Experimental calibration of the sphalerite cosmobarometer

The pressure and temperature dependence of the composition of sphalerite in equilibrium with troilite + metallic iron has been determined experimentally at 2.5 and 5.0 kbar between 400° and 800°C using both the aqueous and anhydrous alkali halide flux recrystallization techniques. The measured pressure effect is larger than that calculated by us and by Schwarczet al. (1975a), and is described by the equation (T in Kelvins), P (kbar) = ?3.576 + 0.0551T ?0.0296Tlogmole % FeS.Assuming temperatures of final equilibration between sphalerite and troilite of 350°C for iron meteorites and 600°C for enstatite chondrites, published analyses of sphalerites provide estimates of pressures of formation and possible radii of parent objects of meteorites as follows: IA irons (Landes, Sardis, Gladstone, Bogou, Odessa, Toluca) 0.0 to 3.5 kbar, 0 to 442 km; E6 enstatite chondrites (Yilmia, Pillistfer) ?0.2 to 0.7 kbar, 0 to 198 km.     

The Zymoetz River landslide, British Columbia, Canada: description and dynamic analysis of a rock slide–debris flow

The Zymoetz River landslide is a recent example of an extremely mobile type of landslide known as a rock slide–debris flow. It began as a failure of 900,000 m³ of bedrock, which mobilized an additional 500,000 m³ of surficial material in its path, transforming into a large debris flow that traveled over 4 km from its source. Seasonal snow and meltwater in the proximal part of the path were important factors. A recently developed dynamic model that accounts for material entrainment, DAN3D, was used to back-analyze this event. The two distinct phases of motion were modeled using different basal rheologies: a frictional model in the proximal path and a Voellmy model in the distal path, following the initiation of significant entrainment. Very good agreement between the observed and simulated results was achieved, suggesting that entrainment capabilities are essential for the successful simulation of this type of landslide.     

Fault-induced perturbed stress fields and associated tensile and compressive deformation at fault tips in the ice shell of Europa: implications for fault mechanics

Secondary fractures at the tips of strike-slip faults are common in the ice shell of Europa. Large magnitude perturbed stress fields must therefore be considered to be a viable driving mechanism for the development of part of the fracture sequence. Fault motions produce extensional and compressional quadrants around the fault tips. Theoretically, these quadrants can be associated with tensile and compressive deformational features (i.e. cracks and anti-cracks), respectively. Accordingly, we describe examples of both types of deformation at fault tips on Europa in the form of extensional tailcracks and compressional anti-cracks. The characteristics of these features with respect to the plane of the fault create a fingerprint for the mechanics of fault slip accumulation when compared with linear elastic fracture mechanics (LEFM) models of perturbed stress fields around fault tips. Tailcrack kink angles and curving geometry can be used to determine whether opening accompanies sliding motion. Kink angles in the 50–70° range are common along strike-slip faults that resemble ridges, and indicate that little to no opening accompanied sliding. In contrast, tailcrack kink angles are closer to 30° for strike-slip faults that resemble bands, with tailcrack curvatures opposite to ridge-like fault examples, indicating that these faults undergo significant dilation and infill during fault slip episodes. Anti-cracks, which may result from compression and volume reduction of porous near-surface ice, have geometries that further constrain fault motion history, corroborating the results of tailcrack analysis. The angular separation between anti-cracks and tailcracks are similar to LEFM predictions, indicating the absence of cohesive end-zones near the tips of Europan faults, hence suggesting homogeneous frictional properties along the fault length. Tailcrack analysis can be applied to the interpretation of cycloidal ridges: chains of arcuate cracks on Europa that are separated by sharp kinks called cusps. Cusp angles are reminiscent of tailcrack kink angles along ridge-like strike-slip faults. Cycloid growth in a temporally variable tidal stress field ultimately resolves shear stresses onto the near-tip region of a growing cycloid segment. Thus, resultant slip and associated tailcrack development may be the driving force behind the initiation of the succeeding arcuate segment, hence facilitating the ongoing propagation of the cycloid chain.     

