Sediment distribution and transport across the continental shelf and slope under idealized wind forcing

Resuspension, transport, and deposition of sediments over the continental shelf and slope are complex processes and there is still a need to understand the underlying spatial and temporal dynamical scales. As a step towards this goal, a two-dimensional slice model (zero gradients in the alongshore direction) based on the primitive flow equations and a range of sediment classes has been developed. The circulation is forced from rest by upwelling or downwelling winds, which are spatially uniform. Results are presented for a range of wind speeds and sediment settling speeds. Upwelling flows carry fine sediments (low settling speeds) far offshore within the surface Ekman layer, and significant deposition eventually occurs beyond the shelf break. However, coarser sediments quickly settle out of the deeper onshore component of the circulation, which can lead to accumulation of bottom sediments within the coastal zone. Downwelling flows are more effective at transporting coarse sediments off the shelf. However, strong vertical mixing at the shelf break ensures that some material is also carried into the surface Ekman layer and returned onshore. The concentrations and settling fluxes of coarse sediments decrease offshore and increase with depth under both upwelling and downwelling conditions, consistent with trends observed in sediment trap data. However, finer sediments decrease with depth (upwelling) or reach a maximum around the depth of the shelf break (downwelling). It is shown that under uniform wind conditions, suspended sediment concentrations and settling fluxes decay offshore over a length scale of order τ_s/ρf|w_s|, where τ_s is the wind stress, ρ the water density, f the Coriolis parameter, and w_s is the sediment settling velocity. This scaling applies to both upwelling and downwelling conditions, provided offshore transport is dominated by wind-driven advection, rather than horizontal diffusion.     

Linear free energy techniques for estimation of metal sulfide complexation constants

Unknown sulfide complex formation constants have been estimated through linear free energy comparisons of known values with sulfide solubility products, and with reactions of the model ligand dithizone. Results of the two techniques are in agreement for complexes of the +2 metals with two sulfide ligands. Data are currently insufficient to establish a slope for free energy lines relating single ligand +2 complexes. Alternative methods for deducing single ligand formation include interpolation across oxidation states and correlation of bisulfide formation constants with the analogous hydroxide values. By linear free estimates, several trace metals speciate predominantly as sulfide complexes over the bisulfide concentration ranges calculated from carbonyl sulfide hydrolysis in the mixed layer. Recent preliminary measurements of total dissolved sulfide confirm this result for Cu, and perhaps also Hg.     

Cadmium bioconcentration in the echinoid Paracentrotus lividus: Influence of the cadmium concentration in seawater

Uptake and loss kinetics of cadmium were studied in Paracentrotus lividus exposed for 24 d to different stable Cd concentrations (0 to 1.14 μg Cd l⁻¹) and ¹⁰⁹Cd tracer added to seawater. The whole-body uptake kinetics were linear over the time course of the experiment. The whole-body ¹⁰⁹Cd concentration factor was independent of the stable Cd concentration in ambient seawater. Bioconcentration of Cd in whole individuals and their body compartments was directly proportional to the Cd concentration added to the seawater. The echinoid digestive tract wall showed the highest degree of Cd uptake. Whole-body loss kinetics were described by a 2-component exponential equation. The loss kinetics were similar for each of the treatments examined. Cadmium was found to display a long biological half-life in echinoid tissues; the major fraction (73 to 85%) of the Cd taken up by echinoids was eliminated following a loss component whose biological half-life was of the order of 1 year, regardless of the absolute Cd concentration accumulated by the echinoid. Paracentrotus lividus is suggested as a valuable biomonitor of Cd, particularly where knowledge of Cd concentration variations over long-term is of interest.     

