Diffuse and concentrated recharge evaluation using physical and tracer techniques: results from a semiarid carbonate massif aquifer in southeastern Spain

In the high-permeability, semiarid carbonate aquifer in the Sierra de Gádor Mountains (southeastern Spain), some local springs draining shallow perched aquifers were of assistance in assessing applicability of the atmospheric chloride mass balance (CMB) for quantifying total yearly recharge (R _T) by rainfall. Two contrasting hydrological years (October through September) were selected to evaluate the influence of climate on recharge: the average rainfall year 2003–2004, and the unusually dry 2004–2005. Results at small catchment scale were calibrated with estimated daily stand-scale R _T obtained by means of a soil water balance (SWB) of rainfall, using the actual evapotranspiration measured by the eddy covariance (EC) technique. R _T ranged from 0.35 to 0.40 of rainfall in the year, with less than a 5% difference between the CMB and SWB methods in 2003–2004. R _T varied from less than 0.05 of rainfall at mid-elevation to 0.20 at high elevation in 2004–2005, with a similar difference between the methods. Diffuse recharge (R _D) by rainfall was quantified from daily soil water content field data to split R _T into R _D and the expected concentrated recharge (R _C) at catchment scale in both hydrological years. R _D was 0.16 of rainfall in 2003–2004 and 0.01 in 2004–2005. Under common 1- to 3-day rainfall events, the hydraulic effect of R _D is delayed from 1 day to 1 week, while R _C is not delayed. This study shows that the CMB method is a suitable tool for yearly values complementing and extending the more widely used SWB in ungauged mountain carbonate aquifers with negligible runoff. The slight difference between R _T rates at small catchment and stand scales enables results to be validated and provides new estimates to parameterize R _T with rainfall depth after checking the weight of diffuse and concentrated mechanisms on R _T during moderate rainfall periods and episodes of marked climatic aridity.     

Hazard assessment at San Martín volcano based on geological record, numerical modeling, and spatial analysis

The San Martín shield volcano, located in the Los Tuxtlas Volcanic Field, has experienced effusive shield-building activity, as well as explosive eruptions, as evidenced by direct observations during the last eruption in 1793. The threat to the surrounding villages consists principally of lahars, especially because of the tropical climate in the region. Ash fallout and lava flows represent additional hazards. In addition, the surrounding Quaternary monogenetic field includes more than 300 scoria cones and about 40 explosion craters (mainly maars) that also represent a hazard source. In the present study we constructed hazard maps using field data, orthophotos, spatial analysis, and specialized software (LAHARZ and HAZMAP) to deliminate lahar inundation zones, areas that could potentially be affected by ash fallout (including the evaluation of houses prone to roof collapse due to ash load), and the most susceptible areas for hosting future monogenetic vent formation.     

Anodic Oxidation as Green Alternative for Removing Diethyl Phthalate from Wastewater Using Pb/PbO2 and Ti/SnO2 Anodes

The electrochemical oxidation (EO) of diethyl phthalate (DEP) in aqueous solution was studied at Pb/PbO₂ and Ti/SnO₂ anode materials under galvanostatic‐experimental conditions. Results obtained clearly demonstrated that the anode plays a significant role for the optimization of the oxidation process, deciding the mechanisms and by‐products formed. DEP and by‐products of oxidation were also analyzed during various stages of the electrolysis reaction by HPLC and GC/MS techniques. Before the analysis by GC/MS technique, the samples were treated by solid phase microextraction (SPME) in order to concentrate the compounds from the reaction solution and identify all electrolysis intermediates. Current efficiencies (instantaneous current efficiency; ICE and total current efficiency; TCE) achieved during EO experiments were dependent on anode used and current density (20–40 mA cm^?2) at 40°C. The results obtained demonstrated that the environmental electrochemical methods can be a feasible alternative for the wastewater treatment containing hazardous phthalates.     

Subsurface thermal conductivity assessment in Calabria (southern Italy): a regional case study

Determining the suitability of a local area at a regional or local scale for the geothermal application of low enthalpy systems requires the knowledge of rock thermal conductivity values to evaluate the possibility of low-enthalpy heat exchange. A digital cartographic tool is also needed to synthesize the thermal properties of the underground. This tool should be easily accessible and upgradeable and thus suitable for territorial planning and environmental control. In order to address these key issues, a methodological approach was developed within the framework of the national VIGOR Project, dedicated to evaluating the geothermal potential in southern Italy. In this paper the region of Calabria was selected as a case study. Around 70 samples that were representative of the main geological formations were collected from all over the area. Thermal property tests were carried out both in dry and wet conditions, using a thermal device in accordance with the modified transient plane source method. The thermal conductivity values were then compared with data from the international literature. In order to consider the influence of the entire stratigraphic sequence on the thermal conductivity parameters, a geostatistical analysis of the available lithostratigraphic data was performed using the MATLAB toolbox Modalstrata, specially developed for this purpose. A comprehensive geothermal subsurface characterization of Calabria was thus obtained.     

