Chemical evolution ahead of Herbig–Haro objects

Compact regions of enhanced HCO⁺ and NH₃ emission have been detected close to a number of Herbig–Haro objects. An interpretation of these detections is the following: a transient clump within the molecular cloud has been irradiated by the shock that generates the Herbig–Haro object. The irradiation releases icy mantles from the grains within the transient clump and initiates a photochemistry. On the basis of this picture, we have developed an extensive chemical model which predicts that a wide range of species, other than NH₃ and HCO⁺, should also be detectable. These include CH₃OH, H₂S, C₃H₄, H₂CO, SO, SO₂, H₂CS and NS. The chemical effects should last ∼  10⁴ yr  .     

In‐plane strength of unreinforced masonry piers

The definition of adequate simplified models to assess the in‐plane load‐bearing capacity of masonry piers, in terms of both strength and displacement, plays a fundamental role in the seismic verification of masonry buildings. In this paper, a critical review of the most widespread strength criteria present in the literature and codes to interpret the failure modes of piers (rocking, crushing, bed joint sliding or diagonal cracking) are proposed. Models are usually based on an approximate evaluation of the stress state produced by the external forces in a few points/sections and on its assessment with reference to a limit strength domain. The aim of the review is to assess their reliability by discussing the hypotheses, which they are based on (assumed stress states; choice of reference points/sections on which to assess the pier strength; characteristics of the limit strength domain) and to verify the conditions for their proper use in practice, in terms of both stress fields (depending on the geometry of the pier, boundary conditions and applied loads) and types of masonry (i.e. regular brick masonry vs rubble stone masonry). In order to achieve these objectives, parametric nonlinear finite element analyses are performed and different experimental data available in the literature are analysed and compared. Copyright © 2008 John Wiley & Sons, Ltd.     

Estimating Stable Measured Values and Detecting Anomalies in Groundwater Geochemistry Time Series Data Across the Athabasca Oil Sands Area,Canada

Regional groundwater monitoring in the Athabasca region of Alberta, Canada, provides information on groundwater quality and geochemical changes over time, including data useful for evaluating potential impacts of industrial activity such as oil sands mining and in situ operations. Data collected from over 5000 wells from the 1950s to 2014, including 161 wells from government’s monitoring network, were used to develop and apply bootstrap techniques for the detection of changes in groundwater geochemistry over time and at specific points in time. Increasing temporal anomalies were identified in Cl, TDS, B, and naphthenic acids in the McMurray formation across 2003 and 2008, while decreasing anomalies were found for SO₄. Temporal variance for 15 indicators was quantified for a smooth bootstrap approach to arrive at stable values representative of the most recent samples taken from wells in the study area. Stable values revealed sampling bias in the Devonian, Grand Rapids, Empress, Channel Beverly, and Muriel Lake formations suggesting expansion of sampling may be necessary. Although temporal anomalies were found in the McMurray formation, sampling bias was not identified. The entropy and relative magnitude of time series were evaluated to identify candidate wells for continued observations, which consist of wells with low measurements and low entropy that are near active industry lease boundaries. Temporal anomalies, stable values, and entropy were combined into type-well information to provide plots for visual inspection and interpretation. Stable values are useful for regional mapping, for detecting future changes and trends, and for identifying areas of interest warranting further investigation.

     

Recent advances in star-formation studies

David A Williams and Serena Viti survey the contributions made to this fast-moving field at a recent RAS Discussion Meeting. The resulting debates were often both challenging and confrontational.     

Dissolved organic carbon variability in a shallow coastal marine system (Gulf of Trieste,northern Adriatic Sea)

The variability of dissolved organic carbon (DOC) over days to a multi-year time span has been investigated in the Gulf of Trieste (northern Adriatic Sea) over a period of 5 years (January 1999 to December 2003). Samples were collected in a grid of 9 to 12 stations on monthly frequency and in one station on weekly (2003) and daily (1-month) frequency. DOC samples were analyzed by the HTCO method. DOC concentration varied over the five years in the range of 50 to 194 μM with annual median values ranging from 88 to 98 μM. Over the years 1999–2002, DOC showed a clear annual periodicity with winter minima and late summer maxima, higher in 1999 and 2000. During 2003 no seasonality was detected. The absence of DOC seasonality and the lower DOC concentrations during 2003 are most likely related to the drought that characterized the whole year. Accumulation was calculated as the difference between averaged winter minima (59 ± 7 μM) and the monthly averaged integrated value. DOC that had accumulated from spring to summer totally disappeared from the water column in winter when DOC concentrations reached the background value. The Gulf of Trieste, as with the rest of the Northern Adriatic each year, seems to be able to bring back DOC concentrations at low levels despite the significant external (mainly Isonzo River inputs) and internal organic matter loads. DOC concentration exhibited quite wide fluctuations weekly and daily, suggesting there might be DOC of different turnover time through production, consumption, migration and accumulation.     

Nonlinear modeling of the seismic response of masonry structures: critical review and open issues towards engineering practice

Bulletin of Earthquake Engineering - This paper provides a comphrensive review of the critical aspects of nonlinear modeling for evaluating the seismic response of masonry structures, emphasizing...     

Effects of rainwater-harvesting-induced artificial recharge on the groundwater of wells in Rajasthan, India

In light of the increasing deterioration of groundwater supplies in Rajasthan, India, rainwater harvesting practices in southern Rajasthan were studied to determine the effects of artificially recharged groundwater on the supply and quality of local groundwater. A physical and geochemical investigation utilizing environmental tracers (δ¹⁸O and Cl^–), groundwater level and groundwater quality measurements, and geological surveys was conducted with two objectives: (1) to quantify the proportion of artificially recharged groundwater in wells located near rainwater harvesting structures and (2) to examine potential effects of artificial recharge on the quality of groundwater in these wells. A geochemical mixing model revealed that the proportion of artificial recharge in these wells ranged from 0 to 75%. Groundwater tracer, water table, and geological data provided evidence of complex groundwater flow and were used to explain the spatial distribution of artificial recharge. Furthermore, wells receiving artificial recharge had improved groundwater quality. Statistical analysis revealed a significant difference between the water quality in these wells and wells determined not to receive artificial recharge, for electrical conductivity and SO ₄ ^– . The findings from this study provide quantitative evidence that rainwater harvesting structures in southern Rajasthan influence the groundwater supply and quality of nearby wells by artificially recharging local groundwater.     

Revealing the “fingerprints” of the magnetic precursor of C-shocks

We present the first C-shock and radiative transfer model that calculates the evolution of the line profiles of neutral and ion species like SiO, H¹³CO⁺ and HN¹³C for different flow times along the propagation of the shock through the unperturbed gas. We find that the line profiles of SiO characteristic of the magnetic precursor stage have very narrow linewidths and are centered at velocities close to the ambient cloud velocity, as observed toward the young shocks in the L1448-mm outflow. Consistently with previous works, our model also reproduces the broad SiO emission detected in the high velocity gas in this outflow, for the downstream postshock gas in the shock. This implies that the different velocity components observed in L1448-mm are due to the coexistence of different shocks at different evolutionary stages.