Biofiltration of Hexane Vapor: Experimental and Neural Model Analysis

Biofiltration is a commonly practiced biological technique to remove volatile compounds from waste gas streams. From an industrial view‐point, biofilter (BF) operation should be flexible to handle temperatures and inlet load (IL) variations. A compost BF was operated at different temperatures (30–45°C) and at various inlet loading rates (ILR; 8–598 g m^?3 h^?1) under intermittent loading conditions. Complete removal of n‐hexane was observed at 30 and 35°C at ILRs up to 330 g m^?3 h^?1. Besides, 20–75% of the pollutant was removed at 40°C, corresponding to the different ILs applied to the BF. Increasing the temperature to 45°C decreased the removal efficiency (RE) significantly. A feed forward neural network was used to predict the RE of BF with temperature and ILR as the input variables. The experimental data was divided into training (2/3) and test datasets (1/3). The best structure of neural network was obtained by trial and error on the basis of the least differences between predicted and experimental values, as ascertained from their coefficient of regression (R²) values. The modeling results showed that a multilayer network with the topology 2?10?1 was able to predict BF performance effectively with R²‐value of 0.995 for the test data. The results from this study showed the predicting capability of ANNs which can be considered as an alternative for conventional knowledge‐based models.     

Mixed model for interoccurrence times of earthquakes based on the expectation-maximization algorithm

In this paper, the goodness-of-fit test based on a convex combination of Akaike and Bayesian information criteria is used to explain the features of interoccurrence times of earthquakes. By analyzing the seismic catalog of Iran for different tectonic settings, we have found that the probability distributions of time intervals between successive earthquakes can be described by the generalized normal distribution. This indicates that the sequence of successive earthquakes is not a Poisson process. It is found that by decreasing the threshold magnitude, the interoccurrence time distribution changes from the generalized normal distribution to the gamma distribution in some seismotectonic regions. As a new insight, the probability distribution of time intervals between earthquakes is described as a mixture distribution via the expectation-maximization algorithm.     

Ascribing soil erosion types for sediment yield using composite fingerprinting technique

Abstract

Soil erosion and eroded sediment are serious threats to sound land management. However, less attention has been given to quantifying the importance of different soil erosion features based on appropriate control measures that could be designated. Accordingly, this research was planned to quantify the contribution of potential sediment sources, i.e. sheet, rill and gully erosion, in Idelo watershed in Zanjan Province, Iran, using composite fingerprinting. Toward this aim, 16 geochemical and organic tracers were detected in sediment sources and sediment deposited at the outlet. The results of applying the composite fingerprinting technique, with a relative error of 16%, showed that sheet, rill and gully sources contributed 56%, 44% and 0%, respectively, to sediment yield. It was also apparent from the results that the composite fingerprinting approach could be successfully utilized to assess the provenance of sediment deposited at the main outlet of the study watershed by soil erosion type.

Editor Z.W. Kundzewicz     

The western Durkan Complex (Makran Accretionary Prism,SE Iran): A Late Cretaceous tectonically disrupted seamounts chain and its role in controlling deformation style

The Durkan Complex is a key tectonic element of the Makran accretionary prism (SE Iran) and it has been interpreted as representing a continental margin succession. We present here a multidisciplinary study of the western Durkan Complex, which is based on new geological, stratigraphic, biostratigraphic data, as well as geochemical data of the volcanic and meta-volcanic rocks forming this complex. Our data show that this complex consists of distinct tectonic slices showing both non-metamorphic and very low-grade metamorphic deformed successions. Stratigraphic and biostratigraphic data allow us to recognize three types of successions. Type-I is composed by a Coniacian – early Campanian pelagic succession with intercalation of pillow lavas and minor volcaniclastic rocks. Type-II succession includes a volcanic sequence passing to a volcano-sedimentary sequence with Cenomanian pelagic limestones, followed by a hemipelagic sequence. This succession is characterized by abundant mass-transport deposits. Type-III succession includes volcanic and volcano-sedimentary sequences, which are stratigraphically covered by a Cenomanian platform succession. The latter is locally followed by a hemipelagic sequence. The volcanic rocks in the different successions show alkaline geochemical affinity, suggesting an origin from an oceanic within-plate setting. Our new results indicate that the western Durkan Complex represents fragments of seamounts tectonically incorporated in the Makran accretionary wedge during the latest Late Cretaceous–Paleocene. We propose that incorporation of seamounts in the frontal prism caused a shortening of the whole convergent margin and possibly contributed to controlling the deformation style in the Makran Accretionary Wedge during Late Cretaceous–Paleocene times.     

Leaching of an oxide gold ore with chloride/hypochlorite solutions

An oxide gold ore was subjected to chloride/hypochlorite leaching at room temperature. The effects of three factors, including Ca(OCl)₂ vs. NaOCl, OCl⁻ concentration, and HCl concentration on gold leaching performance were investigated. Due to formation of CaOCl⁺ complex in solution and hence less reactivity, calcium hypochlorite produces a sluggish gold leaching kinetics, taking twice the time (46 h) to achieve maximum gold recovery of 58% compared to sodium hypochlorite. 10 g/L of total initial hypochlorite species in solution produces reasonable gold recoveries. The amount of added HCl and hence the initial pH was found to have a major effect on gold leaching kinetics and maximum gold recovery. A high level of 9 g/L of added HCl causes HClO to be very reactive, producing very fast kinetics, reaching 67% gold extraction in 4 h. It also causes a faster consumption of hypochlorous acid, through catalytic decomposition (by NiO and CuO) and disproportionation. Hypochlorous acid reactions with sulfide and ferrous content of ore proceed very slowly in the pH range of 4–11. Gold–chloro complexes are strongly adsorbed on quartz component of ore. To minimize this undesirable adsorption of gold–chloro species, the aging time must be limited to a few hours only.     

