Capacity and mechanism of phenol adsorption on lignite

A raw lignitic coal from Soma, Turkey was investigated to determine its potential as an adsorbent for phenol removal from wastewaters. Kinetic batch tests demonstrated that phenol could be completely removed from solution given sufficient solids loading and reaction time. The adsorption capacity of 10 mg/g obtained with the lignite is low compared to those achievable with activated carbons (around 300 mg/g). However, when normalized for the surface area, the adsorption capacity was much larger for the lignite (1.3 mg/m²) than that generally observed with activated carbons (0.05–0.3 mg/m²). Hydrogen-bonding of the phenolic –OH with the oxygen sites on the lignite surface is the most likely mechanism for adsorption. Though water molecules also have affinity for the same oxygen sites, lateral benzene ring interactions make phenol adsorption energetically more favorable. Since phenol molecules adsorbed in this fashion would project their benzene rings into solution, formation of a second layer through the action of the dispersive π–π interactions between the benzene rings is very likely. Residual water quality with respect to major elements and heavy metals was within acceptable limits defined by the ASTM standards. Dissolution of organic matter from the lignite was also observed to be negligible.     

Analysis and interpretation of the aftershock sequence of the August 17, 1999, Izmit (Turkey) earthquake

A micro-seismic field experiment has been carried out in the Marmara Searegion. The analysis of the events before and after the August 17, 1999Izmit (Turkey) earthquake has been completed. 1446 events have beenwell located out of a total of 3165 recorded within the period from July15 to November 2, 1999. 67% of the aftershocks with magnitudegreater than 4 have occurred within the first 6 days after the main-shock. Earthquakes of the Izmit sequence are distributed in the first 15 km of theearth crust, but major events are located in between 5 km and 15 kmdepth. The seismicity pattern defines a rupture plane extending for about150 km in an E-W direction. The rupture is extremely linear butsegmented, and its complexity increases towards the western endmanifesting bifurcation. A stress analysis has been carried out both at thewestern end and all along the aftershock zone. 96 selected aftershocks,registered between August 21 and October 22, were chosen in order tocompute their focal mechanisms and obtain information about the stressregime after the Izmit earthquake. Strike-slip and normal faultingmechanisms are dominant. The numerous strike-slip mechanisms arecompatible with a dextral motion on an EW oriented vertical fault plane. The best stress tensor solution shows a regime in extension with awell-defined ₃ axis oriented approximately N35^°.     

An integration of GIS and remote sensing in groundwater investigations: A case study in Burdur, Turkey

The importance of groundwater is growing based on an increasing need and decreasing spring discharges in the Burdur area. Remote Sensing and the Geographic Information System (GIS) have been used for investigation of springs, which are an important groundwater source. The chemical composition of groundwater is not of drinking water quality in Burdur city and water in the Burdur residential area is being obtained from the Cine plain.The purpose of this study was to investigate new water sources by using remote sensing and GIS methods. Geology, lineament and land use maps of the research area were prepared using the Landsat TM satellite image composed of different analyses on the TM 7–4-1 band. In addition, contours, creeks, roads and springs were digitized using a topographic map of 1/100,000 scale to produce a drainage density map. A groundwater potential map was produced which integrated thematic maps, such as annual rainfall, geology, lineament density, land use, topography, slope and drainage density. According to this investigation, the surrounding villages of Askeriye, Bugduz, Gelincik, Taskap and Kayaalt were determined to be important from the point of view of groundwater potential in the research area.     

Magnesian andesites, Nb-enriched basalt-andesites, and adakites from late-Archean 2.7 Ga Wawa greenstone belts, Superior Province, Canada: implications for late Archean subduction zone petrogenetic processes

