Organisation hydrochimique,biologique et sédimentologique d’un lac intracontinental à peuplements lagunaires : la Birket Karoun (Fayoum,Egypte)

Résumé

La Birket Karoun a été étudiée d’un point de vue biogéologique sur une période de 12 mois. Les données ainsi obtenues, ajoutées à celles de la littérature disponible, permettent de présenter les caractéristiques biogéologiques essentielles de ce bassin original.

Le lac n’est alimenté actuellement que par des eaux continentales issues du système nilotique ce qui entraîne des propriétés hydrochimiques assez différentes des corps d’eau paraliques influencés par la mer. Cependant, les caractéristiques hydrologiques, biologiques et sédimen-taires de la Birket Karoun la classent parmi les écosystèmes de type lagunaire. Il est même possible d’y reconnaître une organisation biogéologique zonale très semblable à celle des lagunes, la partie la plus « marine » (ou la moins confinée) se situant à l’opposé de la zone des apports d’eau douce. Une connexion entre le lac et la mer, actuelle ou passée, étant à peu près exclues, il faut admettre que les eaux continentales concentrées peuvent présenter, dans certains cas, des caractéristiques chimiques et biochimiques presque marines vis-à-vis des êtres vivants.

Dans cette optique, la Birket Karoun apparaît comme un modèle actuel susceptible de fournir une alternative à l’hypothèse d’une « Mer Saharienne » pour rendre compte de l’existence des lacs sahariens pleistocènes à faunes fossiles lagunaires.     

Distribution and Influence of Iron Phases the Physico—Chemical Properties of Phyllosilicates

Clay minerals from different Cretaceous stratigraphic successions of Egypt were investigated using XRD,DTA,dissolution analysis(DCB),IR,Moessbauer and X-ray Electron Spin Resonance(ESR) spectroscopes.The purity of the samples and the degree of their structural order were determined by XRD.The location of Fe in the octahedral sheet is characterized by absorption bands at-875cm^-1 assigned as Al-OH-Fe which persist after chemical dissolution of free iron.The Moessbauer spectra of these clays show two doublets with isomer shift and quadrupole splitting typical of octahedrally coordinated Fe^3 ,in addition to third doublet with hyperfine parameter typical of Fe^2 in the spectra of Abu-Had kaolinite (H) sample.Six-lines magnetic hyperfine components which are consistent with those of hematite are confirmed in the spectra of both Isel and Rish kaolinite samples.Goethite was confirmed by both IR and DTA.Multiple nature of ESR of these clays suggested structural Fe in distorted octahedral symmetry as well as non-structural Fe.Little dispersion and low swelling indices as well as incomplete activation of the investigated montmorillonite samplas by NaCO3 appear to be due to incomplete disaggregation of montmorillonite particles.This can be explained by the ability of Fe-gel to aggregate the montmorillonite into pseudo-particles and retard the rigid-gel structure.However,extraction of this ferric amorphous compound by dithonite treatment recovers the surface properties of the montmorillonite samples.On the other hand,the amount and site occupation of Fe associated with kaolinite samples show an inverse correlation with the parameters used to describe the degree of crystallinity perfection,color,brightness and vitrification range of these kaolinite samples.     

Removal of cadmium (II) from aqueous solution and natural water samples using polyurethane foam/organobentonite/iron oxide nanocomposite adsorbent

A novel polyurethane foam/organobentonite/iron oxide nanocomposite adsorbent was successfully prepared via in situ polymerization of toluene diisocyanate and polyol in presence of 5 wt% organobentonite/iron oxide. The obtained nanocomposite was characterized in detail, and the results revealed that the clay layers are exfoliated and/or intercalated in the polymer matrix forming a nanocomposite structure. The application of the prepared nanocomposite for adsorption of cadmium ions from aqueous solution was tested as a function of various experimental parameters using batch procedures. Adsorptive removal of Cd(II) onto the nanocomposite attained maximum at adsorbent content 1.5 g/L, pH 6, and the equilibrium was established within 60 min. Kinetic studies showed that the experimental data fit very well to pseudo-second-order model, and the adsorption process proceeds through three steps. It was found that external liquid film and intraparticle diffusion steps deeply affect the rate of Cd²⁺ ions adsorption onto the synthesized nanocomposite. Langmuir isotherm model fitted the adsorption data better than Freundlich with a maximum adsorption capacity (q _m) for Cd(II) equal to 78 mg/g under the specified experimental conditions. The synthesized nanocomposite afforded effective extraction for Cd²⁺ ions from natural water samples and excellent reusability feature. This study declares the potential efficiency of a new clay/polymer nanocomposite as alternative for wastewater remediation.     

