Investigation of acidic dissolution of mixed clays between pH 1.0 and −3.0 using Si and Al X-ray absorption near edge structure

Although widely investigated in relation to acid mine drainage systems at pH > 1.0, we know little about the impact of sulfuric acid (H₂SO₄) on the geochemistry and mineralogy of clays at pH < 1.0 (including negative pH values). Thus, laboratory batch experiments were conducted on three mixed clay samples with different mass ratios of phyllosilicates (smectite, illite, and kaolinite) to investigate the impact of H₂SO₄ from pH 1.0 to −3.0 for exposure periods of 14, 90, 180, and 365 days. Si and Al K- and L_2,3-edge X-ray absorption near edge structure (XANES) spectroscopy were employed on these samples to determine the chemical and structural changes that occur during acidic dissolution of phyllosilicates that cannot be distinguished using X-ray diffraction analyses. A series of silicate, phyllosilicate, and Al-bearing standard compounds were also studied to provide an explanation for the observed changes in the clay samples. The Si XANES results indicated the preferential dissolution of the phyllosilicates (pH ? 1.0, t ? 14 d), the persistence of quartz even at pH ? −3.0 and t ? 365 d, and the formation of an amorphous silica-like phase that was confined to the surface layer of the altered clay samples at pH ? 0.0 and t ? 90 d). Al XANES results demonstrated dissolution of Al-octahedral layers (pH ? 1.0, t ? 14 d), the persistence of four-fold relative to six-fold coordinated Al, and the precipitation of an Al-SO₄-rich phase (pH ? −1.0, t ? 90 d). An existing conceptual model of phyllosilicate dissolution under extremely acidic conditions was modified to include the results of this study.     

Objectives of fisheries management: case studies from the UK, France, Spain and Denmark

The main objectives of fisheries management are generally similar throughout the world. These are often stated in policy documents such as the Common Fisheries Policy and the Magnuson–Stevens Fishery Conservation and Management Act. However, at the local level often the key objectives of management are more detailed, characterised by both the overriding management structure and the status and type of fishery concerned. In this paper, we consider case study fisheries from the UK, France, Spain and Denmark to compare some of the various types of fisheries and fisheries management systems that exist in the European Union. From this, we define the key objectives for each management system.     

Realistic survey simulations for kilometer class near Earth objects

We present a new Near Earth Object (NEO) survey simulator which incorporates the four-dimensional population model of 4668 NEOs [Bottke, W.F., Morbidelli, A., Jedicke, R., Petit, J.-M., Levison, H.F., Michel, P., Metcalfe, T.S., 2002. Icarus 156, 399-433] and the observing strategies of most asteroid search programs. With the recent expansion of survey capabilities, previous simulators focused on a specific survey facility are no longer useful in predicting the future detection rates. Our simulation is a superposition of simplified search patterns adopted by all major wide-field surveys in operation in both hemispheres. We defined five different simulation periods to follow the evolution of survey efficiencies reflecting changes in either search volume as a result of upgrades of telescopes and instruments or in observing schedules. The simulator makes remarkably good reproductions of actual survey results as of December 2005, not only the total number of detections but also (a,e,i,H) (‘H’ means absolute magnitude of an asteroid) distributions. An extended experiment provides excellent predictions for discovery statistics of NEOs (H<18) reported to the Minor Planet Center in 2006. These support that our simulator is a plausible approximation of real surveys. We further confirm that, with the Bottke et al. [Bottke, W.F., Morbidelli, A., Jedicke, R., Petit, J.-M., Levison, H.F., Michel, P., Metcalfe, T.S., 2002. Icarus 156, 399-433] population model and present survey capability, the 90% completeness level of kilometer-sized NEOs will be achieved by 2010 or 2011. However, about 8% of the kilometer-sized or larger NEOs would remain undetected even after 10-year operation (2007-2016) of all current NEO survey facilities. They are apparently faint, with orbits characterized by large semimajor axis and higher eccentricity; these “hardest-to-find” objects tend to elude the search volume of existing NEO survey facilities. Our simulation suggests that 15% of undetectable objects are Atens and Inner Earth Objects. Because of their orbital characteristics, they will remain within ±45° from the Sun, thus cannot be discovered in the forthcoming decade if our effort is limited to current ground-based telescopes.     