Forced vertical and horizontal movements of a rectangular rigid foundation on a transversely isotropic half‐space

An analytical investigation of a half‐space containing transversely isotropic material under forced vertical and horizontal displacements applied on a rectangular rigid foundation is presented in this paper. With the goal of a rigorous solution to the shape‐ and rigidity‐ induced singular mixed boundary value problem, the formulation employs scalar potential representation, the Fourier expansion and the Hankel integral transforms method to obtain the surface arbitrary point‐load solution in cylindrical coordinate system. The obtained Green's functions are rewritten in rectangular coordinate system, allowing the response of the half‐space because of an arbitrary distributed load on a rectangular surface area be given in terms of a double integral. The numerical evaluations of stresses are done with the use of an element, which is singular at the edge and the corner of the rectangle. Upon the imposition of the rigidity displacement boundary condition for a rigid foundation and the use of a set of two‐dimensional adaptive‐gradient elements, which can capture the singular behavior in the contact stress effectively, a set of new numerical results are presented to illustrate the effect of transverse isotropy on the foundation response. Copyright © 2012 John Wiley & Sons, Ltd.     

Investigation of RS and GIS techniques on MPSIAC model to estimate soil erosion

Soil erosion due to surface water is a standout among the serious threat land degradation problem and an hazard environmental destruction. The first stage for every kind of soil conservation planning is recognition of soil erosion status. In this research, the usability of two new techniques remote sensing and geographical information system was assessed to estimate the average annual specific sediments production and the intensity erosion map at two sub-basins of DEZ watershed, southwest of Lorestan Province, Iran, namely Absorkh and Keshvar sub-basins with 19,920 ha, using Modified Pacific Southwest Inter-Agency Committee (MPSIAC) soil erosion model. At the stage of imagery data processing of IRS-P6 satellite, the result showed that an overall accuracy and kappa coefficient were 90.3% and 0.901, respectively, which were considered acceptable or good for imagery data. According to our investigation, the study area can be categorized into three level of severity of erosion: moderate, high, and very high erosion zones. The amount of specific sediments and soil erosion predicted by MPSIAC model was 1374.656 and 2396.574 m³ km^?2 year^?1, respectively. The areas situated at the center and south parts of the watershed were subjected to significant erosion because of the geology formation and ground cover, while the area at the north parts was relatively less eroded due to intensive land cover. Based on effective of nine factors, the driving factors from high to low impact included: Topography > Land use > Upland erosion > Channel erosion > Climate > Ground cover > Soil > Runoff > Surface geology. The measured sediment yield of the watershed in the hydrometric station (Keshvar station) was approximately 2223.178 m³ km^?2 year^?1 and comparison of the amount of total sediment yield predicted by model with the measured sediment yield indicated that the MPSIAC model 38% underestimated the observed value of the watershed.     

Seismicity Characterization of Iran: A Multivariate Statistical Approach

This paper presents the results of two multivariate analysis techniques—principal component and cluster analysis—as they are applied to the seismicity characterization of Iran. The seismic data used in this study covers a period of 50 years, from the beginning of 1957 to the end of 2006. The values of eight seismic variables were calculated on a grid of equally spaced points at one geographic degree spacing in both latitude and longitude. The data matrix was analyzed using principal component and cluster analysis. Principal component analysis identified two significant components, introduced in this study as the Seismic Frequency Index (SFI) and the Seismic Severity Index (SSI), responsible for the data structure. The SFI and SSI explain 34.34 % and 32.33 % of the total variance of the data set, respectively, and allowed grouping of the selected variables according to their common features. The standardized data matrix was analyzed using Ward’s clustering method. The resulting seismicity pattern recognition maps of the region at three levels of similarity are presented. From these maps, differentiated seismic zones are outlined in detail and compared quantitatively. Comparison between the seismic zoning maps obtained in this analysis and the general tectonic map of the region indicates that the seismic zones are consistent with the tectonic zones of the region. This study presents the necessity and usefulness of multivariate analysis in evaluating and interpreting seismic data catalogues with the goal of obtaining more objective information about the seismicity pattern of regions.     

Distinct element simulation of ultimate bearing capacity in jointed rock foundations

In this paper, distinct element method numerical modeling is applied to evaluate bearing capacity of strip footing rested on anisotropic discontinuous rock mass. As yet, a little work has been carried out to investigate the effect of joint set orientation on the bearing capacity of rock mass. Generally, the overall behavior of rock mass under loading is very complicated and such analysis should include deformation determination, sliding along discontinuities and failure of rock material. Failure mechanism of rock mass depended on both geometrical parameters of joint sets and strength parameters of rock mass. In this research, it is assumed that rock mass contains one joint set, and therefore the anisotropy in bearing capacity and rock behavior is only due to the existence and orientation of the joint set. In this study, by assuming constant strength parameters and using Mohr–Coulomb failure criterion for the single joint set and nonlinear Hoek–Brown failure criterion for rock material, variation of the bearing capacity values and the type of failure mechanism of rock mass with different joint set dips is investigated. The obtained results indicate that the ultimate bearing capacity of rock mass containing one joint set varies between 27 and 86 % of intact rock.