Carbon dioxide on the satellites of Saturn: Results from the Cassini VIMS investigation and revisions to the VIMS wavelength scale

Several of the icy satellites of Saturn show the spectroscopic signature of the asymmetric stretching mode of C-O in carbon dioxide (CO₂) at or near the nominal solid-phase laboratory wavelength of 4.2675 μm (2343.3 cm⁻¹), discovered with the Visible-Infrared Mapping Spectrometer (VIMS) on the Cassini spacecraft. We report here on an analysis of the variation in wavelength and width of the CO₂ absorption band in the spectra of Phoebe, Iapetus, Hyperion, and Dione. Comparisons are made to laboratory spectra of pure CO₂, CO₂ clathrates, ternary mixtures of CO₂ with other volatiles, implanted and adsorbed CO₂ in non-volatile materials, and ab initio theoretical calculations of CO₂ * nH₂O. At the wavelength resolution of VIMS, the CO₂ on Phoebe is indistinguishable from pure CO₂ ice (each molecule’s nearby neighbors are also CO₂) or type II clathrate of CO₂ in H₂O. In contrast, the CO₂ band on Iapetus, Hyperion, and Dione is shifted to shorter wavelengths (typically ∼4.255 μm (∼2350.2 cm⁻¹)) and broadened. These wavelengths are characteristic of complexes of CO₂ with different near-neighbor molecules that are encountered in other volatile mixtures such as with H₂O and CH₃OH, and non-volatile host materials like silicates, some clays, and zeolites. We suggest that Phoebe’s CO₂ is native to the body as part of the initial inventory of condensates and now exposed on the surface, while CO₂ on the other three satellites results at least in part from particle or UV irradiation of native H₂O plus a source of C, implantation or accretion from external sources, or redistribution of native CO₂ from the interior.The analysis presented here depends on an accurate VIMS wavelength scale. In preparation for this work, the baseline wavelength calibration for the Cassini VIMS was found to be distorted around 4.3 μm, apparently as a consequence of telluric CO₂ gas absorption in the pre-launch calibration. The effect can be reproduced by convolving a sequence of model detector response profiles with a deep atmospheric CO₂ absorption profile, producing distorted detector profile shapes and shifted central positions. In a laboratory blackbody spectrum used for radiance calibration, close examination of the CO₂ absorption profile shows a similar deviation from that expected from a model. These modeled effects appear to be sufficient to explain the distortion in the existing wavelength calibration now in use. A modification to the wavelength calibration for 13 adjacent bands is provided. The affected channels span about 0.2 μm centered on 4.28 μm. The maximum wavelength change is about 10 nm toward longer wavelength. This adjustment has implications for interpretation of some of the spectral features observed in the affected wavelength interval, such as from CO₂, as discussed in this paper.     

Whole-disk spectrophotometric properties of Mercury: Synthesis of MESSENGER and ground-based observations

Disk-integrated and disk-resolved measurements of Mercury’s surface obtained by both the Mercury Dual Imaging System (MDIS) and the Mercury Atmospheric and Surface Composition Spectrometer (MASCS) onboard the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft were analyzed and compared with previous ground-based observations of Mercury at 11 wavelengths. The spectra show no definitive absorption features and display a red spectral slope (increasing reflectance with increasing wavelength) typical of space-weathered rocky surfaces. The MDIS spectra show evidence of phase reddening, which is not observed in the MASCS spectra. The MDIS spectra are commensurate with ground-based observations to within 10%, whereas the MASCS spectra display greater discrepancies with ground-based observations at near-infrared wavelengths. The derived photometric calibrations provide corrections within 10% for observations taken at phase angles less than ∼100°. The derived photometric properties are indicative of a more compact regolith than that of the lunar surface or of average S-type asteroids. The photometric roughness of the surface is also much smoother than the Moon’s. The calculated geometric albedo (reflectance at zero phase) is higher than lunar values. The lower reflectance of immature units on Mercury compared with immature units on the Moon, in conjunction with the higher geometric albedo, is indicative of more complicated grain structures within Mercury’s regolith.     

The Impact of New EUV Diagnostics on CME-Related Kinematics

We present the application of novel diagnostics to the spectroscopic observation of a Coronal Mass Ejection (CME) on disk by the Extreme Ultraviolet Imaging Spectrometer (EIS) on the Hinode spacecraft. We apply a recently developed line profile asymmetry analysis to the spectroscopic observation of NOAA AR 10930 on 14?–?15 December 2006 to three raster observations before and during the eruption of a 1000 km?s^?1 halo CME. We see the impact that the observer’s line-of-sight and magnetic field geometry have on the diagnostics used. Further, and more importantly, we identify the on-disk signature of a high-speed outflow behind the CME in the dimming region arising as a result of the eruption. Supported by recent coronal observations of the STEREO spacecraft, we speculate about the momentum flux resulting from this outflow as a secondary momentum source to the CME. The results presented highlight the importance of spectroscopic measurements in relation to CME kinematics, and the need for full-disk synoptic spectroscopic observations of the coronal and chromospheric plasmas to capture the signature of such explosive energy release as a way of providing better constraints of CME propagation times to L1, or any other point of interest in the heliosphere.     

The chemical composition of the Sun

We present a redetermination of the solar abundances of all available elements. The new results have very recently been published by Asplund et al. (Annu. Rev. Astron. Astrophys. 47:481, 2009). The basic ingredients of this work, the main results and some of their implications are summarized hereafter.     

