Gas saturation prediction and effect of low frequencies on acoustic impedance images at Foinaven Field

Low frequencies are necessary in seismic data for proper acoustic impedance imaging and for petrophysical interpretation. Without lower frequencies, images can be distorted leading to incorrect reservoir interpretation and petrophysical predictions. As part of the Foinaven Active Reservoir Management (FARM) project, a Towed Streamer survey and an Ocean Bottom Hydrophone (OBH) survey were shot in both 1995 and 1998. The OBH surveys contain lower frequencies than the streamer surveys, providing a unique opportunity to study the effects that low frequencies have on both the acoustic impedance image along with petrophysical time‐lapse predictions. Artefacts that could easily have been interpreted as high‐resolution features in the streamer data impedance volumes can be distinguished by comparison with the impedance volumes created from the OBH surveys containing lower frequencies. In order to obtain results from the impedance volumes, impedance must be related to saturation. The mixing of exsolved gas, oil and water phases involves using the Reuss (uniform) or Voigt (patchy approximation) mixing laws. The Voigt average is easily misused by assuming that the end‐points correspond to 0% and 100% gas saturation. This implies that the patches are either 0% gas saturation or 100% gas saturation, which is never the case. Here, the distribution of gas as it comes out of solution is assumed to be uniform until the gas saturation reaches a sufficiently high value (critical gas saturation) to allow gas to flow. Therefore, at low gas saturations the distribution is uniform, but at saturations above critical, it is patchy, with patches that range from critical gas saturation to the highest gas saturation possible (1 minus residual oil and irreducible water saturation).     

Elevation of the olivine-spinel transition in subducted lithosphere: Seismic evidence

The top of the olivine-spinel phase change in subducted oceanic lithosphere can be located by the travel times of seismic waves which have propagated through the slab. P-wave travel-time residuals from deep earthquakes in the Tonga island are observed at Australian seismic stations are grouped according to the depth of the earthquake. The change in mean residual with a change in earthquake depth is related to the velocity contrast between slab and normal mantle at that depth. The curve mean residual versus earthquake depth displays a region of markedly increased slope between earthquake depths of about 250 and 350 km. The most probable explanation of this observation is an elevation by 100 km of the olivine-spinel phase change within the relatively cooler slab. No evidence was found for vertical displacements within the slab of any deeper phase changes.A temperature contrast between slab and normal mantle of about 1,000°C at 250 km depth is implied. This finding confirms current thermal models for subducted lithosphere but is inconsistent with the global intraplate stress field unless only a few percent of the negative buoyancy force at subduction zones is transmitted to the surface plates.     

Post-peak,fluid-mediated modification of granulite facies zircon and monazite in the Trivandrum Block,southern India

The quarry at Kottavattom in the Trivandrum Block of southern India contains spectacular examples of fluid-assisted alteration of high-grade metamorphic rocks. Garnet-biotite gneiss has undergone a change in mineral assemblage to form submetre scale orthopyroxene-bearing patches, later retrogressed to form an amphibole-bearing lithology. These patches, often referred to as arrested or incipient charnockite, crosscut the original metamorphic foliation and are typically attributed to passage of a low aH₂O fluid through the rock. Whilst this conversion is recognised as a late stage process, little detailed chronological work exists to link it temporally to metamorphism in the region. Zircon and monazite analysed from Kottavattom not only record metamorphism in the Trivandrum Block but also show internal, lobate textures crosscutting the original zoning, consistent with fluid-aided coupled dissolution-reprecipitation during formation of the orthopyroxene-bearing patches. High-grade metamorphism at the quarry occurred between the formation of metamorphic monazite at ~585 Ma and the growth of metamorphic zircon at ~523 Ma. The fluid-assisted alteration of the garnet-biotite gneiss is poorly recorded by altered zircon with only minimal resetting of the U–Pb system, whereas monazite has in some cases undergone complete U–Pb resetting and records an age for fluid infiltration at ~495 Ma. The fluid event therefore places the formation of the altered patches at least 25 Myr after the zircon crystallisation in the garnet-biotite gneiss. The most likely fluid composition causing the modification and U–Pb resetting of zircon and monazite is locally derived hypersaline brine.     

Solubility of plutonium(VI) carbonate in saline solutions

Among the plutonium oxidation states found to form in the environment, mobile plutonium(VI) can exist under oxidizing conditions and in waters with high chloride content due to radiolysis effects. We are investigating the solubility and speciation of plutonium(VI) carbonate under conditions relevant to natural waters and brines such as those found near some geologic radioactive waste repositories. The solid Pu(VI) phase PuO₂CO₃(s) was prepared and its solubility was measured in NaCl and NaClO₄ solutions in a CO₂ atmosphere as a function of pH and ionic strength (0.1-5.6 m). The concentration of soluble plutonium in solution was calculated from spectroscopic data and liquid scintillation counting. Spectroscopic measurements also revealed the plutonium oxidation state. The apparent solubility product of PuO₂CO₃(s) was determined at selected electrolyte concentrations to be, log K_s,0 = −13.95 ± 0.07 (0.1 m NaCl), log K_s,0 = −14.07 ± 0.13 (5.6 m NaCl), and log K_s,0 = −15.26 ± 0.11 (5.6 m NaClO₄). Specific ion interaction theory was used to calculate the solubility product at zero ionic strength, .     

