Granulite sulphides as tracers of lower crustal origin and evolution: An example from the Slave craton, Canada

We carried out a detailed study of sulphide minerals, a ubiquitous mineral group in lower crustal mafic to peraluminous granulite xenoliths from the Diavik kimberlites, to assess their use in constraining the origin and tectonothermal evolution of the deep crust, and to obtain additional data on the composition of lower crust beneath ancient continents. Sulphides are overwhelmingly pyrrhotite with minor Ni (0.7-3.9 at.%), Co (0.1-0.7 at.%), and Cu contents (0.4-3.9 at.%). Sulphide modes in mafic granulites range from 0.14 to 0.55 vol%, translating into bulk rock S contents from ∼600 to 2000 ppm, similar to S contents in other mafic igneous rocks and indicating preservation of primary igneous S contents. In mafic granulites, Re and Os abundances in sulphides range from 42.5 to 726 ppb and 3.2 to 180 ppb, respectively, whereas those in peraluminous granulites are distinctly lower (36.1-282 ppb and 1.8-7.2 ppb, respectively), suggestive of Re and Os loss to fractionating sulphides in the more evolved precursors of these rocks.The significant within-sample variability of ¹⁸⁷Os/¹⁸⁸Os and correlation with ¹⁸⁷Re/¹⁸⁸Os indicates the preservation of primary Re-Os isotope systematics and time-integrated decay of the measured ¹⁸⁷Re. Within the large uncertainties inherent in the nature of the samples and technique, sulphides in some granulites may record major tectonothermal events in the central Slave craton spanning several billion years of evolution. Multiple generations of sulphide can occur in a single sample. These data attest to the heterogeneous composition and complex history of the Slave craton lower crust.     

Ultrasonic Velocities, Acoustic Emission Characteristics and Crack Damage of Basalt and Granite

Acoustic emissions (AE), compressional (P), shear (S) wave velocities, and volumetric strain of Etna basalt and Aue granite were measured simultaneously during triaxial compression tests. Deformation-induced AE activity and velocity changes were monitored using twelve P-wave sensors and eight orthogonally polarized S-wave piezoelectric sensors; volumetric strain was measured using two pairs of orthogonal strain gages glued directly to the rock surface. P-wave velocity in basalt is about 3 km/s at atmospheric pressure, but increases by > 50% when the hydrostatic pressure is increased to 120 MPa. In granite samples initial P-wave velocity is 5 km/s and increases with pressure by < 20%. The pressure-induced changes of elastic wave speed indicate dominantly compliant low-aspect ratio pores in both materials, in addition Etna basalt also contains high-aspect ratio voids. In triaxial loading, stress-induced anisotropy of P-wave velocities was significantly higher for basalt than for granite, with vertical velocity components being faster than horizontal velocities. However, with increasing axial load, horizontal velocities show a small increase for basalt but a significant decrease for granite. Using first motion polarity we determined AE source types generated during triaxial loading of the samples. With increasing differential stress AE activity in granite and basalt increased with a significant contribution of tensile events. Close to failure the relative contribution of tensile events and horizontal wave velocities decreased significantly. A concomitant increase of double-couple events indicating shear, suggests shear cracks linking previously formed tensile cracks.     

Neoproterozoic ‘anomalous’ kimberlites of Guaniamo, Venezuela: Mica kimberlites of ‘isotopic transitional’ type

In Venezuela, kimberlites have so far only been found in the Guaniamo region, where they occur as high diamond grade sheets in massive to steeply foliated Paleoproterozoic granitoid rocks. The emplacement age of the Guaniamo kimberlites is 712±6 Ma, i.e., Neoproterozoic. The Guaniamo kimberlites contain a high abundance of mantle minerals, with greater than 30% olivine macrocrysts. The principal kimberlite indicator minerals found are pyrope garnet and chromian spinel, with the overwhelming majority of the garnets being of the peridotite association. Chrome-diopside is rare, and picroilmenite is uncommon. Chemically, the Guaniamo kimberlites are characterized by high MgO contents, with low Al₂O₃ and TiO₂ contents and higher than average FeO and K₂O contents. These rocks have above average Ni, Cr, Co, Th, Nb, Ta, Sr and LREE concentrations and very low P, Y and, particularly, Zr and Hf contents. The Nb/Zr ratio is very distinctive and is similar to that of the Aries, Australia kimberlite. The Guaniamo kimberlites are similar in petrography, mineralogy and mantle mineral content to ilmenite-free Group 2 mica kimberlites of South Africa. The Nd-Sr isotopic characteristics of Guaniamo kimberlites are distinct from both kimberlite Group 1 and Group 2, being more similar to transitional type kimberlites, and in particular to diamondiferous kimberlites of the Arkhangelsk Diamond Province, Russia. The Guaniamo kimberlites form part of a compositional spectrum between other standard kimberlite reference groups. They formed from metasomatised subcontinental lithospheric mantle and it is likely that subduction of oceanic crust was the source of this metasomatised material, and also of the eclogitic component, which is dominant in Guaniamo diamonds.     