Magnesian andesites (MA) occur with 'normal' tholeiitic to calc-alkaline basalt-andesite suites in four greenstone belts of the 2.7 Ga Wawa subprovince, Canada. Collectively, the magnesian andesites span ranges of SiO₂=56-64 wt%, Mg-number=0.64-0.50, with Cr and Ni contents of 531-106 and 230-21 ppm, respectively. Relative to 'normal' andesites, the magnesian andesites form distinct trends on variation diagrams, with relatively high Th and LREE contents, uniform Yb over a range of MgO, more fractionated HREE, and lower Nb/Th_pm and Nb/La_pm ratios. Niobium-enriched basalts and andesites (NEBA; Nb=7-16 ppm), and an Al-enriched rhyolite (adakite) suite are associated in space and time with the magnesian andesites. Nb-enriched basalts and andesites are characterized by high TiO₂, P₂O₅, Th, and Zr contents, variably high Zr/Hf (36-44) ratios, and more fractionated HREE (Gd/Yb_cn=1.3-4.1) compared to the 'normal' tholeiitic to calc-alkaline basalt-andesite suites. The adakite suite has the high Al (Al₂O₃=16-18 wt%), high La/Yb_cn (21-43), and low Yb (0.4-1.2 ppm) of Archean tonalite-trondhjemite-granodiorite (TTG) suites and Cenozoic adakites, indicative of liquids derived mainly from slab melting. The basalt-andesite suites are not characterized by normal tholeiitic or calc-alkaline fractionation trends of major or trace elements. Rather, compositional trends can be accounted for by some combination of fractional crystallization and variable degrees of metasomatism of the source of basalt and/or andesites by adakitic liquids. The occurrence of magnesian andesites, Nb-enriched basalts/andesites, and adakites has been described from certain Phanerozoic arcs featuring shallow subduction of young and/or hot oceanic lithosphere. Adakites likely represent slab melts, magnesian andesites the product of hybridization of adakite liquids with mantle peridotite, and Nb-enriched basalts/andesites melts of the residue from hybridization. Geological similarities between the late-Archean Wawa greenstone belts and certain Cenozoic transpressional orogens with the MA-NEBA-adakite association suggest that subduction of young, hot oceanic lithosphere may have played an important role in the production of this arc-related association in the late Archean.     

A structural record of the emplacement of the Pozanti-Karsanti ophiolite onto the Menderes-Taurus block in the late Cretaceous, eastern Taurides, Turkey

The Aladag region of eastern Taurides, Turkey, is characterized by an imbricated thrust structure developed during late stage emplacement of the Pozanti-Karsanti ophiolite onto the Menderes-Taurus block in the late Cretaceous. The mid to late Cretaceous dynamothermal metamorphic sole and the underlying unmetamorphosed mélange, here named the Aladag accretionary complex, were accreted to the base of the Pozanti-Karsanti ophiolite during intra-oceanic subduction, transport and final obduction of the ophiolite onto the Menderes-Taurus block.In the dynamothermal metamorphic sole, intensity of deformation and degree of metamorphism increase from the base to the top, and at least three episodes of foliation, lineation and fold development are recognized. The asymmetry of quartz c-axis fabrics, tightness and asymmetry of folds of the same generation, and curvature of fold hinge lines increase from base to top, indicating that non-coaxial progressive deformation prevailed during the development of the metamorphic sole. The mélange is divided into three major thrust fault-bounded tectonic slivers, each of which is characterized by distinctive types of matrix and block lithologies, structures and deformation style. Kinematic analyses of the dynamothermal metamorphic sole and the mélange reveal that the tectonic transport direction of the Pozanti-Karsanti ophiolite during its emplacement was from north-northwest to south-southeast, suggesting that the Pozanti-Karsanti ophiolite was derived from a Neo-Tethyan ocean to the north of the Menderes-Taurus block.     

Petrogenetic and geodynamic origin of the Neoarchean Doré Lake Complex,Abitibi subprovince,Superior Province,Canada

International Journal of Earth Sciences - The Neoarchean (ca. 2728 Ma) anorthosite-bearing Doré Lake Complex in the northeastern Abitibi subprovince, Quebec, was emplaced into an...     

An Assessment of the Seismicity of the Bursa Region from a Temporary Seismic Network

A temporary earthquake station network of 11 seismological recorders was operated in the Bursa region, south of the Marmara Sea in the northwest of Turkey, which is located at the southern strand of the North Anatolian Fault Zone (NAFZ). We located 384 earthquakes out of a total of 582 recorded events that span the study area between 28.50–30.00°E longitudes and 39.75–40.75°N latitudes. The depth of most events was found to be less than 29 km, and the magnitude interval ranges were between 0.3 ≤ M_L ≤ 5.4, with RMS less than or equal to 0.2. Seismic activities were concentrated southeast of Uludag Mountain (UM), in the Kestel-Igdir area and along the Gemlik Fault (GF). In the study, we computed 10 focal mechanisms from temporary and permanents networks. The predominant feature of the computed focal mechanisms is the relatively widespread near horizontal northwest-southeast (NW–SE) T-axis orientation. These fault planes have been used to obtain the orientation and shape factor (R, magnitude stress ratio) of the principal stress tensors (σ₁, σ₂, σ₃). The resulting stress tensors reveal σ₁ closer to the vertical (oriented NE–SW) and σ₂, σ₃ horizontal with R = 0.5. These results confirm that Bursa and its vicinity could be defined by an extensional regime showing a primarily normal to oblique-slip motion character. It differs from what might be expected from the stress tensor inversion for the NAFZ. Different fault patterns related to structural heterogeneity from the north to the south in the study area caused a change in the stress regime from strike-slip to normal faulting.