The High-Resolution Coronal Imager (Hi-C)

The High-Resolution Coronal Imager (Hi-C) was flown on a NASA sounding rocket on 11 July 2012. The goal of the Hi-C mission was to obtain high-resolution (≈?0.3?–?0.4′′), high-cadence (≈?5 seconds) images of a solar active region to investigate the dynamics of solar coronal structures at small spatial scales. The instrument consists of a normal-incidence telescope with the optics coated with multilayers to reflect a narrow wavelength range around 19.3 nm (including the Fe xii 19.5-nm spectral line) and a 4096×4096 camera with a plate scale of 0.1′′?pixel^?1. The target of the Hi-C rocket flight was Active Region 11520. Hi-C obtained 37 full-frame images and 86 partial-frame images during the rocket flight. Analysis of the Hi-C data indicates the corona is structured on scales smaller than currently resolved by existing satellite missions.     

Determination of the properties of Mercury's magnetic field by the MESSENGER mission

The MESSENGER mission to Mercury, to be launched in 2004, will provide an opportunity to characterize Mercury's internal magnetic field during an orbital phase lasting one Earth year. To test the ability to determine the planetary dipole and higher-order moments from measurements by the spacecraft's fluxgate magnetometer, we simulate the observations along the spacecraft trajectory and recover the internal field characteristics from the simulated observations. The magnetic field inside Mercury's magnetosphere is assumed to consist of an intrinsic multipole component and an external contribution due to magnetospheric current systems described by a modified Tsyganenko 96 model. Under the axis-centered-dipole approximation without correction for the external field the moment strength is overestimated by ∼4% for a simulated dipole moment of , and the error depends strongly on the magnitude of the simulated moment, rising as the moment decreases. Correcting for the external field contributions can reduce the error in the dipole term to a lower limit of ∼1-2% without a solar wind monitor. Dipole and quadrupole terms, although highly correlated, are then distinguishable at the level equivalent to an error in the position of an offset dipole of a few tens of kilometers. Knowledge of the external magnetic field is therefore the primary limiting factor in extracting reliable knowledge of the structure of Mercury's magnetic field from the MESSENGER observations.     

Local hydraulic gradient estimator analysis of long-term monitoring networks

Three measurements of head at unique locations form a three-point estimator of the local magnitude and orientation of the hydraulic gradient. The relative head measurement error (RHME) is defined here as the measurement error normalized by the head drop across the three-point estimator. Monte Carlo simulation results show that estimators with base to height ratios between 0.5 and 5.0 and that are large enough to keep the RHME below 0.05 create the most accurate gradient estimates and provide criteria for identifying good estimators. These criteria are applied to an example ground water monitoring network design problem in the Culebra dolomite near the Waste Isolation Pilot Plant repository to both analyze temporal changes and modify and expand the current monitoring network. Limiting the three-point estimators to those that meet the shape and RHME criteria reduces the number of possible estimators by >50% and leads to approximately 1 order of magnitude decrease in the average estimated magnitude of the gradient relative to using all estimators. Application of these criteria also reduces the variability in estimated gradient magnitude and orientation between the two time periods of measurements. Redundant wells in the network are identified by removing each existing well in turn and determining which removals yield the smallest decrease in the number of acceptable estimators. Optimal new well locations are identified by mapping the increase in total number of acceptable estimators for a single new well placed in the study domain.     

The diverse nature of optical emission lines in brightest cluster galaxies: IFU observations of the central kiloparsec

We present integral field spectroscopy of the nebular line emission in a sample of nine brightest cluster galaxies (BCGs). The sample was chosen to probe both cooling flow and non-cooling flow clusters, as well as a range of cluster X-ray luminosities. The line emission morphology and velocity gradients suggest a great diversity in the properties of the line emitting gas. While some BCGs show evidence for filamentary or patchy emission (Abell 1060, Abell 1668 and MKW 3s), others have extended emission (Abell 1204, Abell 2199), while still others have centrally concentrated emission (Abell 2052). We examine diagnostic line ratios to determine the dominant ionization mechanisms in each galaxy. Most of the galaxies show regions with active galactic nucleus like spectra, however, for two BCGs, Abell 1060 and Abell 1204, the emission line diagnostics suggest regions which can be described by the emission from young stellar populations. The diversity of emission-line properties in our sample of BCGs suggests that the emission mechanism is not universal, with different ionization processes dominating different systems. Given this diversity, there is no evidence for a clear distinction of the emission-line properties between cooling flow and non-cooling flow BCGs. It is not always cooling flow BCGs which show emission (or young stellar populations), and non-cooling flow BCGs which do not.