Numerical Computation of Hansen-like Expansions

Fourier expansions of elliptic motion functions in multiples of the true, eccentric, elliptic and mean anomalies are computed numerically by means of the fast Fourier transform. Both Hansen-like coefficients and their derivatives with respect to eccentricity of the orbit are considered. General behavior of the coefficients and the efficiency (compactness) of the expansions are investigated for various values of eccentricity of the orbit. This revised version was published online in July 2006 with corrections to the Cover Date.     

Palaeomagnetism of the Lower Ordovician Orthoceras Limestone, St. Petersburg, and a revised drift history for Baltica in the early Palaeozoic

Palaeomagnetic investigation of Lower Ordovician limestone in the vicinity of St. Petersburg yields a pole position at latitude 34.7°N, longitude 59.1°E ( dp / dm =5.7°/6.4°). A probable primary remanence origin is supported by the presence of a field reversal. The limestone carries one other remanent magnetization component associated with a Mesozoic remagnetization event.
An apparent polar wander path is compiled for Baltica including the new result, ranging in age from Vendian to Cretaceous. Ages of the published Lower to mid-Palaeozoic palaeomagnetic pole positions are adjusted in accordance with the timescale of Tucker & McKerrow (1995). The new Arenig result is the oldest of a series of Ordovician and Silurian palaeomagnetic pole positions from limestones in the Baltic region. There are no data to constrain apparent polar wander for the Tremadoc, Cambrian and latest Vendian. If the Fen Complex results, previously taken to be Vendian in age ( c . 565 Ma), are reinterpreted as Permian remagnetizations, an Early Ordovician–Cambrian–Vendian cusp in the polar wander path for Baltica is eliminated. The apparent polar wander curve might then traverse directly from poles for Vendian dykes on the Kola peninsula ( c . 580 Ma) towards our new Arenig pole ( c . 480 Ma). The consequence of this change in terms of the motion of Baltica in Cambrian times is to reduce significantly a rotational component of movement.
The new Arenig pole extends knowledge of Ordovician apparent polar wander an increment back in time and confirms the palaeolatitude and orientation of Baltica in some published palaeogeographies. Exclusion of the Fen Complex result places Baltica in mid- to high southerly latitudes at the dawn of the Palaeozoic, consistent with faunal and sedimentological evidence but at variance with some earlier palaeomagnetic reconstructions.     

Biostratigraphy of the Mussau Trench (Caroline Basin)

A sedimentary rock complex overlays the deep layers of oceanic crust in the Mussau Trench (and the conjugated underwater ridge) of the Caroline Basin. Paleontological analyses supported the previous idea of Oligocene-Quaternary deposits. In addition, Upper Cretaceous (Acila ex gr. demessa, Anisomyon sp., and others) and Eocene (Heterostegina sp., Discocyclina sp., and others) deposits have been found, suggesting shallow water environments in Late Cretaceous-Early Cenozoic time. Later on, regional submergence started. The complex of the deep-seated formations of the Mussau Trench is not younger than the Early Cretaceous oceanic crust of the Ontong-Java Plateau.     

Chemical speciation of copper and zinc in surface waters of the western Black Sea

The chemical speciation of Cu and Zn was investigated by voltammetric titration methods in the surface waters (10 m) of the western Black Sea during an Istanbul–Sevastopol cruise conducted in November 1998. Supporting parameters (temperature (T), salinity (S), pH, alkalinity (Alk), suspended particulate matter (SPM) and dissolved and particulate ²³⁴Th) were obtained in order to distinguish hydrographic features against involvement of the metals in biogeochemical processes. In the Turkish continental slope region, the cruise track intersected a narrow vein of colder water originating on the western shelf. The core of this cold water vein was characterised by a relatively low salinity, higher specific alkalinity and higher metal (especially Cu) and metal-binding ligand concentrations.A very large portion of Cu (93–99.8%) and Zn (82–97%) was organically complexed. The degree of complexation was highest in shelf waters and lowest in the central gyre. Titration data for Cu were modelled by two classes of organic binding ligands characterised by (C_L1=3–12 nM, log K₁′=13.1–13.9) and (C_L2=20–70 nM, log K₂′=9.4–11.2). These ligands occurred mainly in the ‘dissolved’ phase, as defined by 0.4-μm filtration. The stronger Cu-binding ligand seemed to be produced in situ in response to Cu concentration, whereas the weaker Cu-binding ligand appeared to be derived from terrestrial sources and/or reducing shelf sediments. Titration results for Zn were generally represented by one class of ligands (C_L1=8–23 nM, log K₁′=9.4–10.2), which were almost uniformly distributed between the ‘dissolved’ (78±8%) and the particulate phase (22±8%). The concentration of these strong Zn-binding ligands showed a very good correlation with SPM (r²=0.64), which improved when the dissolved ligands alone were considered (r²=0.78). It is hypothesised that these ligands were produced in situ by the bacterial breakdown of particulate organic matter.     