Recent Summer Climate Recorded in Complex Varved Sediments, Nicolay Lake, Cornwall Island, Nunavut, Canada

The recent (1950–1996) varve record from the proximal sediments in Nicolay Lake, Cornwall Island, Nunavut, Canada (77°46′ N, 94°40′ W) contains distinct subannual rhythmites. Deposition of these subannual rhythmites is due primarily to nival snow melt, with additional sedimentary units resulting from major summer precipitation and subaqueous mass wasting events. In order to evaluate the potential hydroclimatic signal contained in the varves from the unglacierized catchment, the nival deposition record was estimated by delineating the initial subannual rhythmite within each varve. When the record is split into temporal segments based on two phases that exhibit different sediment deposition patterns in the lake, the nival rhythmites are significantly correlated to annual cumulative melting degree days (MDD) from the nearest weather station Isachsen (78°47′ N, 103°32′ W) (1950–1962 AD and 1963–1977 AD with r = 0.55 and r = 0.82, respectively). A similar analysis with data from Resolute (74°43′ N, 94°59′ W) yields slightly weaker correlations (1950–1962 AD, r = 0.60; 1963–1994, r = 0.59). The strong positive correlation with both the Isachsen and Resolute thermal records suggests that the paleoclimatic signal in the sediments reflects regional climate conditions. Notably, the signal is strongest when the entire melt season is considered; weaker correlations with instrumental weather records are associated with comparisons limited to the peak melt or early season melt periods. We attribute this to the ongoing supply of snowmelt through the season in this polar region and the availability of sediment for transport throughout the melt season. These results indicate that a high resolution hydroclimatic signal is present in the sediments from Nicolay Lake and can be used for paleoclimate reconstruction provided sedimentary depositional controls are taken into account.     

Influences of the Gulf of Maine intrusion on the Massachusetts Bay spring bloom: A comparison between 1998 and 2000

The Boston Harbor, Massachusetts Bay and Cape Cod Bay system (MBS) is a semi-enclosed coastal embayment located in the western Gulf of Maine (GOM). The strength of the spring bloom in the MBS varies dramatically and the underlying mechanisms are not well understood. It has been hypothesized that the weak (or missing) 1998 spring bloom was due to increased zooplankton grazing pressure after a relatively warmer winter that led to earlier development of zooplankton populations. However, chlorophyll concentrations were low in the entire GOM region during the spring bloom period of 1998. These low chlorophyll waters would enter the MBS by persistent intrusion from the GOM and affect the MBS spring bloom by reducing the accumulation of phytoplankton biomass, suggesting an alternative explanation for the missing bloom. In this study, the influences of the intruding GOM waters on the MBS spring bloom are examined using numerical simulations and observations to compare two contrasting spring blooms (a weak bloom in 1998 versus a strong bloom in 2000). The results indicate that intruding waters from the GOM significantly reduced the strength of spring bloom in 1998, but enhanced the spring bloom in 2000. A theoretical analysis suggests that the influence of the intrusion on the MBS spring bloom is mostly limited to the northern portion of the MBS, and the impact area is determined by local net growth, velocity of intruding flow and horizontal mixing. The intrusion of GOM waters carries the signal of long-term variability in the GOM region and thus may be an important oceanic pathway for climate changes to impact the MBS ecosystem.     

Effects of hydrothermal alteration on Pb in the active PACMANUS hydrothermal field, ODP Leg 193, Manus Basin, Papua New Guinea: A LA-ICP-MS study

