A new type of noble metal mineralization in the Northern Caucasus

The weathering crust of the Beden ultrabasite massif (the basin of Big Laba River) is identified and studied. Anomalously high contents of noble metals (Au, Pt, Pd) are revealed in the basal horizon of the Jurassic part of the weathering crust. For this reason we suspect an existence of a belt of noble metal miner-alization in the Paleozoic ultrabasites in the Peredovoi Range of the Northern Caucasus.     

A GIS-index integration approach to groundwater suitability zoning for irrigation purposes

In recent decades, the high population growth has increased the demand for agricultural lands and products. Groundwater offers reliability and flexibility in access to water for irrigation purposes, especially in arid and semi-arid areas, such as Amol-Babol Plain, Iran. However, the quality and quantity of groundwater may not be suitable for irrigation purposes in all areas due to urbanizations, and intensive agricultural and industrial activities. Groundwater suitability zoning for irrigation purposes could be useful to improve water resources and land use planning, mostly in areas with water scarcity. Therefore, a GIS-based indices method is proposed to assess suitable zones for agricultural activities, integrating the irrigation water quality (IWQ) index and hydrogeological factors. IWQ index was utilized to assess groundwater quality based on salinity hazard, infiltration hazard, specific ions, and trace elements hazards, and miscellaneous effects such as pH, bicarbonate, and nitrate. The potential of the aquifer for irrigation water abstraction was investigated using hydrogeological surveys such as slope angle of the plain, hydraulic conductivity, and aquifer thickness. The groundwater suitability index classified most of the study area (more than 90 %) as “excellent” or “good” suitability zones for irrigation purposes. A limited area of around 5.6 % of the total area has moderate suitability for irrigation purposes due to the Caspian Seawater intrusion and the presence of fossil saline water. The proposed methodology provides useful information in order to allow irrigation management to prevent water and soil deterioration.     

Facies analysis and sequence stratigraphy of Kometan Formation (Upper Cretaceous) in the imbricated zone,northeastern Iraq

Facies and sequence stratigraphic analysis of the Kometan Formation (Upper Cretaceous) were studied from Kometan village, Kurdistan region of northeastern Iraq. Lithologically, the formation consists of 44 m of white weathering, light grey, thin to medium-bedded highly fractured limestones with chert nodules. Petrographic study of the carbonates shows that both skeletal and non-skeletal grains were present. The skeletal grains include a variety of planktonic foraminifera (including Oligostegina), calcispheres, ostracods, pelecypods, larva ammonite, and echinoderms. Non-skeletal grains include peloids only. Three main microfacies types are distinguished in the studied formation. The results of stable carbon and oxygen isotopes of the studied carbonate samples show negative values of δ¹⁸O. These indicate that the seawater was warm with low salinity during precipitation of the carbonates in the Kometan Formation in northeastern Iraq. The positive δ¹³C values of carbonate samples, in the middle part of the formation, reflect the widespread deposition of organic-rich marine sediments during a transgression and deepening of the basin. Petrographic, facies and stable isotopic analyses revealed that the Kometan Formation was deposited in a warm, basinal, pelagic (open marine) environment with low salinity. The Kometan Formation consists of one complete third-order depositional sequence, separated by a sequence boundary (SB) of type 2. The third-order sequence is subdivided into a transgressive systems tract (TST) and highstand systems tract (HST). This reflects episodes of transgression and still stands of the relative sea level. The TSTs are topped by maximum flooding surface (MFS) characterized by deepening-/fining-upward parasequences implying a retrogradational stacking pattern. The HST is marked by shallowing-/coarsening-upward parasequences implying a progradational stacking pattern.     

Scanning electron microscopy and Raman spectroscopy as combined methods for studying zoning in minerals: The case of spinels from Archean komatiites

Several types of both magmatic and metamorphic spinels have been found in Archean komatiites of the Sovdozero and Kostomuksha greenstone belts in the eastern part of the Fennoscandian Shield. Scanning electron microscopy and Raman spectroscopy revealed relics of cores of primary magmatic chrome-spinels with high Cr and Al contents. In the Sovdozero structure, the relics are better retained than those in the Kostomuksha structure, which is caused by a different degree of metamorphic transformation. The comparable 100 · Cr/(Al + Cr) values of spinel cores from Sovdozero and Kostomuksha reflect similar conditions of partitional melting in the mantle. These data agree with the fact that both komatiite complexes belong to the Al-undepleted petrogenic type. Wide variations in the Cr and Al contents in primary chrome-spinel cores together with a constant Mg/(Fe²⁺ + Mg) ratio correspond to low oxygen fugacity during magma crystallization. In general, the composition of these primary chrome-spinels is similar to that of accessory phases in peridotites from suprasubduction zones and agrees with hypothesis of komatiite complex formation in back-arc basins.     

Pb isotope composition of granitoids from the Hercynides of the Central Asian orogenic Belt: Evidence for growth of the juvenile crust

Based on study of the Middle Paleozoic (Hercynian) structures of the Central Asian Fold Belt located in Southwest Mongolia, the problem of the sources of juvenile crust growth registered in the Pb isotope composition of postaccretional granitoids is considered. Our study shows that the Pb isotope system of Late Paleozoic granitoids from the Hercynides of the Central Asian Fold Belt provides evidence for the juvenile nature of the continental crust in this region. The evolution of the Pb isotope composition in the Hercynides of Mongolia corresponds to the model parameter μ = 9.25, according to the Stacey–Kramers twostage model. The juvenile source of the Hercynian crust should be characterized by a lower μ value. In addition, according to the Stacey–Kramers two-stage model, the Th/U value in this crust is 3.58.     

Geochemical features of the utilization of buried wastes of the Tyrnyauz Tungsten–Molybdenum Plant using acid leaching

The decontamination of buried wastes of the Tyrnyauz Tungsten–Molybdenum Plant is complicated by the geochemical features of the waste composition: low sulfide and high carbonate content, polyelemental composition, and considerable amounts of technogenic admixtures (kerosene, oils, soda, and soluble glasses). These circumstances result in sufficient complication of the suggested technology of waste treatment, including the sulfuric-acid leaching and separate sorption recovery of hazardous and useful elements from the working solution.     

Coesite inclusions in diamonds of Yakutia

The results of the study of diamonds with inclusions of high-pressure modification of SiO₂ (coesite) by Raman spectroscopy are reported. It is established that the octahedral crystal from the Zapolyarnaya pipe is characterized by the highest residual pressure (2.7 ± 0.07 GPa). An intermediate value of this parameter (2.1 ± 0.07 GPa) was obtained for a crystal of transitional habit from the Maiskaya pipe. The minimal Raman shift was registered for coesite in diamond from the Komsomol’skaya–Magnitnaya pipe and provided a calculated residual pressure of 1.8 ± 0.03 GPa. The residual pressures for crystals from the placer deposits of the Kuoika and Bol’shaya Kuonamka rivers are 2.7 ± 0.07 and 3.1 ± 0.1 GPa, respectively. Octahedral crystals were formed in the mantle at a higher pressure than rhombododecahedral diamonds.