Arsenic in shallow groundwater of Bangladesh: investigations from three different physiographic settings

Occurrences of arsenic (As) in the Bengal Basin of Bangladesh show close relationships with depositional environments and sediment textures. Hydrochemical data from three sites with varying physiography and sedimentation history show marked variations in redox status and dissolved As concentrations. Arsenic concentration in groundwater of the Ganges Flood Plain (GFP) is characteristically low, where high Mn concentrations indicate redox buffering by reduction of Mn(IV)-oxyhydroxides. Low DOC, \( {\text{HCO}}^{ - }_{3} \), \( {\text{NH}}^{ + }_{4} \) and high \( {\text{NO}}^{ - }_{3} \) and \( {\text{SO}}^{{2 - }}_{4} \) concentrations reflect an elevated redox status in GFP aquifers. In contrast, As concentration in the Ganges Delta Plain (GDP) is very high along with high Fe and low Mn. In the Meghna Flood Plain (MFP), moderate to high As and Fe concentrations and low Mn are detected. Degradation of organic matter probably drives redox reactions in the aquifers, particularly in MFP and GDP, thereby mobilising dissolved As. Speciation calculations indicate supersaturation with respect to siderite and vivianite in the groundwater samples at MFP and GDP, but groundwater in the GFP wells is generally supersaturated with respect to rhodochrosite. Values of log P_CO2 at MFP and GDP sites are generally higher than at the GFP site. This is consistent with Mn(IV)-redox buffering suggested at the GFP site compared to Fe(III)-redox buffering at MFP and GDP sites.     

Morphometric evidence of seismicity around Wagad and Gedi Faults, eastern Kachchh, Gujarat

Recent studies suggest that the eastern Kachchh is a potential zone for major earthquakes in the near future. Particularly, the E-W trending faults are considered capable of generating large magnitude earthquakes is further indicated by the recent concentration of the earthquake shocks, which, show two prominent clustering around west and north of the Wagad upland. In view of this, the conventional morphometric analyses of a terrain bounded by the E-W trending North Wagad Fault (NWF) and the Gedi Fault (GF) has been undertaken to ascertain the influence of seismicity in the evolution of the drainage basin. The study suggests that the fifth order drainage basins responded to the seismicity associated with both the NWF and GF. However, compared to the GF, the NWF seems to be more active. In addition to this, based on the stream morphology, we could identify two lineaments trending N-S and E-W. The former appears to be associated with the activity along the Manfara Fault (MF), whereas, the later seems to be the splays of the NWF. Further, a preferential westward shift of the streams suggests left lateral displacement of the E-W trending faults. Overall it can be suggested that the terrain is in juvenile stage implying tectonic instability.     

Proterozoic crustal scale shearing in the Bundelkhand massif with special reference to quartz reefs

Quartz reefs that constitute the most spectacular feature of the Bundelkhand massif of Central India are as yet riddled with controversy. We consider the NE-SW trending quartz reefs and the NE-SW trending brittle-ductile shear system developed outside the quartz reefs to constitute a single tectonic fabric of the massif. The study of structural features of the quartz reefs and the associated NE-SW trending shear zones coupled with the mineralogical and structural features suggests that the quartz reefs represent strike-slip dominated vertical to subvertical shear zones with dominantly sinistral sense of shear. The loci of the quartz reefs constitute the large scale fractures developed as a consequence of extensional processes in this part of Central India. These fractures were the sites for later emplacement of siliceous magmatic melt, commonly known as quartz reef that was also responsible for the mineralization of some base metals as well as pyrophyllite and diaspore. The lithotectonic system of these quartz reefs thus developed was later on subjected to strike-slip movements. A generalized model of large scale extensional tectonics during the Proterozoic times has thus been suggested for the development of the NE-SW tectonic fabric of the Bundelkhand massif.     

