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91.
Geochemistry and mineralogy of shallow alluvial aquifers in Daudkandi upazila in the Meghna flood plain, Bangladesh 总被引:1,自引:0,他引:1
M. Aziz Hasan Mattias von Br?mssen Prosun Bhattacharya Kazi Matin Ahmed Arif Mohiuddin Sikder Gunnar Jacks Ondra Sracek 《Environmental Geology》2009,57(3):499-511
The shallow alluvial aquifers of the delta plains and flood plains of Bangladesh, comprises about 70% of total land area are
mostly affected by elevated concentrations of arsenic (As) in groundwater exposing a population of more than 35 million to
As toxicity. Geochemical studies of shallow alluvial aquifer in the Meghna flood plain show that the uppermost yellowish grey
sediment is low in As (1.03 mg/kg) compared to the lower dark grey to black sediment (5.24 mg/kg) rich in mica and organic
matter. Sequential extraction data show that solid phase As bound to poorly crystalline and amorphous metal (Fe, Mn, Al)-oxyhydroxides
is dominant in the grey to dark grey sediment and reaches its maximum level (3.05 mg/kg) in the mica rich layers. Amount of
As bound to sulphides and organic matter also peaks in the dark grey to black sediment. Vertical distributions of major elements
determined by X-ray fluorescence (XRF) show that iron (Fe2O3), aluminum (Al2O3) and manganese (MnO) follow the general trend of distribution of As in the sediments. Concentrations of As, Mn, Fe, HCO3
−, SO4
2− and NO3
− in groundwater reflect the redox status of the aquifer and are consistent with solid phase geochemistry. Mineralogical analysis
by X-ray diffraction (XRD) and scanning electron microscopy (SEM) fitted with energy dispersive X-ray spectrometer (EDS) revealed
dominance of crystalline iron oxides and hydroxides like magnetite, hematite and goethite in the oxidised yellowish grey sediment.
Amorphous Fe-oxyhydroxides identified as grain coating in the mica and organic matter rich sediment suggests weathering of
biotite is playing a critical role as the source of Fe(III)-oxyhydroxides which in turn act as sink for As. Presence of authigenic
pyrite in the dark grey sediment indicates active reduction in the aquifer. 相似文献
92.
An accurate numerical survey of the density profiles corresponding to the crusts of neutron stars for representative equation
of state models is presented. This will find application in calculations of thermal and magnetic evolution of neutron stars. 相似文献
93.
Oxygen and carbon isotopes were measured to a high depth resolution in a nannoplankton carbonate sequence spanning the Cretaceous-Tertiary boundary at Koshak Hill, Mangyshlak Peninsula, Kazakhstan. The boundary is characterized by the presence of a ∼ 1 cm thick clay layer having a sharp peak in iridium concentration with a maximum value of 3.7 ng g-1 . The δ18 O data reveal rapid (∼103 years) excursion of sea-surface temperature at the boundary where an initial cold pulse is followed by a persistent warm period. The δ13 C data, in contrast, indicate only a gradual change in productivity across the boundary. The observations suggest a biogeochemical scenario for the boundary event pertaining to shallow epicontinental seas. 相似文献
94.
Garnet-sillimanite gneisses, locally known as khondalites, occur abundantly in the Chilka Lake granulite terrane belonging
to the Eastern Ghats Proterozoic belt of India. Though their chemistry has been modified by partial melting, it is evident
that the majority of these rocks are metapelitic, with some tending to be metapsammitic. Five petrographically distinct groups
are present within the khondalites of which the most abundant group is characteristically low in Mg:Fe ratios — the main chemical
discriminant separating the five groups. The variations in Mg:Fe ratios of the garnets, biotites, cordierites, orthopyroxenes
and spinels from the metapelites are compatible with those in the bulk rocks.
A suite of granitoids containing garnet, K-feldspar, plagioclase and quartz, commonly referred to as leptynites in Indian
granulite terranes, are interlayered with khondalites on the scale of exposures; in a few spots, the intercalated layers are
thin. The peraluminous character of the leptynites and presence of sillimanite trails within garnets in some of them suggest
derivation of leptynites by partial melting of khondalites. Here we examine this connection in the light of results derived
from dehydration melting experiments of micas in pelitic and psammitic rocks.
