Geochemical modeling,fate distribution,and risk exposure of potentially toxic metals in the surface sediment of the Shyok suture zone,northern Pakistan

The objective of the current study was to assess the contamination of potentially toxic metals (PTMs) in weathered surface sediment, along stream tributaries, and surrounding area of the river Chitral, Shyok suture zone district Chitral, Pakistan. To understand the geochemical features of 113 sediment, samples were collected from the Mirkhani and Drosh area. Then, different statistical tools including the geo-accumulation index (Igeo), cluster analysis (CA), principal component analysis (PCA), and ecological risk assessment (ERA) were used to unravel the origin, intensity, and exposure level of PTMs to control risk and restore the ecosystem within the study area. The results for the PTMs namely nickle (Ni), chromium (Cr), copper (Cu), cadmium (Cd), lead (Pb), zinc (Zn), and cobalt (Co) in Mirkhani and Drosh were in the following ranges: 10–150, 15–210, 15–250, 0.08–1.00, 10–70, 76–240 and 14–51; and 13–240, 17–210, 15–150, 0.08–0.60, 7–140, 47–150 and 13–36 mg/kg, respectively. In consequence, the potential ecological risk caused by Pb, Ni, Cu, Co, Cr, and Zn is reflected by the percentages of samples with an ecological risk index (ERI) greater than one which were 100%, 91%, 100%, 100%, 92%, and 100%, respectively. However, the overall mean decreasing order of ecological risk of PTMs in the district Chitral was Pb > Ni > Cu > Co > Cr > Zn > Cd. Moreover, the PCA yielded 78% variability which indicated that mineral prospects play an important role in the contamination of sediment. Furthermore, the mineral phases of Pb and Zn suggested supersaturation, while that for Cd revealed unsaturation. The results of Igeo, ERI, and CA indicated contamination of PTMs in the study area. The ERI value of Pb, Ni, Cu, Co, Cr, and Zn was higher than 1 suggesting an ecological risk in the study area. Moreover, the current study showed the dominance of geogenic contamination with major contributions from ultramafic rock and known mineral prospects. Therefore, contaminated sediment of the Shyok suture zone is extremely detrimental to the aquatic ecosystem of the study area.     

The structure and dynamics of young star clusters: King 16, NGC 1931, NGC 637 and NGC 189

In this paper, using 2MASS photometry, we study the structural and dynamical properties of four young star clusters viz. King 16, NGC 1931, NGC 637 and NGC 189. For the clusters King 16, NGC 1931, NGC 637 and NGC 189, we obtain the limiting radii of 7′, 12′, 6′ and 5′ which correspond to linear radii of 3.6 pc, 8.85 pc, 3.96 pc and 2.8 pc respectively. The reddening values E(B?V) obtained for the clusters are 0.85, 0.65–0.85, 0.6 and 0.53 and their true distances are 1786 pc, 3062 pc, 2270 pc and 912 pc respectively. Ages of the clusters are 6 Myr, 4 Myr, 4 Myr and 10 Myr respectively. We compare their structures, luminosity functions and mass functions (φ(M)=dN/dM ∝ M ^?(1+χ)) to the parameter τ=t _age /t _relax to study the star formation process and the dynamical evolution of these clusters. We find that, for our sample, mass seggregation is observed in clusters or their cores only when the ages of the clusters are comparable to their relaxation times (τ≥1). These results suggest mass seggregation due to dynamical effects. The values of χ, which characterize the overall mass functions for the clusters are 0.96±0.11, 1.16±0.18, 0.55±0.14 and 0.66±0.31 respectively. The change in χ as a function of radius is a good indicator of the dynamical state of clusters.     

Building the Hindu Kush: monazite records of terrane accretion,plutonism and the evolution of the Himalaya–Karakoram–Tibet orogen

In situ U‐Th/Pb (LA‐ICP‐MS) monazite ages from the Hindu Kush of NW Pakistan provide new petrochronologic constraints on the tectonic evolution of the Himalaya–Karakoram–Tibet orogen. Monazites from two adjacent garnet + staurolite schist specimens yield multiple age populations that record the major Mesozoic and Cenozoic deformational, magmatic and metamorphic events along the southern margin of Eurasia. These include the accretion of the Hindu Kush–SW Pamir to Eurasia during the Late Triassic, followed by the accretion of the Karakoram terrane in the Early Jurassic. Younger Jurassic and Cretaceous ages record the development of an Andean‐style volcanic arc along the southern Eurasian margin, which ended with the docking of the Kohistan island arc and the emplacement of the Kohistan–Ladakh batholith during the Late Cretaceous. The initial Eocene collision of India with Eurasia was followed by widespread high‐temperature metamorphism and anatexis associated with crustal thickening within the Himalaya system in the Late Oligocene and Early Miocene.     