New Insights into the Origin of Kabbaldurga Charnockites, Karnataka, South India

A detailed study of the structure and petrology of the rocks bordering the Kabbaldurga-type charnockites provides important constraints on the origin of these charnockites. The structural elements register three phases of deformation and show a uniform pattern in the larger area, a pattern consistent with the regional structure of the Precambrian of Southern Karnataka. In the Kabbaldurga area, however, some of the earlier structures are poorly preserved. Yet there are vestiges of early folds described by banded/layered charnockites as in the neighbouring Kodamballi area, and a consistent development of dilatant structures which can be related to the kinematics of deformation in the larger terrain. At Kabbaldurga the pegmatitic charnockites occur as veins of diverse orientation; but they rarely follow the shear - generated structures.

The metamorphic reactions invoked by previous workers to explain in situ transformation of gneiss to charnockite were based on chemical similarity of some close pairs. But the petrographic and chemical variations in the pegmatitic charnockites and the Peninsular gneisses at Kabbaldurga quarry are compelling features which cannot be explained by the hypothesis of in situ transformation. We have argued, on the basis of rock and mineral chemistry, that derivation of the pegmatitic charnockites by dehydration melting in metabasites offers a better explanation. Pressure-temperature values (at least 850° to 900° C, 7 kbar) obtained by us for the granulites of this area, viewed against the results of experimental dehydration melting in basic rocks with hornblende and/or biotite, provide strong support for this model. In the field leucosomes within the basic granulites of Kabbaldurga are not uncommon. The compositions of the pegmatitic charnockites (tonalitic and granitic) match those of the melts produced in experiments. Further, the pattern of variation in the composition of hornblende and plagioclase in the basic granulites of the Kabbaldurga area is compatible with extraction of melts. This alternative model for the origin of the Kabbaldurga charnockites is petrologically feasible and does not require either in situ transformation or structurally controlled growth, which, incidentally, are not ubiquitous at Kabbaldurga     

Archean Granitoids at the Contact of Eastern Ghat Granulite Belt and Singhbhum-Orissa Craton, in Bhuban-Rengali Sector, Orissa, India

The small granite plutons occurring at the contact of the Singhbhum-Orissa Iron Ore craton (IOC) to the north and the Eastern Ghat Granulite Belt (EGGB) to the south in eastern Indian shield are characterised by the presence of enclaves of the granulites of EGGB and the greenschist facies rocks of IOC. These granites also bear the imprints of later cataclastic deformation which is present at the contact of the IOC and the EGGB. In situ Pb-Pb zircon dating of these granites gives minimum age of their formation 2.80 Ga. A whole-rock three point Rb-Sr isochron age of this rock is found to be 2.90 Ga. Therefore, the true age of formation of these granites will be around 2.90–2.80 Ga. These granitic rocks also contain xenocrystic zircon components of 3.50 Ga and show a later metasomatic or metamorphic effect 2.48 Ga obtained from the analyses on overgrowths developed on 2.80 Ga old zircon cores. The presence of granulitic enclaves within these contact zone granite indicates that the granulite facies metamorphism of the EGGB is 2.80 Ga or still older in age. The cataclastic deformations observed at the contact zone of the two adjacent cratons is definitely younger than 2.80 Ga and possibly related to 2.48 Ga event observed from the overgrowths. As 2.80 Ga granite plutons of small dimensions are also observed at the western margin of the IOC; it can be concluded that a geologic event occurred 2.80 Ga over the IOC when small granite bodies evolved at the marginal part of this craton after its stabilisation at 3.09 Ga.     

Clay mineralogy of the ocean sediments from the Wilkes Land margin,east Antarctica: implications on the paleoclimate,provenance and sediment dispersal pattern

Core U1359 collected from the continental rise off Wilkes Land, east Antarctica, is analyzed for the clay mineralogy and carbon content. The temporal variation of the clay mineralogical data shows a dominance of illite with chlorite, smectite and kaolinite in decreasing concentration. Clay mineral illite is negatively correlated with smectite which shows enrichment during 6.2–6.8, 5.5–5.8, 4.5 and 2.5 Ma. The mineralogical analyses on the silt size fraction (2–53 μm) of some selected samples were also carried out. The combined result of both the size fractions shows the presence of chlorite and illite in both size fractions, smectite and kaolinite only in clay size fraction (<2 μm) and similarity in the crystallinity and chemistry of illite in both fractions. Similar nature of illite in both fractions suggests negligible role of sorting probably due to the deposition from the waxing ice sheet. During times of ice growth, nearby cratonic east Antarctica shield provided biotite-rich sediments to the depositional site. On the other hand, the presence of smectite, only in the clay size fraction, suggests the effective role of sorting probably due to the deposition from distal source in ice retreat condition. During times of ice retreat, smectite-rich sediment derived from Ross Orogen is transported to the core site through surface or bottom water currents. Poor crystallinity of illite due to degradation further corroborates the ice retreat condition. The ice sheet proximal sediments of U1359 show that in the eastern part of Wilkes Land, the ‘warming’ was initiated during late Miocene.     