Observable consequences of planet formation models in systems with close-in terrestrial planets

To date, two planetary systems have been discovered with close-in, terrestrial-mass planets     . Many more such discoveries are anticipated in the coming years with radial velocity and transit searches. Here we investigate the different mechanisms that could form 'hot Earths' and their observable predictions. Models include: (1) in situ accretion; (2) formation at larger orbital distance followed by inward 'type 1' migration; (3) formation from material being 'shepherded' inward by a migrating gas giant planet; (4) formation from material being shepherded by moving secular resonances during dispersal of the protoplanetary disc; (5) tidal circularization of eccentric terrestrial planets with close-in perihelion distances and (6) photoevaporative mass-loss of a close-in giant planet. Models 1–4 have been validated in previous work. We show that tidal circularization can form hot Earths, but only for relatively massive planets     with very close-in perihelion distances (≲0.025 au), and even then the net inward movement in orbital distance is at most only 0.1–0.15 au. For planets of less than     , photoevaporation can remove the planet's envelope and leave behind the solid core on a Gyr time-scale, but only for planets inside 0.025–0.05 au. Using two quantities that are observable by current and upcoming missions, we show that these models each produce unique signatures, and can be observationally distinguished. These observables are the planetary system architecture (detectable with radial velocities, transits and transit timing) and the bulk composition of transiting close-in terrestrial planets (measured by transits via the planet's radius).     

Testing the fidelity of thermometers at ultrahigh temperatures

A highly residual granulite facies rock (sample RG07‐21) from Lunnyj Island in the Rauer Group, East Antarctica, presents an opportunity to compare different approaches to constraining peak temperature in high‐grade metamorphic rocks. Sample RG07‐21 is a coarse‐grained pelitic migmatite composed of abundant garnet and orthopyroxene along with quartz, biotite, cordierite, and plagioclase with accessory rutile, ilmenite, zircon, and monazite. The inferred sequence of mineral growth is consistent with a clockwise pressure–temperature (P–T) evolution when compared with a forward model (P–T pseudosection) for the whole‐rock chemical composition. Peak metamorphic conditions are estimated at 9 ± 0.5 kbar and 910 ± 50°C based on conventional Al‐in‐orthopyroxene thermobarometry, Zr‐in‐rutile thermometry, and calculated compositional isopleths. U–Pb ages from zircon rims and neocrystallized monazite grains yield ages of c. 514 Ma, suggesting that crystallization of both minerals occurred towards the end of the youngest pervasive metamorphic episode in the region known as the Prydz Tectonic Event. The rare earth element compositions of zircon and garnet are consistent with equilibrium growth of these minerals in the presence of melt. When comparing the thermometry methods used in this study, it is apparent that the Al‐in‐orthopyroxene thermobarometer provides the most reliable estimate of peak conditions. There is a strong textural correlation between the temperatures obtained using the Zr‐in‐rutile thermometer––maximum temperatures are recorded by a single rutile grain included within orthopyroxene, whereas other grains included in garnet, orthopyroxene, quartz, and biotite yield a range of temperatures down to 820°C. Ti‐in‐zircon thermometry returns significantly lower temperature estimates of 678–841°C. Estimates at the upper end of this range are consistent with growth of zircon from crystallizing melt at temperatures close to the elevated (H₂O undersaturated) solidus. Those estimates, significantly lower than the calculated temperature of this residual solidus, may reflect isolation of rutile from the effective equilibration volume leading to an activity of TiO₂ that is lower than the assumed value of unity.     

Stratigraphic architecture of Solander Basin records Southern Ocean currents and subduction initiation beneath southwest New Zealand

Solander Basin is characterized by subduction initiation at the Pacific‐Australia plate boundary, where high biological productivity is found at the northern edge of the Antarctic Circumpolar Current. Sedimentary architecture results from tectonic influences on accommodation space, sediment supply and ocean currents (via physiography); and climate influence on ocean currents and biological productivity. We present the first seismic‐stratigraphic analysis of Solander Basin based on high‐fold seismic‐reflection data (voyage MGL1803, SISIE). Solander Trough physiography formed by Eocene rifting, but basinal strata are mostly younger than ca. 17 Ma, when we infer Puysegur Ridge formed and sheltered Solander Basin from bottom currents, and mountain growth onshore increased sediment supply. Initial inversion on the Tauru Fault started at ca. 15 Ma, but reverse faulting from 12 to ca. 8 Ma on both the Tauru and Parara Faults was likely associated with reorganization and formation of the subduction thrust. The new seabed topography forced sediment pathways to become channelized at low points or antecedent gorges. Since 5 Ma, southern Puysegur Ridge and Fiordland mountains spread out towards the east and Solander Anticline grew in response to ongoing subduction and growth of a slab. Solander Basin had high sedimentation rates because (1) it is sheltered from bottom currents by Puysegur Ridge; and (2) it has a mountainous land area that supplies sediment to its northern end. Sedimentary architecture is asymmetric due to the Subtropical Front, which moves pelagic and hemi‐pelagic sediment, including dilute parts of gravity flows, eastward and accretes contourites to the shelf south of Stewart Island. Levees, scours, drifts and ridges of folded sediment characterize western Solander Basin, whereas hemi‐pelagic drape and secondary gravity flows are found east of the meandering axial Solander Channel. The high‐resolution record of climate and tectonics that Solander Basin contains may yield excellent sites for future scientific ocean drilling.     