Optimization of sulfur adsorption over Ag-zeolite nanoadsorbent by experimental design method

Environmental protection has mentioned the need to cut out all of fuels sulfur compounds. One of the most important processes that affect sulfur removal in atmospheric condition is the interaction of liquid fuels with solid sulfur removal adsorbents such as zeolites. To investigate the nano-AgX-zeolite efficiency for the sulfur adsorption process, a set of experimental tests was arranged and conducted by Box–Behnken design software, in an adsorption laboratory setup. The selected variables comprised metal percent, adsorption temperature and calcination temperature. The parameter levels were 0.5–10 %, 30–120 and 200–500 °C, respectively. The experiment results were used to find the statistical model. The results demonstrate that the sulfur concentration level is 48.36 ppm in the last product at 83 °C for adsorption temperature, 5.53 % for metal percent and 436 °C for calcination temperature in constant pH and constant process time.     

Arsenic contamination of ground and pond water and water purification system using pond water in Bangladesh

This paper, firstly, shows the distribution of arsenic-contaminated groundwater in Samta village. This village, which is in Jessore district in Bangladesh, was chosen as a model village for investigating the mechanism of groundwater contamination. 90% of the tube wells in this village had arsenic concentrations above the Bangladesh standard of 0.05 mg/l. Tube wells with arsenic concentrations of over 0.50 mg/l were distributed in the southern part of the village with a belt-like shape from east to west. Secondly, groundwater distribution is discussed with respect to its flow and the high arsenic zone (As≥0.50 mg/l) agrees well with the drifting zone of the groundwater. Furthermore, arsenic-free water supply systems suitable for a small area in the village have been developed. A pond sand filter (PSF) system which purifies pond water is discussed in this paper. Prior to the construction of the PSF, the water quality in ponds was examined for arsenic levels. The inflow of drainage from the tube wells was found to be the major cause of arsenic contamination of pond water. The PSF installed in Samta is working very well and produces a good quality of treated water.     

Current stabilizer for the magnetic field of a mass spectrograph

Summary A new automatic current stabilizer is constructed, which can be used for a magnetic field of a mass spectrograph. A stability of the order of 10^–6 is attained for relatively long intervals. The dependence of the magnetic field constancy on the different parameters of the stabilizer is investigated by methods of servomechanism.     

Velocity and attenuation of compressional waves in nearly saturated soils

Based on the two-phase theory of Biot, we present exact and approximate expressions for the velocity and attenuation of compressional waves within nearly saturated poroelastic media. We use the approximate solutions to model the low-frequency compressional waves within nearly saturated soils. The model accounts for the effective stress, degree of saturation, and void ratio, and is capable of describing experimental results on Ottawa sand. The three-phase theory of Vardoulakis and Beskos and the two-phase theory of Biot similarly describe the velocity and attenuation of compressional waves in most soils. However, the former theory breaks down for nearly saturated gravels and dense sands.     

Estimation of frequency dependent coda wave attenuation structure at the vicinity of Cairo Metropolitan Area

Estimation of seismic wave attenuation in the shallow crust in terms of coda wave Q structure previously investigated in the vicinity of Cairo Metropolitan Area was improved using seismograms of local earthquakes recorded by the Egyptian National Seismic Network. The seismic wave attenuation was measured from the time decay of coda wave amplitudes on narrow bandpass filtered seismograms based on the single scattering theory. The frequency bands of interest are from 1.5 to 18 Hz. In general, the values obtained for various events recorded at El-Fayoum and Wadi Hagul stations are very similar for all frequency bands. A regional attenuation law Q _c = 85.66 f ^0.79 was obtained.