Nuclear and incommensurate magnetic structure of NaFeGe2O6 between 5?K and 298?K and new data on multiferroic NaFeSi2O6

The compound NaFeGe₂O₆ was grown synthetically as polycrystalline powder and as large single crystals suitable for X-ray and neutron-diffraction experiments to clarify the low temperature evolution of secondary structural parameters and to determine the low temperature magnetic spins structure. NaFeGe₂O₆ is isotypic to the clinopyroxene-type compound aegirine and adopts the typical HT-C2/c clinopyroxene structure down to 2.5?K. The Na-bearing M2 polyhedra were identified to show the largest volume expansion between 2.5?K and room temperature, while the GeO₄ tetrahedra behave as stiff units. Magnetic susceptibility measurements show a broad maximum around 33?K, which marks the onset of low-dimensional magnetic ordering. Below 12?K NaFeGe₂O₆ transforms to an incommensurately modulated magnetic spin state, with k?=?[0.323, 1.0, 0.080] and a helical order of spins within the M1-chains of FeO₆ octahedra. This is determined by neutron-diffraction experiments on a single crystal. Comparison of NaFeGe₂O₆ with NaFeSi₂O₆ is given and it is shown that the magnetic ordering in the latter compound, aegirine, also is complex and is best described by two different spin states, a commensurate one with C2??/c?? symmetry and an incommensurate one, best being described by a spin density wave, oriented within the (1 0 1) plane.     

Torngat ultramafic lamprophyres and their relation to the North Atlantic Alkaline Province

Geological mapping and diamond exploration in northern Quebec and Labrador has revealed an undeformed ultramafic dyke swarm in the northern Torngat Mountains. The dyke rocks are dominated by an olivine-phlogopite mineralogy and contain varying amounts of primary carbonate. Their mineralogy, mineral compositional trends and the presence of typomorphic minerals (e.g. kimzeyitic garnet), indicate that these dykes comprise an ultramafic lamprophyre suite grading into carbonatite. Recognized rock varieties are aillikite, mela-aillikite and subordinate carbonatite. Carbonatite and aillikite have in common high carbonate content and a lack of clinopyroxene. In contrast, mela-aillikites are richer in mafic silicate minerals, in particular clinopyroxene and amphibole, and contain only small amounts of primary carbonate. The modal mineralogy and textures of the dyke varieties are gradational, indicating that they represent end-members in a compositional continuum.

The Torngat ultramafic lamprophyres are characterized by high but variable MgO (10–25 wt.%), CaO (5–20 wt.%), TiO₂ (3–10 wt.%) and K₂O (1–4 wt.%), but low SiO₂ (22–37 wt.%) and Al₂O₃ (2–6 wt.%). Higher SiO₂, Al₂O₃, Na₂O and lower CO₂ content distinguish the mela-aillikites from the aillikites. Whereas the bulk rock major and trace element concentrations of the aillikites and mela-aillikites overlap, there is no fractional crystallization relation between them. The major and trace element characteristics imply related parental magmas, with minor olivine and Cr-spinel fractionation accounting for intra-group variation.

The Torngat ultramafic lamprophyres have a Neoproterozoic age and are spatially and compositionally closely related with the Neoproterozoic ultramafic lamprophyres from central West Greenland. Ultramafic potassic-to-carbonatitic magmatism occurred in both eastern Laurentia and western Baltica during the Late Neoproterozoic. It can be inferred from the emplacement ages of the alkaline complexes and timing of Late Proterozoic processes in the North Atlantic region that this volatile-rich, deep-seated igneous activity was a distal effect of the breakup of Rodinia. This occurred during and/or after the rift-to-drift transition that led to the opening of the Iapetus Ocean.     

The channel between Gran Canaria and Tenerife: constructive processes and destructive events during the evolution of volcanic islands

Seismic, sidescan sonar, bathymetric multibeam and ODP (Ocean Drilling Program) data obtained in the submarine channel between the volcanic islands of Gran Canaria and Tenerife allow to identify constructive features and destructive events during the evolution of both islands. The most prominent constructive features are the submarine island flanks being the acoustic basement of the seismic images. The build-up of Tenerife started following the submarine stage of Gran Canaria because the submarine island flank of Tenerife onlaps the steeper flank of Gran Canaria. The overlying sediments in the channel between Gran Canaria and Tenerife are chaotic, consisting of slumps, debris flow deposits, syn-ignimbrite turbidites, ash layers, and other volcaniclastic rocks generated by eruptions, erosion, and flank collapse of the volcanoes. Volcanic cones on the submarine island flanks reflect ongoing submarine volcanic activity. The construction of the islands is interrupted by large destructive events, especially by flank collapses resulting in giant landslides. Several Miocene flank collapses (e.g., the formation of the Horgazales basin) were identified by combining seismic and drilling data whereas young giant landslides (e.g., the Güimar debris avalanche) are documented by sidescan, bathymetric and drilling data. Sediments are also transported through numerous submarine canyons from the islands into the volcaniclastic apron. Seismic profiles across the channel do not show a major offset of reflectors. The existence of a repeatedly postulated major NE-SW-trending fault zone between Gran Canaria and Tenerife is thus in doubt. The sporadic earthquake activity in this area may be related to the regional stress field or the submarine volcanic activity in this area. Seismic reflectors cannot be correlated through the channel between the sedimentary basins north and south of Gran Canaria because the channel acts as sediment barrier. The sedimentary basins to the north and south evolved differently following the submarine growth of Gran Canaria and Tenerife in the Miocene.     

