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141.
142.
The membrane interface probe (MIP) is widely used to characterize the subsurface distribution of volatile organic compounds (VOCs). One problem that arises during MIP application is that disproportionately high MIP signals are obtained after passing source zones which contain mobile or residual phases. This serious problem occurs because of a carry-over effect, in particular caused by compound-specific retention times in the conventional unheated transfer line, commonly used during such an investigation. The objective of this study was to perform a qualitative methodical field evaluation of the carry-over effect of a conventional MIP system with a conventional unheated transfer line. This was achieved by coupling a mobile mass spectrometer to the MIP device. Results obtained were then further compared with those achieved using a laser induced fluorescence (LIF) system. Because of this coupling, time- and depth-dependent signals for different substances became known. Field evaluation data obtained showed complex superpositions of compounds with MIP system results. As a result of this superposition, MIP signals from the saturated zone beneath the source zone (zone with free and/or residual phase) are blurred and are therefore not representative of particular depths. However, utilizing multidirectional probing alongside conventional MIP probing (forwards and backwards), it was possible to detect the upper and lower phase boundary of the source zone. These MIP results correlated excellently with the LIF results. An important conclusion that can be drawn from the field investigation is that coupling a mobile mass spectrometer to the MIP system enables advanced MIP signal interpretation to be successfully achieved. 相似文献
143.
Global set of trajectories of satellite-tracked Lagrangian drifters is used to study the dynamics of marine debris. A probabilistic model is developed to eliminate the bias in spatial distribution of drifter data due to heterogeneous deployments. Model experiments, simulating long-term evolution of initially homogeneous drifter array, reveal five main sites of drifter aggregation, located in the subtropics and maintained by converging Ekman currents. The paper characterizes the geography and structure of the collection regions and discusses factors that determine their dynamics. A new scale R(c)=(4k/|D|)(?) is introduced to characterize tracer distribution under competing effects of horizontal divergence D and diffusion k. Existence and locations of all five accumulation zones have been recently confirmed by direct measurements of microplastic at the sea surface. 相似文献
144.
145.
An elasto-plastic constitutive model is introduced for rock joints under cyclic loading, considering the additional shear resistance generated by the asperity damage in the first forward shear cycle and sliding mechanism for further shearing. A series of cyclic loading direct shear tests was conducted on artificial joints with triangular asperities and replicas of a real rock asperity surface under constant normal stiffness (CNS) conditions. The model was calibrated and then validated using selected data sets from the experimental results. Model simulations were found to be in good agreement with the rock joints behaviour under cyclic loading and CNS conditions both in stress prediction and dilation behaviour. In addition, dynamic stability analysis of an underground structure was carried out, using Universal Distinct Element Code and the proposed constitutive model. 相似文献
146.
Laser ablation multi-collector-inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS) has become a valuable tool for the in situ measurement of the boron isotope composition of geological samples at high (tens to hundreds of μm) spatial resolution. That said, this application suffers from significant analytical challenges. We focus in this study on the underlying processes of two of the main causes for inaccuracies using this technique. We provide empirical evidence that not only Ca ions (Sadekov et al. 2019, Standish et al. 2019, Evans et al. 2021) but also Ar ions, that are reflected within the flight tube of the mass spectrometer, are the source for previously reported issues with spectral baselines. We also address the impact of plasma conditions on the instrumental mass fractionation as a source for matrix- and mass-load-related analytical biases. Comparing experimental data with the results of a dedicated release and diffusion model (RDM) we estimate that a close to complete (~ 97%) release of boron from the sample aerosol is needed to allow for consistently accurate LA boron isotope measurement results without the need for corrections. 相似文献
147.
The asymptotic distribution of the coefficient of cross-association between two sequences of nominal data is investigated under the assumption of independent random sampling from a multinomial distribution slightly modified to suit geological applications. This modification is due to merging consecutive strata of the same rock type into one lithological unit, and can be described by a simple Markov chain. A distinction is made between the case in which the theoretical frequencies are known, and the situation where these have to be estimated from the observed data. 相似文献
148.
Richard T. Jones Jim D. Marshall Stephen F. Crowley Alan Bedford Nigel Richardson Jan Bloemendal Frank Oldfield 《第四纪科学杂志》2002,17(4):329-340
A lacustrine carbonate sequence from Hawes Water, Lancashire, UK, has been studied using stable isotopic, lithological, pollen and mineral magnetic analysis. The data reveal four abrupt climatic oscillations in the Late‐glacial Interstadial leading up to the onset of the Loch Lomond Stadial. The data also point to climatic warming relatively early within the stadial, ca. 12 500 GRIP yr, prior to the onset of the Holocene. The oxygen isotope record is taken as a signature of climate forcing against which the response of the lake‐system can be monitored. By adopting this approach it is revealed that the response of the biological system to the rapid climatic oscillations is non‐linear and primarily a function of the antecedent conditions. A significant end‐Devensian isotopic excursion (A) is matched by only minor changes in the cold‐adapted floras and faunas. During the warmer interstadial, the response of the biological ecosystem (events B–D) is clearly influenced by thresholds: major changes in the catchment vegetation associated with relatively minor oscillations in the isotopic signature. The stratigraphical patterns reveal significant lag effects between the onset of climate deterioration and resulting changes in vegetation. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
149.
150.
The contributions of any arbitrary photospheric velocity field to (macroturbulent) line displacement, and to (microturbulent) line broadening can be expressed by the macro- and micro-turbulent filters f
M
(k) and f
t(k), where k is the wavenumber of the energy spectrum in which the line-of-sight component of the velocity field can be decomposed. As a correction to a previous computation of f
M
and f
t
we give in this Note improved values for the filter functions for weak lines in LTE. An example of the way to use the filter functions is given. 相似文献