The plots of leptynites of different chemical compositions in a (MgO + FeO)-Na2O-K2O projection match the composition of liquids derived by biotite and muscovite dehydration melting, when corrected for co-products
of melting reactions constrained by mass balance and modal considerations. The melt components of the leptynites describe
four clusters in the M-N-K diagram. One of them matches melts produced dominantly by muscovite dehydration melting, while
three clusters correspond to melting of biotite. The relative disposition of the clusters suggests two trends, which can be
correlated with different paths that pelitic and psammitic protoliths are expected to generate during dehydration melting.
Thus the leptynites evidently represent granitoids which were produced by dehydration melting in metapelites of different
compositions.
The contents of Ti, Y, Nb, Zr and Th in several leptynites indicate departures from equilibrium melt compositions, and entrainment
of restites is considered to be the main causative factor. Disequilibrium in terms of major elements is illustrated by leucosomes
within migmatites developed in a group of metapelites. But the discrete leptynites that have been compared with experimental
melts approach equilibrium melt compositions closely. 相似文献
95.
96.
97.
S. N. Bhattacharya 《Pure and Applied Geophysics》1996,147(3):497-514
Love waves recorded by a long-period seismograph at New Delhi (NDI) from seven earthquakes of magnitude 4.3 to 5.2 in Koyna and Bhatsa on the western coast and one earthquake in Ongole on the eastern coast of the Indian Peninsula have been used to determine the seismic moment for each of the earthquakes by waveform modeling. Transverse component of the synthetic seismogram shows that the maximum amplitude of waveform decreases with an increase of source duration. Thus for an evaluation of the seismic moment by equating the amplitude level of the observed and synthetic waveforms, we must know the source duration. The synthetic seismogram also indicates that a short source duration gives rise to a small but sharp pulse and this pulse is interpreted as anLg wave. Comparison of the observed and synthetic waveforms has been used for a simultaneous evaluation of the source duration and seismic moment. The source durations are found to vary between 2.2 and 4.4 s; for earthquakes with a magnitude range between 4.3 and 5.2 these durations are slightly higher than normal. We obtain moment (M
0) of Ongole earthquake (M
L
=5.1)as 1.7×1024 dyne-cm; moments of Koyna and Bhatsa earthquakes (4.3M
L
5.2) on the western coast lie between 0.7×1023 and 3.6×1023 dyne-cm. Moment (M
0)-magnitude (M
L
) relation logM
0=1.5M
L
+16.0 for the western United States region agrees as well, in general, with the results for the earthquakes in the Indian Peninsula. 相似文献
98.
The massif-type anorthosite complex at Bolangir in the northern part of the Eastern Ghats belt occurs in a milieu of predominantly
supracrustal granulite-grade rocks. The massif is separated from the host gneisses by coarse-grained garnetiferous granitoid
gneisses which are interpreted as coeval crustallyderived melts. Melanocratic ferrodiorite rocks occur at the immediate contact
with the anorthosite massif which they intrude in cross-cutting dikes and sheets. The emplacement age of the anorthosite diapir
and the associated igneous suites is deemed to be pre-D2. Recrystallization of the igneous assemblages of the ferrodiorite suite (750–800°C, 7–8kbar,
) during a period of near-isobaric cooling from the igneous crystallization stage to the regionalP-T regime led to extensive development of coronitic garnet at the interface of plagioclase phenocrysts with the mafic matrix
assemblage (opx + fay + cpx + ilm ± amph, bio). Abundant accessory phases are zircon, apatite and thorite. The mafic phases
have extremely ferrous compositions (XFe gar: 0.93-0.87, fay: 0.90-0.87, opx: 0.80-0.60, cpx: 0.70-0.47, amph: 0.81-0.71) reflecting the low Mg-number (16-8) of the
rocks. Compared to worldwide occurrences of similar rocks, the Bolangir ferrodiorites (SiO2 36–58 wt.%, FeO*: 39-10 wt.%) are characterized by exceptionally high concentrations of HFSE and REE (TiO2: 4.8-1.0 wt.%, P2O5: 1.7-0.5 wt.%, Zr: 5900-1300 ppm, Y: 240-80 ppm, La: 540-100 ppm, Ce: 1100-200 ppm, Yb: 22-10 ppm, Th: 195-65 ppm). Well
defined linear variation trends for major and trace elements reflect progressive plagioclase accumulation towards the felsic
members of the suite. The ferrodiorites are interpreted to represent residual liquids of anorthosite crystallization which
after segregation and extraction from the ascending diapir became enriched in HFSE and REE through selective assimilation
of accessory phases (zircon, monazite, apatite) from crustal felsic melts. Ferromonzodioritic rock presumably formed through
hybridization between the ferrodiorite and overlying felsic melts. 相似文献
99.