Dolomitic marbles and associated calc-silicates, Tandilia belt, Argentina: Geothermobarometry, metamorphic evolution, and P–T path

The metamorphic evolution of dolomitic marbles and associated calc-silicate rocks from Punta Tota (NE Tandilia belt, Buenos Aires province, Argentina) has been evaluated through petrographic, geothermobarometric, and fluid inclusion studies. Thin beds of dolomitic marble are intercalated in amphibolites and constitute the upper part of a stratified basement sequence, which starts at the base with garnet migmatites showing a great abundance of pegmatitic segregates, overlain by biotite–garnet gneisses. Peak metamorphic conditions are estimated at 750–800 °C and 5–6 kb, followed by near isobaric cooling to about 500–450 °C and 5.5–6.5 kb. Anhydrous progressive metamorphic assemblages in both marbles (Fo + Cal + Dol + Cpx + Spl) and adjacent calc-silicate rocks (Cpx + An + Cal + Qtz) strongly retrogressed to hydrous minerals (Tr, Tlc, Grs, Czo, Srp) with decreasing temperatures and increasing water activities. The intense rehydration of the rocks relates to the emplacement of volatile-rich pegmatitic bodies (Qtz + Pl + Kfs + Bt + Grt), which also resulted in the crystallization of clinochlore + phlogopite in the marble and biotite + muscovite in the adjacent calc-silicate rocks. Metamorphic reactions based on textural relations and evaluated on a suitable petrogenetic grid, combined with geothermobarometric results and fluid inclusion isochores, indicate a metamorphic evolution along a counterclockwise P–T path. Two probable geotectonic settings for the determined P–T trajectory are proposed: (1) thinning of the crust and overlying supracrustal basin in an ensialic intraplate tectonic setting and (2) development of a marginal back-arc basin, associated with an oceanic–continental convergent plate margin. In both models, the initial extensional regime is followed by a compressional stage, with overthickening of the basement and supracrustal rocks, during the climax of the Transamazonian cycle at approximately 1800 Ma ago. Continuous convergence and blockage of structures produce transition to transcurrent tectonics (transpression) with a consequent moderate uplift.     

Weakening of gneiss surfaces colonized by endolithic lichens in the temperate climate area of northwest Italy

A role of lithobionts in geomorphological processes is increasingly argued, but the spatio‐temporal scale of their impact is largely unexplored in many ecosystems. This study first characterizes in the temperate zone (northwest Italy) the relationships between lithobiontic communities including endolithic lichens and the hardness of their siliceous rock substrate (Villarfocchiardo Gneiss). The communities are characterized, on humid and xeric quarry surfaces exposed for decades and natural outcrops exposed for centuries, in terms of lichen and microbial constituents, using a combined morphological and molecular approach, and with regard to their development on and within the gneiss. A lichen species belonging to Acarosporaceae (Polysporina‐Sarcogyne‐Acarospora group, needing taxonomic revision) chasmoendolithically colonizes both the humid and xeric quarry surfaces, on which epilithic cyanobacterial biofilms and epilithic pioneer lichens respectively occur. Light and electron microscopic observations show the development of the endolithic thalli within rock microcracks and the hyphal penetration along crystal boundaries down to depths of 1 to 3 mm, more pronounced within the humid surfaces. Such colonization patterns are likely related to biogeophysical deterioration, while no chemical alteration characterizes minerals contacted by the endolithic lichen. By contrast, on natural outcrops, where the endolithic colonization is negligible, a reddish rind below epilithic lichens indicates chemical weathering processes. Schmidt Hammer measurements highlight that the endolithic lichens deeply affect the hardness of the gneiss (down to ?60% with respect to fresh controls and surfaces only colonized by cyanobacteria), exerting a significantly higher weakening effect with respect to the associated epilithic lithobionts. The phenomenon is more remarkable on humid than on xeric quarry surfaces and natural outcrops, where epilithic lichens are likely involved in long‐term hardening processes supporting surface stabilization. Endolithic lichens are thus active biogeomorphological agents at the upper millimetric layer of siliceous rocks in temperate areas, exerting their weakening action during the early decade‐scaled stages of surface exposure. Copyright © 2015 John Wiley & Sons, Ltd.     

Microdeformation of lacustrine laminite sequences from Late Miocene formations of SE Spain: an interpretation of loop bedding

Lacustrine laminated sediments (laminites) present in Late Miocene formations of the Híjar Basin, SE Spain, display well developed loop bedding, a structure consisting of bundles of laminae that are sharply constricted at intervals, giving a morphology of loops or links of a chain. The laminite sequences, which are interbedded with turbidite marlstones, were accumulated on the bottom of a permanently stratified lake developed in a rapidly subsiding basin limited by 010° and 105° normal faults. As deduced from both macro- and microdeformational analyses, the basin evolved under an extensional stress field throughout the Late Miocene. Four main types of loops, simple and complex loops with subcategories, have been recognized within the laminite sequence. Simple loops of type 1 show the best definite pattern, quite similar to ' pinch and swell structures ', a type of boudinage typical of stretching of alternating beds where the competence contrast is not strongly marked. The remaining loop types display contortion and occasional breakage of laminae (microfaulted edges) indicative of microdeformation near the boundary between the ductile-brittle deformational fields. The distribution of the various loop types across the laminite sequence reflects an interplay between progressive lithification of the laminites as sedimentation progressed and tectonic stresses which affected the sediment sequence. Accordingly, a mechanism of deformation under an extensional stress field, ultimately related to the creep movement of the main basin faults which resulted in successive seismic shocks of low magnitude, is proposed to explain the formation of loop bedding in the laminites.     

Solar-Terrestrial Signal Record in Tree Ring Width Time Series from Brazil

This work investigates the behavior of the sunspot number and Southern Oscillation Index (SOI) signal recorded in the tree ring time series for three different locations in Brazil: Humaitá in Amaz?nia State, Porto Ferreira in S?o Paulo State, and Passo Fundo in Rio Grande do Sul State, using wavelet and cross-wavelet analysis techniques. The wavelet spectra of tree ring time series showed signs of 11 and 22?years, possibly related to the solar activity, and periods of 2–8?years, possibly related to El Ni?o events. The cross-wavelet spectra for all tree ring time series from Brazil present a significant response to the 11-year solar cycle in the time interval between 1921 to after 1981. These tree ring time series still have a response to the second harmonic of the solar cycle (5.5?years), but in different time intervals. The cross-wavelet maps also showed that the relationship between the SOI x tree ring time series is more intense, for oscillation in the range of 4–8?years.