China's North Central Plain. Examination of the spatial order and layout of settlements reveal that central place theory's transportation principle, k=4 exists. The study distinguishes four hierarchical settlement sizes and shows how effective rural societies are in evolving settlement structures whose spatial order and regularity avoids spatial inefficiencies. The advent of space based imaging systems such as SIR‐A radar imagery has permitted tests of new sites where the restrictive conditions of central place theory exist. These studies allow parallels to be drawn between the postulates of this theory of settlement structure and whether the theory is matched in reality.

This work is needed because of such scarcities. It allows the theory to undergo further subjections, a scrutiny needed for the validation, or otherwise of its postulates. The work adds to a large body of literature on this topic whose limitation has been the scarcity of actual test sites where theory and reality can be compared. The study presents positive indications that central place theory exists in reality, a compliment to the remarkable perceptions of Walter Christaller.     

A plutonic brother from another magma mother: Disproving the Eocene Foraker‐McGonagall pluton piercing point and implications for long‐term slip on the Denali Fault

The Denali Fault is an active strike‐slip fault system responsible for the highest topography in North America, yet there are conflicting constraints on the fault's Cenozoic slip history. The long‐term slip rate constraint of the eastern Denali Fault is ~400 km since 57 Ma. In apparent conflict, the long‐term slip rate of the western Denali Fault is 38 km since 38 Ma based on the reconstruction of the Foraker and McGonagall plutons. Tests of the genetic relationship of the plutons with bulk rock geochemical and paired U‐Pb and Hf zircon analysis suggest a disparate origin. The McGonagall pluton, despite having a lower SiO₂, has lower ε_Hf values inconsistent with chemical and isotopic variations between the two being the result of contamination. The Denali Fault is a highly strain partitioned system, but the amount of Cenozoic slip dispersed east to west is likely significantly less than the previous ~360 km constraint.     

Andesitic Plinian eruptions at Mt. Ruapehu: quantifying the uppermost limits of eruptive parameters

New tephro-stratigraphic studies of the Tongariro Volcanic Centre (TgVC) on the North Island (New Zealand) allowed reconstruction of some of the largest, andesitic, explosive eruptions of Mt. Ruapehu. Large eruptions were common in the Late Pleistocene, before a transition to strombolian-vulcanian and phreatomagmatic eruptive styles that have predominated over the past 10,000?years. Considering this is the most active volcano in North Island of New Zealand and the uppermost hazard limits are unknown, we identified and mapped the pyroclastic deposits corresponding to the five largest eruptions since ~27?ka. The selected eruptive units are also characterised by distinctive lithofacies associations correlated to different behaviours of the eruptive column. In addition, we clarify the source of the ~10–9.7?ka Pahoka Tephra, identified by previous authors as the product of one of the largest eruptions of the TgVC. The most common explosive eruptions taking place between ~13.6 and ~10?ka?cal?years BP involved strongly oscillating, partially collapsing eruptive columns up to 37?km high, at mass discharge rates up to 6?×?10⁸?kg/s and magnitudes of 4.9, ejecting minimum estimated volumes of 0.6?km³. Our results indicate that this volcano (as well as the neighbouring andesitic Mt. Tongariro) can generate Plinian eruptions similar in magnitude to the Chaitén 2008 and Askja 1875 events. Such eruptions would mainly produce pyroclastic fallout covering a minimum area of 1,700?km² ESE of the volcano, where important touristic, agricultural and military activities are based. As for the 1995/1996 eruption, our field data indicate that complex wind patterns were critical in controlling the dispersion of the eruptive clouds, developing sheared, commonly bilobate plumes.