Holocene pollen record from a peatland in the West Caucasus,Abkhasia, Black Sea region

A pollen sequence spanning over 4000 years was recovered from a small (0.1 ha)Sphagnum-dominated peatland in the mountains near Sukhumi, Abkhasia, West Georgia. The peatland lies atc. 1650 m a.s.l. in denseFagus-Abies forest. The pollen record reveals totally forested surroundings throughout since at least 4000 years BP (90–95% AP). It begins with a complex forest dominated byFagus with large proportions ofCastanea, Acer andUlmus. ThenCastanea became dominant whileFagus was still prominent. This might indicate a warmer climate. Later development shows a dramatic decline ofCastanea. Its pollen drops down to 3–5%. RecentlyAbies has been experiencing an exponential growth. Now it comprises over 50% of the forest composition around the peatland. These changes have possibly been caused by human influence together with climatic change. The basin started as aPotamogeton-dominated shallow lake with ferns andAlisma along the margins. Later it developed into a sedge fen and finally aSphagnum andMenyanthes poor fen with scatteredCarex limosa. The record indicates a progression towards oligotrophy.This publication is the fifth paper in a series of papers presented at the session on Past Climatic Change and the Development of Peatlands at the ASLO and SWS Meetings in Edmonton, Canada, May 30–June 3, 1993. Dr. P. Kuhry and Dr S. C. Zoltai are serving as Guest Editors.     

An object-oriented information model for territorial system management

This article examines an object-oriented geospatial information model for territorial system management, its benefits compared to current automated territorial management systems, and special aspects of its development and implementation in multi-level geoinformation systems. The presented study reflects the major functions of geoinformation materials used in spatial planning, particularly in Earth remote sensing. A territorial information management model is developed from the perspective of the object-oriented geoinformation approach. The study identifies the major functions of the proposed management system and demonstrates what kinds of problems can be solved using this system, develops a spatial algorithmic model for managerial decision-making and a methodology for analyzing local territorial system characteristics; and introduces basic information arrays that can be used to solve practical territorial management problems at various levels.     

Initiation and Propagation of Compaction Bands in Dry and Wet Bentheim Sandstone

We investigated initiation and propagation of compaction bands (CB) in six wet and four dry Bentheim sandstone samples deformed in axial compression tests with strain rates ranging from 3.2 × 10^?8 s^?1 to 3.2 × 10^?4 s^?1. Circumferential notches with 0.8-mm width and 5-mm depth served to initiate CB at mid-sample length. Wet samples were saturated with distilled water and deformed at 195 MPa confining pressure and 10 MPa pore pressure. Dry samples were deformed at 185 MPa confining pressure. Twelve P-wave sensors, eight S-wave sensors and two pairs of orthogonally oriented strain-gages were glued to the sample surface to monitor acoustic emission (AE), velocities and local strain during the loading process. Nucleation of compaction bands is indicated by AE clusters close to the notch tips. With progressive loading, AE activity increased and AE hypocenters indicated propagation of a single CB normal to the sample axis. CB propagation from the sample periphery towards the centre was monitored. Microstructural analysis of deformed samples shows excellent agreement between location of AE clusters and CBs. In both dry and wet samples the lateral propagation of CBs was about 100 times faster than axial shortening rates. At the slowest displacement rate, AE activity during band propagation was reduced and CB nucleation in wet samples occurred at 20% lower stresses. This may indicate an increasing contribution of stress corrosion processes to the formation of the compaction bands. In dry and wet samples inelastic compaction energy per area ranged between 16 and 80 kJ m^?2. This is in good agreement with previous estimates from laboratory and field studies.     

Y/Ho Ratios in the Late Cenozoic Basalts from the Eastern Tuva, Russia: An ICP-MS Study with Enhanced Data Quality

A set of forty seven Late Cenozoic basaltic rocks from the Eastern Tuva (southern Siberia, Russia) have been studied by ICP-MS using In as an internal standard. Yttrium and Ho concentrations, determined along with other trace elements, varied systematically from one analytical run to another and covered the entire charge-and-radius-controlled field within the range 24 < Y/Ho < 34, so obscuring any geochemical interpretation. A correction procedure was therefore developed in which the Y/Ho ratios were recalculated using concentrations of these elements determined in international and in-house reference materials (BHVO-1, AGV-1, BIR-1 and U-94-5). Statistical analysis of the recalculated data set revealed two groups of samples not related by their genesis but rather by their respective analytical runs. Fourteen samples originally analysed in five different runs were then re-measured by the same instrument in peak-hopping mode using only specific mass peaks (m/z = 89, 115 and 165). All of these samples yielded Y/Ho ratios in a narrow range between 29 and 31, thus illustrating how analytical problems in the determination of Y and Ho by routine ICP-MS procedures can be overcome. Finally, a mean value of Y/Ho = 30.3 ± 1.1 (1s) was derived for the basaltic rocks of the Eastern Tuva. This is close to the value of 28.8 accepted for chondrites and for ocean island basalts. Despite the uniform Y/Ho ratio, the element concentrations in basaltic rocks from the Eastern Tuva show systematic enrichment in heavy rare earth elements and yttrium from the Miocene to the Quaternary.     

Towards the solution of the λ Bootis problem

Having analysed the accretion-based model of the dust–gas separation, which is regarded to be the most promising for the explanation of the anomalous properties of λ Bootis-type stars, we can conclude that: (i) for any reasonable density profiles of the shell, dust grains appear to be decoupled from the gaseous background within the region where the temperature drops to a value that is less than the condensation temperature of heavy elements such as Mg, Ca, Fe, etc; (ii) most likely, in the shell of λ Bootis-type stars only small dust particles (of less than ≈10⁻⁶ cm in size) can be created; (iii) significant alteration of the initial atmospheric chemical composition can take place in the case when the density in the shell changes as ∼ r ⁻².