Integration of Cluster Analysis and Rock Physics for the Identification of Potential Hydrocarbon Reservoir

Natural Resources Research - Rock physics has proven its credibility for the quantitative seismic interpretation of reservoir and reservoir characterization. In this study, we implemented K-means...     

Continuous process study on simultaneous nitrification–denitrification of high ammoniacal nitrogen load wastewater in aerobic–anoxic sequencing bioreactors

The study focused on the feasibility of high NH₄ ⁺–N (400–600 mg/L) and COD load at two different hydraulic retention times (HRTs = 36 and 24 h) in two identical aerobic–anoxic sequencing bioreactors which were constructed in series in a single system using a specifically designed single biomass containing autotrophic nitrifying and heterotrophic denitrifying bacteria. Internal recirculation of synthetic wastewater from one tank to other was not carried out like the conventional aerobic–anoxic processes. Cycles of 15 days under sequences of aerated and non-aerated periods of three hour each were repeated during each continuous flow experiment conducted. Sodium bicarbonate and sodium acetate were selected as the appropriate inorganic and organic carbon sources. The results showed that the HRT may not affect the simultaneous nitrification and denitrification processes. Average nitrification ratio was obtained to be above 20 mg/L NH₄ ⁺–N/h daily. Results of 90 days’ operation also showed high removal efficiencies of ammoniacal nitrogen of about 83% daily. The main advantage of this process includes efficient ammoniacal nitrogen removal without separated aerobic and anoxic tanks, decrease operating costs due to the lesser oxygen concentration requirement in the bioreactors.     

Agrobiodiversity of Muda Rice Agroecosystem:A case Study in Largest Granary Area of Malaysia

A survey was carried out at the largest rice cultivation area in Peninsular Malaysia,the Muda rice agroecosystem.The main objective of this study was to document the overall biodiversity associated with this unique agroecosystem by using a combination of sampling techniques in order to record different groups of fauna and flora.The total number of biota recorded and identified from the rice field ecosystem during the study period consisted of 46 species of zooplankton,81 species of aquatic insects,5 species of rodents,7 species of bats,87 species of birds,11 species of fishes and 58 species of weeds.A long-term study should be carried out as more species are expected to be recorded when more of the Muda rice agroecosystem area has been sampled to obtain sufficient information on the Muda rice agrobiodiversity.     

Evaluation of Bioavailability and Partitioning of Aluminum in Sediment Samples of Different Ecosystems by Modified Sequential Extraction Methods

Sequential extraction procedures are widely used to characterize the different operational fractions with different potential toxicity of metals in environmental solid samples. The present work describes the application of different analytical approaches for sequential extraction of aluminum to evaluate its mobility, availability, and persistent chemical forms in sediment samples of different fresh water ecosystems (lake, canal, and river). The conventional BCR three‐stage sequential extraction procedure (C‐BCR) was modified at each stage, by applying ultrasonic device (U‐BCR), in order to shorten the required shaking time of 16 h for each three steps (excluding the hydrogen peroxide digestion in step 3, which was not performed with ultrasonic bath), could be completed in 40, 50, and 45 min, respectively. The aluminum in all extracts were determination by atomic absorption spectrometry using nitrous oxide – acetylene flame. The accuracy of results obtained from C‐BCR and proposed U‐BCR was verified with literature reported values of certified sediment sample (BCR 701). The overall recoveries of aluminum obtained by proposed U‐BCR were found in the range of 96.7–113% of those values obtained with C‐BCR for all fractions. Use of ultrasonic device, provided a large saving in extraction time relative to conventional shaking. It was observed that major part of Al in real sediment samples (80–83% of total Al) were bound to residual fraction. The acid soluble fraction of aluminum extracted by 0.11 mol/L CH₃COOH has good correlation with aluminum content in corresponding water samples of each ecosystem.