Extratropical cyclone variability in the Northern Hemisphere winter from the NCEP/NCAR reanalysis data

 The winter climatology of Northern Hemisphere cyclone activity was derived from 6-hourly NCEP/NCAR reanalysis data for the period from 1958 to 1999, using software which provides improved accuracy in cyclone identification in comparison to numerical tracking schemes. Cyclone characteristics over the Kuroshio and Gulfstream are very different to those over continental North America and the Arctic. Analysis of Northern Hemisphere cyclones shows secular and decadal-scale changes in cyclone frequency, intensity, lifetime and deepening rates. The western Pacific and Atlantic are characterized by an increase in cyclone intensity and deepening during the 42-year period, although the eastern Pacific and continental North America demonstrate opposite tendencies in most cyclone characteristics. There is an increase of the number of cyclones in the Arctic and in the western Pacific and a downward tendency over the Gulf Stream and subpolar Pacific. Decadal scale variability in cyclone activity over the Atlantic and Pacific exhibits south-north dipole-like patterns. Atlantic and Pacific cyclone activity associated with the NAO and PNA is analyzed. Atlantic cyclone frequency demonstrates a high correlation with NAO and reflects the NAO shift in the mid 1970s, associated with considerable changes in European storm tracks. The PNA is largely linked to the eastern Pacific cyclone frequencies, and controls cyclone activity over the Gulf region and the North American coast during the last two decades. Assessment of the accuracy of the results and comparison with those derived using numerical algorithms, shows that biases inherent in numerical procedures are not negligible. Received: 7 July 2000 / Accepted: 30 November 2000     

The new state flags as the iconographic symbols of the post-Soviet space

State flags may be appreciated as iconographic symbols according to Jean Gottmann's definition. Especially interesting is to analyze the state flags in the moment of their creation – as for example on the territory of the former Soviet Union where almost all the new independent states have to create or restore their state symbols. On many of these flags we can see the historical elements, the political and geographical situation of a new state or even religious beliefs of most of the inhabitants. On the state flags we can also observe the state ideology, but its interpretation may be ambiguous, e.g., the green color on the state flag means either that the state is proud of its rich nature or that Islam is a state religion. Ambitions are expressed on the flags of the entities, which are fighting for their independence.     

Modelling the compliance of crustal rock—I. Response of shear-wave splitting to differential stress

We show that seismic shear waves may be used to monitor the in situ stress state of deep inaccessible rocks in the crust. The most widespread manifestation of the stress-related behaviour of seismic waves is the shear-wave splitting (shear-wave birefringence) observed in almost all rocks, where the polarizations of the leading split shear waves are usually subparallel to the direction of the local maximum horizontal stress. It has been recognized that such shear-wave splitting is typically the result of propagation through distributions of stress-aligned fluid-filled microcracks and pores, known as extensive-dilatancy anisotropy or EDA. This paper provides a quantitative basis for the EDA hypothesis. We model the evolution of anisotropic distributions of microcracks in triaxial differential stress, where the driving mechanism is fluid migration along pressure gradients between neighbouring microcracks and pores at different orientations to the stress field. This leads to a non-linear anisotropic poroelasticity (APE) model for the stress-sensitive behaviour of fluid-saturated microcracked rocks. A companion paper shows that APE modelling matches a range of observed phenomena and is a good approximation to the equation of state of a stressed fluid-saturated rock mass.     

Impact of ice cover in the Arctic on ocean–atmosphere turbulent heat fluxes

The impact of spatiotemporal variability of the ice-covered area in the Arctic on the value and interannual dynamics of turbulent heat fluxes on the ocean–atmosphere border is considered. An expected inverse dependence of the heat fluxes integrated over the Arctic area and the area of ice is not detected. The largest interannual oscillations of heat fluxes from the ocean to the atmosphere are timed to the varying position of the ice edge and, to a lesser extent, are connected with total area of ice. The role of the marginal ice zone in oceanic heat transfer is analyzed. In particular, it is shown that while moving along the marginal zone from the ice-free surface to the surface with an ice concentration of 0.8, latent and sensible heat fluxes are reduced by a factor of 2.5–3.     

Formation of extreme surface turbulent heat fluxes from the ocean to the atmosphere in the North Atlantic

The role of extreme surface turbulent fluxes in total oceanic heat loss in the North Atlantic is studied. The atmospheric circulation patterns enhancing ocean–atmosphere heat flux in regions with significant contributions of the extreme heat fluxes (up to 60% of the net heat loss) are analyzed. It is shown that extreme heat fluxes in the Gulf Stream and the Greenland and Labrador Seas occur in zones with maximal air pressure gradients, i.e., in cyclone–anticyclone interaction zones.