The conventional model of leaching volcanic rocks as a source of metals in a seafloor hydrothermal systems has been tested by examining the behavior of Pb and other trace elements during hydrothermal alteration. ODP Leg 193 drill sites 1188 (Snowcap) and 1189 (Roman Ruins) on Pual Ridge in the eastern Manus Basin offshore eastern Papua New Guinea provide a unique three-dimensional window into an active back-arc hydrothermal system. We investigate by means of a LA-ICP-MS microbeam technique the capacity of Pb to be leached from a host volcanic rock exposed to various types and intensities of alteration. Our results are in general agreement with previous studies that utilized bulk analytical techniques but provide a more detailed explanation of the processes.Fresh representative dacitic lavas from the Pual Ridge have an average whole rock Pb content of 5.2 ppm, an average interstitial glass Pb content of 5.6 ppm and an average plagioclase Pb content of 1.0 ppm. Altered matrix samples have highly variable Pb values ranging from 0 to 52.4 ppm. High Pb values in altered samples are associated with a low temperature chlorite and clay mineral assemblage, in some cases overprinted by a high temperature (up to 350 °C) silica-rich “bleaching” alteration. Only the most highly altered matrix samples have REE patterns that differ from the fresh Pual Ridge dacite. This may represent either different lava histories or alteration characteristics that have affected normally immobile REEs. Altered samples with the highest Pb values have similar REE patterns to those of the local unaltered lavas. They are compositionally similar to typical Pual Ridge dacites indicating a genetic relationship between the main regional volcanic suite and the subseafloor hydrothermally altered, Pb-enriched material.Relative loss/gain for Pb between the analyzed altered samples and a calculated precursor show a maximum relative gain of 901%. Samples with relative Pb gain from both drill sites are associated with lower temperature alteration mineral assemblages characterized by pervasive chloritization. The related lower temperature (220-250 °C) neutral to slightly acidic fluids have been ascribed by others to return circulation of hydrothermal fluids that did not interact with seawater. Because altered samples have a higher Pb content than the fresh precursor, leaching of fresh volcanic rocks cannot be the source of Pb in the hydrothermal systems.     

Predicting selenite adsorption by soils using soil chemical parameters in the constant capacitance model

The constant capacitance model, a chemical surface complexation model, was applied to selenite, Se(IV), adsorption on 36 soils selected for variation in soil chemical properties. The constant capacitance model was able to fit Se(IV) adsorption by optimizing one monodentate Se(IV) surface complexation constant and the surface protonation constant. A general regression model was developed for predicting these surface complexation constants for Se(IV) from easily measured soil chemical characteristics. These chemical properties were inorganic carbon content, organic carbon content, iron oxide content, aluminum oxide content, and surface area. The prediction equations were used to obtain values for the surface complexation constants for four additional soils, thereby providing a completely independent evaluation of the ability of the constant capacitance model to describe Se(IV) adsorption. The model’s ability to predict Se(IV) adsorption was quantitative on one soil and semi-quantitative on three soils. Incorporation of these prediction equations into chemical speciation-transport models will allow simulation of soil solution Se(IV) concentrations under diverse non-calcareous agricultural and environmental conditions without the requirement of soil specific adsorption data and subsequent parameter optimization.     

Geochemistry and morphology of metalliferous sediments and oxyhydroxides from the Endeavour segment, Juan de Fuca Ridge

We present first data on the geochemistry, mineralogy and morphology of near-vent sediments (35 and 200 m from active vent) and ridge flank sediments (approximately 3 km from the vent field) as well as oxyhydroxide deposits from the Endeavour segment, Juan de Fuca Ridge. The purpose of the study was to understand better the origin and characteristic features of metalliferous sediments associated with base and precious metal massive sulfides in volcanic terrains. Hydrothermal components in sediments are Fe-Si ± S-rich and Mn-Fe-Si-rich phases, sulfides and barite, which were exclusively derived from plume fallout. Sulfides are only a minor constituent of near-vent sediments (2-4 wt%) and were not detected in ridge flank sediments. The study suggests that the distribution of hydrothermal phases and associated elements in near-vent and ridge flank sediments is affected mainly by processes of agglomeration, dissolution, absorption and settling that take place within a plume and to a lesser extent post-depositional processes. Rapid deposition of sulfides in the vicinity of the vents is reflected in a sharp drop of the Cu concentrations in sediments with increasing distance from the vents. Besides sulfides, important carriers of Pb, Cu, Zn and Co in near-vent sediments are Fe-Mn oxyhydroxides that occur together with silica as aggregates of gel-like material and flaky particles and as coatings on filaments. Away from the vents, trace metals are mostly in Fe-Mn oxyhydroxides and authigenic Fe-rich montmorillonite. Oxyhydroxides at the Main Endeavour field are interpreted to have originated from oxidation of mound sulfides accompanied by precipitation of primary Fe-oxyhydroxide + silica from low-temperature fluids. At the Mothra field, seafloor deposits and chimney crusts composed of Fe-oxyhydroxide ± Mn + silica are considered to be direct precipitates from hydrothermal fluids that have been less diluted with seawater. Oxyhydroxide deposits exhibit unique microtextures that resemble mineralized microorganisms and may indicate existence of diverse microbial communities.