‘PALEOVAN’, International Continental Scientific Drilling Program (ICDP): site survey results and perspectives

Lake Van is the fourth largest terminal lake in the world (volume 607 km³, area 3570 km², maximum depth 460 m), extending for 130 km WSW–ENE on the Eastern Anatolian High Plateau, Turkey. The sedimentary record of Lake Van, partly laminated, has the potential to obtain a long and continuous continental sequence that covers several glacial–interglacial cycles (ca 500 kyr). Therefore, Lake Van is a key site within the International Continental Scientific Drilling Program (ICDP) for the investigation of the Quaternary climate evolution in the Near East (‘PALEOVAN’). As preparation for an ICDP drilling campaign, a site survey was carried out during the past years. We collected 50 seismic profiles with a total length of ～850 km to identify continuous undisturbed sedimentary sequences for potential ICDP locations. Based on the seismic results, we cored 10 different locations to water depths of up to 420 m. Multidisciplinary scientific work at positions of a proposed ICDP drill site included measurements of magnetic susceptibility, physical properties, stable isotopes, XRF scans, and pollen and spores. This core extends back to the Last Glacial Maximum (LGM), a more extended record than all the other Lake Van cores obtained to date. Both coring and seismic data do not show any indication that the deepest part of the lake (Tatvan Basin, Ahlat Ridge) was dry or almost dry during past times. These results show potential for obtaining a continuous undisturbed, long continental palaeoclimate record. In addition, this paper discusses the potential of ‘PALEOVAN’ to establish new results on the dynamics of lake level fluctuations, noble gas concentration in pore water of the lake sediment, history of volcanism and volcanic activities based on tephrostratigraphy, and paleoseismic and earthquake activities.     

Freshwater Ostracodes in Quaternary Permafrost Deposits in the Siberian Arctic

Ostracode analysis was carried out on samples from ice-rich permafrost deposits obtained on the Bykovsky Peninsula (Laptev Sea). A composite profile was investigated that covers most of a 38-m thick permafrost sequence and corresponds to the last ca. 60 kyr of the Late Quaternary. The ostracode assemblages are similar to those known from European Quaternary lake deposits during cold stages. The ostracode habitats were small, shallow, cold, oligotrophic pools located in low centred ice wedge polygons or in small thermokarst depressions. In total, 15 taxa, representing 7 genera, were identified from 65 samples. The studied section is subdivided into six ostracode zones that correspond to Late Quaternary climatic and environmental stadial-interstadial variations established by other paleoenvironmental proxies: (1) cold and dry Zyrianian stadial (58–53 kyr BP); (2) warm and dry Karginian interstadial (48–34 kyr BP); (3) transition from the Karginian interstadial to the cold and dry Sartanian stadial (34–21 kyr BP); (4) transition from the Sartanian stadial to the warm and dry Late Pleistocene period, the Allerød (21–14 kyr BP); (5) transition from the Allerød to the warm and wet Middle Holocene (14–7 kyr BP); and (6) cool and wet Late Holocene (ca. 3 kyr BP). The abundance and diversity of the ostracodes will be used as an additional bioindicator for paleoenvironmental reconstructions of the Siberian Arctic.     

The Common Fisheries Policy: An enforcement problem

Marine populations in Europe are in decline due to the unsuccessful results of the Common Fisheries Policy. By combining data of scientific recommendations from ICES, TACs approved and reported landings with an age-structured model, the objectives of this paper are to investigate the level of compliance of the TAC regulation, and the level of enforcement and its economic impact on fishery resources. The results presented here suggest that while there does not exist a regular pattern between TAC proposal and TAC approved, there is a clear pattern between TAC approved and reported landings. As a consequence, there is a regular lack of enforcement at national fisheries authority level. The paper also presents results of the recovery plans for the Southern hake and the Atlantic cod fisheries as case studies to illustrate the level of enforcement based on collusion between national fisheries advisers and industry. The results from both cases studies analyzed here indicate that drastic solutions could generate positive results for the recovery of the stocks, but perhaps they are not always the best measure in fisheries management due to the high economic losses for fishermen and social effects on coastal communities in the short and medium term. Finally, this work demonstrates that if the recovery plans had been implemented, the net present profits for both fisheries would have increased over time.     

GIOVE-A initial signal analysis

In late December 2005 the GIOVE-A test satellite was launched by the European Space Agency (ESA) to secure the frequencies for the Galileo system and to provide a platform for testing the new navigation signals. We performed an initial assessment of these signals using the 30 m deep space antenna of the DLR ground station in Weilheim (Germany). The antenna gain raised the signals above the noise level, thus allowing a detailed analysis even without knowledge of the ranging codes. The present paper covers the analysis of the L1/E1 signals, which includes a discussion of the spectrum, the time domain signal and a decoding of the spreading codes for the Open Service.