Linking biogeochemical processes and historic primary producer communities in a SE USA sinkhole lake from the mid-Holocene to present

Many freshwater resources receive materials from human development causing a decrease in ecological services when compared to pre-disturbance periods. As a result, the understanding of eutrophication and limnological change has increased, but less attention has been given to systems under intense human impact that have not eutrophied so that drivers precluding eutrophication can be documented. The primary objective of this research was to reconstruct allochthonous inputs and in-lake processes for Long Pond, Georgia, USA from the mid Holocene to present and link them to primary producer community changes. Long Pond is a mesotrophic lake located in a highly altered watershed from agricultural and municipal land use and housing developments. A 5 m sediment core was collected from Long Pond, and organic matter, nutrients (C, N, P), metals (Al, Fe, Cu), and photosynthetic pigments were measured. Long Pond existed in three limnological states spanning the past ~6000 years. Prior to modern lacustrine conditions, Long Pond was a wetland/peat system that experienced the highest primary producer abundance recorded in the core. The modern lacustrine state began in the late Holocene and was characterized by increased connectivity with the surrounding watershed and low productivity. Human impacts began around 1900 AD and included high levels of phosphorus and metal deposition but moderate levels of primary producer abundance. As a result, in-lake dynamics are believed to be regulating the trophic status of Long Pond. Low concentrations of available phosphorus in the water column combined with high concentrations of sedimentary phosphorus may imply the binding of phosphorus to the sediments by certain materials such as aluminum and iron. Long Pond serves as an example of the complex in-lake processes that can occur from allochthonous inputs and autochthonous responses in lake systems thus complicating management decisions.     

Mercury: Internal structure and thermal evolution

Astronomical observations and cosmochemical calculations suggest that the planet Mercury may be composed of materials which condensed at relatively high temperatures in the primitive solar nebula and may have a basaltic crust similar to parts of the moon. These findings, plus the long standing inference that Mercury is much richer in metallic iron than the other terrestrial planets, provide important constraints which we apply to models of the thermal evolution and density structure of the planet. The thermal history calculations include explicitly the differing thermal properties of iron and silicates and account for core segregation, melting and differentiation of heat sources, and simulated convection during melting. If the U and Th abundances of Mercury are taken from the cosmochemical model of Lewis, then the planet would have fully differentiated a metal core from the silicate mantle for all likely initial temperature distributions and heat transfer properties. Density distributions for the planet are calculated from the mean density and estimates of the present-day temperature. For the fully differentiated model, the moment of inertia C/MR² is 0.325 (J₂=0.302×10^?6). For models with lower heat source abundances, the planet may not yet have differentiated. The density profiles for such models give C/MR²=0.394 (J₂=0.487×10^?6). These results should be useful for preliminary interpretation of the Mariner 10 measurements of Mercury's gravitational field.     

Indigenous Land Management in Peri-Urban Landscapes: An Australian Example

This article examines roles, opportunities, and challenges for Indigenous land management in rapidly developing landscapes through a case study of Bunya Bunya Country Aboriginal Corporation, a not-for-profit organization on the Sunshine Coast, Queensland, Australia. An analysis of data collected through semistructured interviews, participant observation, and analysis of secondary sources reveals that Aboriginal land managers work in a variety of roles to manage issues affecting the local environment and cultural heritage sites. These efforts are challenged by the absence of Native Title and colonial land management policies, which restrict Aboriginal involvement in land management. We conclude that there is a need for alternative pathways to engage with Aboriginal land managers who cannot, or choose not to, proceed with Native Title. Decolonized decision-making tools and sustainable enterprises are viable opportunities that partially address these challenges and could deliver tangible socio-economic and cultural benefits to local Aboriginal and non-Aboriginal people.