A rare reflection effect eclipsing sdB+dM binary: 2M 1533+3759

In this paper, we report a rare reflection effect eclipsing sdB+dM binary, 2M?1533+3759. It is the seventh eclipsing sdB+dM binary that has been discovered to date. This system has an orbital period of 0.16177042 day and a velocity semi-amplitude of 71.1 km?s^?1. Using a grid of zero-metallicity NLTE model atmospheres, we derived T _eff=29250 K, log?g=5.58 and [He/H]=?2.37 from spectra taken near the reflection effection minimum. Lightcurve modeling resulted in a system mass ratio of 0.301 and an orbital inclination angle of 86.6°. The derived primary mass for 2M?1533+3759, 0.376±0.055 M _⊙, is significantly lower than the canonical mass (0.48 M _⊙) found for most previously investigated sdB stars. This implies an initial progenitor mass >1.8 M _⊙, at least a main sequence A star and perhaps even one massive enough to undergo non-degenerate helium ignition.     

Gemini-N mid-IR observations of the dust properties of the ejecta excavated from Comet 9P/Tempel 1 during Deep Impact

We present mid-infrared spectra and images from the Gemini-N (+MICHELLE) observational campaign of Comet 9P/Tempel 1 before, during, and after its encounter with Deep Impact. We use our thermal grain model to probe the 10 μm properties of the dust grains in the coma of the comet. Before impact (3 July 2005 UT), and more than 24 h after impact (5, 16, and 28 July 2005 UT), the comet dust grains were composed mostly of amorphous olivine, and were relatively large (peak of the grain size distribution ). For the night of impact, we extract spectra by centering on the nucleus, and offset 1″ from the nucleus in the direction of the impact ejecta plume. We find small dust grains (∼0.2 μm) of a diverse mineralogy (amorphous olivine, amorphous pyroxene, amorphous carbon, and crystalline olivine) populating the ejecta. The submicron sized dust grains move faster than the other, larger grains (?0.7 μm), with amorphous olivine and amorphous carbon traveling together, and amorphous pyroxene and crystalline olivine dispersing at a similar rate. Deriving a velocity law from a time-of-flight analysis, we find that the material traveled with a velocity law scaled by and with a power of p=0.5. This velocity power-law requires a sustained release of grains for the duration of 45-60 min after impact. Since the mineral species are traveling at different speeds, and there was a sustained release of grains due to a possible “gas-plume,” we conclude that the different minerals did not originate from grain aggregates destroyed by the impact, but instead arise from an inhomogeneous nucleus.     

翼龙类和驰龙类尾的前关节突和脉弧棒的趋同演化及翼龙类和鸟类尾部肌肉退化的平行模式

The caudal morphology of dromaeosaurid dinosaurs and most “rhamphorhynchoid” pterosaurs is a striking example of convergent evolution. In both groups, all but the most anterior five to seven caudal vertebrae have postzygopophyses that are elongate, equaling or exceeding the corresponding centra in length, and have bifurcating rod-shaped prezygopophyses that extend as much as seven times the length of the corresponding centra.     

Paleofire reconstruction for high-elevation forests in the Sierra Nevada, California, with implications for wildfire synchrony and climate variability in the late Holocene

Here, we present two high-resolution records of macroscopic charcoal from high-elevation lake sites in the Sierra Nevada, California, and evaluate the synchroneity of fire response for east- and west-side subalpine forests during the past 9200 yr. Charcoal influx was low between 11,200 and 8000 cal yr BP when vegetation consisted of sparse Pinus-dominated forest and montane chaparral shrubs. High charcoal influx after ∼ 8000 cal yr BP marks the arrival of Tsuga mertensiana and Abies magnifica, and a higher-than-present treeline that persisted into the mid-Holocene. Coeval decreases in fire episode frequency coincide with neoglacial advances and lower treeline in the Sierra Nevada after 3800 cal yr BP. Independent fire response occurs between 9200 and 5000 cal yr BP, and significant synchrony at 100- to 1000-yr timescales emerges between 5000 cal yr BP and the present, especially during the last 2500 yr. Indistinguishable fire-return interval distributions and synchronous fires show that climatic control of fire became increasingly important during the late Holocene. Fires after 1200 cal yr BP are often synchronous and corroborate with inferred droughts. Holocene fire activity in the high Sierra Nevada is driven by changes in climate linked to insolation and appears to be sensitive to the dynamics of the El Niño-Southern Oscillation.     

Spatial and Temporal Variability of Benthic Oxygen Demand and Nutrient Regeneration in an Anthropogenically Impacted New England Estuary

Strong benthic–pelagic coupling is an important characteristic of shallow coastal marine ecosystems. Building upon a rich history of benthic metabolism data, we measured oxygen uptake and nutrient fluxes across the sediment–water interface along a gradient of water column primary production in Narragansett Bay, RI (USA). Despite the strong gradients seen in water column production, sediment oxygen demand (SOD) and benthic nutrient fluxes did not exhibit a clear spatial pattern. Some of our sites had been studied in the 1970s and 1980s and thus allowed historical comparison. At these sites, we found that SOD and benthic fluxes have not changed uniformly throughout Narragansett Bay. In the uppermost portion of the bay, the Providence River Estuary, we observed a significant decrease in dissolved inorganic phosphorus fluxes which we attribute to management interventions. At another upper bay site, we observed significant declines in SOD and dissolved inorganic nitrogen fluxes which may be linked to climate-induced decreases in water column primary production and shifts in bloom phenology. In the 1970s, benthic nutrient regeneration supplied 50% to over 200% of the N and P needed to support primary production by phytoplankton. Summer nutrient regeneration in the Providence River Estuary and Upper bay now may only supply some 5–30% of the N and 3–20% of the P phytoplankton demand.