The origin of chloritoid – 3‐mica pseudomorph growth in staurolite–muscovite schist,Bangriposi (Eastern India) 下载免费PDF全文
At Bangriposi, variable stages in replacement of staurolite by chloritoid – Na–K–Ca mica shimmer aggregates in muscovite schists provides insight into the complex interplay between fluid flow, mass transfer, and dissolution–precipitation during pseudomorph growth. Idioblastic chloritoid growing into mica caps without causing visible deformation, and monomineralic chloritoid veins (up to 300 μm wide) within shimmer aggregates replacing staurolite attest to chloritoid nucleation in fluid‐filled conduits along staurolite grain boundaries and crystallographic planes. The growth of shimmer aggregates initiated along staurolite margins, and advanced inwards into decomposing staurolite along networks of crystallographically controlled fluid‐filled conduits. Coalescence among alteration zones adjacent to channel fills led to dismemberment and the eventual demise of staurolite. Mass balance calculation within a volume‐fixed, silica‐conserved reference frame indicate the shimmer aggregates grew via precipitation from fluids in response to mass transport that led to the addition of H2O, K2O, Na2O and CaO in the reaction zone, and Al2O3 was transported outward from the inward‐retreating margin of decomposing staurolite. This aided precipitation of chloritoid in veins and in the outer collars, and as disseminated grains in the shimmer aggregates at mid‐crustal condition (~520 ± 20 °C, 5.5 ± 2.0 kbar). Computation using one‐dimensional transport equation suggests that staurolite decomposition involved advection dominating over diffusive transport; the permeation of externally derived H2O caused flattening of chemical potential gradients in H2O and aqueous species, for example, and , computed using the Gibbs method. This suggests that staurolite decomposition was promoted by the infiltration of a large volume of H2O that flattened existing chemical potential gradients. In the initial stages of replacement, chloritoid super‐saturation in fluid caused preferential nucleation and growth of chloritoid at staurolite grain boundaries and in crystallographic planes. As reaction progressed, further chloritoid nucleation was halted, but chloritoid continued to grow as the 3‐mica aggregates continued to replace the remaining staurolite in situ, while the chloritoid‐compatible elements were transported in the water‐rich phase facilitating continued growth of the existing chloritoid grains. 相似文献
100.
In a previous paper (hereafter referred to as Paper I) we have tried to show that superdense cores in the nuclei of disk galaxies can be formed by accretion of gas ejected by the evolved stars which populate the central bulge of these galaxies. Solving the equations for radial flow of a magnetized gas, we found that the accretion of an explodable mass at the core can be achieved over a time-scale ranging from a few times 107 and a few times 108 yr. It was shown, however, that the accretion process is seriously inhibited if the gas possesses sufficient rotational velocity but lacks any dissipative, mechanism within the system. Since rotational velocity is an observed parameter of the stars which shed the gas to be accreted, one must consider the existence of some dissipative force in it in order that the accretion process may be efficient. In the present paper, therefore, we have solved the problem of the flow of a rotating, viscous (variable), magnetized gas. With plausible assumptions regarding some of the parameters involved, the time-scale for the accretion of an explodable mass (109
M
) at the core again turns out to be ranging between a few times 107 and a few times 108yr. Such time-scale has been proposed by several authors as that for repeated explosions in nuclei of these galaxies. It has also been proposed by many authors that the spiral arms are generated and destroyed in disk galaxies over the same time-scale. Our solution also yields a nearly linear rotational velocity law which is usually observed in the central regions of these galaxies. 相似文献