Seasonal variations of the ocean surface circulation in the vicinity of Palau

The surface circulation in the western equatorial Pacific Ocean is investigated with the aim of describing intra-annual variations near Palau (134°30′ E, 7°30′ N). In situ data and model output from the Ocean Surface Currents Analysis—Real-time, TRIangle Trans-Ocean buoy Network, Naval Research Laboratory Layered Ocean Model and the Joint Archive for Shipboard ADCP are examined and compared. Known major currents and eddies of the western equatorial Pacific are observed and discussed, and previously undocumented features are identified and named (Palau Eddy, Caroline Eddy, Micronesian Eddy). The circulation at Palau follows a seasonal variation aligned with that of the Asian monsoon (December–April; July–October) and is driven by the major circulation features. From December to April, currents around Palau are generally directed northward with speeds of approximately 20 cm/s, influenced by the North Equatorial Counter-Current and the Mindanao Eddy. The current direction turns slightly clockwise through this boreal winter period, due to the northern migration of the Mindanao Eddy. During April–May, the current west of Palau is reduced to 15 cm/s as the Mindanao Eddy weakens. East of Palau, a cyclonic eddy (Palau Eddy) forms producing southward flow of around 25 cm/s. The flow during the period July to September is disordered with no influence from major circulation features. The current is generally northward west of Palau and southward to the east, each with speeds on the order of 5 cm/s. During October, as the Palau Eddy reforms, the southward current to the east of Palau increases to 15 cm/s. During November, the circulation transitions to the north-directed winter regime.     

Further determinations of upper-atmosphere rotational speed from analysis of satellite orbits

The average angular velocity of the upper atmosphere, which we take as Λ times the Earth's angular velocity, can be evaluated by analysing the changes in the orbital inclinations of satellites. In this paper the nine most suitable orbits now available are analysed and values of Λ are found for heights between 200 and 260 km. The results, which are more accurate than in our previous studies, confirm that Λ 1, i.e. that the atmosphere rotates faster than the Earth at these heights, and show that Λ increases with height, from 1.1 at 210 km to 1.4 at 260 km. This corresponds to mean west-to-east winds of 30 m/s at 210 km, increasing to 130 m/s at 260 km height. Results from one satellite indicate that the wind is probably strongest at times near sunset, with Λ = 1.5 ± 0.1 at 200 km height in August 1966. Comparisons are made with previous observational results and some of the suggested theoretical explanations are outlined.     

Nitrogen loads to New Zealand aquatic receiving environments: comparison with regulatory criteria

ABSTRACT

There is concern about the deteriorating nutrient status of aquatic receiving environments in New Zealand. We estimated the amount by which current nitrogen (N) concentrations and loads exceed criteria in rivers, lakes and estuaries nationally. Criteria corresponded to national ‘bottom-line’ (i.e. minimal) environmental objectives set by government policy. Three metrics were evaluated: (1) degree of compliance describes the current TN loads in receiving environments relative to criteria; (2) catchment N status describes the acceptability of catchment N loads compared to criteria; and (3) excess load indicates the amount by which the N load exceeds the maximum allowable load (kg yr^?1). Non-compliance with N criteria was broadly distributed nationally particularly in low-elevation catchments. Catchments with unacceptable N status constituted at least 31% of New Zealand’s land area, which corresponds to at least 43% of the country’s agricultural land. The national excess load was estimated to be at least 19.1 Gg yr^?1. We are 97.5% confident that estimated excess loads exceed zero for nine of 15 regions and for the nation as a whole. The analyses provide a strategic assessment of where reductions in N emissions are required to achieve the minimal national objectives.     

A fungal epizootic in mussels at a deep-sea hydrothermal vent

Mass mortalities due to disease are important determinants of population and community structure in marine ecosystems, but the speed at which an epizootic may sweep through a population, combined with rapid selection for disease‐resistant stocks, can mask the ecological impact of disease in all but the most closely monitored populations. We document an emergent epizootic event in the deep sea that is occurring in mussels (Bathymodiolus brevior) at the Mussel Hill hydrothermal vent in Fiji Basin and we identify the causal agent as a black yeast (order Chaetothyriales) that elicits a pronounced host immune response and is associated with tissue deterioration. The yeast was not observed in other invertebrate taxa (the gastropods Ifremeria nautilei, Alviniconcha aff. hessleri; the limpets Lepetodrilus schrolli, Symmetromphalus aff. hageni; the polychaetes Branchipolynoe pettiboneae, Amphisamytha cf. galapagensis) associated with the mussel bed, nor in mussels (Bathymodiolus brevior) collected from adjacent Lau Basin mussel beds. Massive mussel mortality resulting from the fungal infection is anticipated at the Mussel Hill site in Fiji Basin; we expect that epizootic outbreaks in dense invertebrate communities have the potential to be major determinants of community structure in deep‐sea chemosynthetic ecosystems. The possibility that submersible assets may serve as vectors for transport of the fungus warrants further attention.