Facies architecture of asymmetrical branching distributary channels: Cretaceous Ferron Sandstone,Utah, USA

Distributary channel systems are an important component of deltaic systems, but details of their branching pattern, stream‐order, internal variability and relation with adjacent levée, bay and bayhead delta are rather poorly documented in ancient examples. Photomosaic and measured sections collected along a gooseneck‐shaped canyon in southern Utah allow direct mapping of the branching pattern of an ancient distributary system. The main channel belt is ca 250 m wide and narrows to ca 200 m downstream of the branching point. A subordinate channel belt, ca 80 m wide, branches off of the main channel, forming a distinctly asymmetrical branching pattern. Water discharge in the main channel is estimated to be 85 to 170 m³ sec^?1. Comparison with palaeodischarge estimates of trunk rivers mapped in previous studies suggests that the branching documented in this study probably is a fourth‐order split. The distributary channels are characterized by a U‐shaped geometry filled with medium‐grained, cross‐bedded sandstone, and are dominated by lateral accretion, suggesting limited lateral migration and moderate sinuosity. Tidally influenced facies and limited trace fossils indicate direct marine influence. The distributary channels erode into adjacent levée and underlying heterolithic bay‐fill deposits, and the marine influence suggests that they were deposited on a lower delta plain, rather than on a non‐marine floodplain. The subordinate channel fed a bayhead delta, suggesting that it was formed by a partial avulsion, rather than bifurcation around a mouth bar, as is more characteristic of terminal distributary channels. Channel‐floor drapes, bar‐accretion drapes and abandoned channel fills within the sandstone channel belts represent the most important heterogeneity from the perspective of reservoir characterization.     

On anomalously high sub-surface dissolved oxygen in the Indian sector of the Southern Ocean

The Southern Ocean (SO) plays a critical role in global ocean productivity and carbon cycling. Bio-Argo floats deployed in the Indian sector of the Southern Ocean provides new insights into the biogeochemical processes. Here we report significantly higher dissolved oxygen(DO) (~?310 μmol/kg) in summer of 2014–2015 for one float (F1) and winter of 2014 in other float (F2) at sub-surface layer in the subantarctic region of the SO. The summer DO peak in F1 was 10% higher than those during the summer of succeeding year, while the winter DO peak in F2 was 20% higher than those during the winter of succeeding year. Temperature and dynamic height structure show that cyclonic eddies play an important role in the observed increase in the dissolved oxygen: the high DO is a manifestation of the co-occurrence of a cold core eddy which transported the cold oxygen rich water from deep to the surface during winter, while, during summer, the high chlorophyll below the mixed layer depth (MLD) also contributed to the elevated DO. Low apparent oxygen utilisation suggests that the observed high oxygen concentration was due to high production rates over the consumption.

     

Petrological and Geochemical Constraints on the Evolution of the Alkaline Complex of Koraput in the Eastern Ghats Granulite Belt, India

The Koraput Alkaline Complex in the high-grade Eastern Ghats Belt, India, is synkinematically emplaced in a pull-apart structure and far from the Bastar cratonic margin. The suite comprises four distinct members, namely, mafic syenite, felsic syenite, nepheline syenite and perthite syenite. Fe-rich orthopyroxene rims on olivine in mafic syenite indicate iron-enrichment in the early stage of differentiation. With plagioclase of andesine composition it could be described as alkali-norite, the plutonic equivalent of hawiite. Felsic syenite with both alkali-feldspars and plagioclase of oligoclase composition could be described as two-feldspar syenite, the plutonic equivalent of mugearite. Albitic rims on nepheline indicates subsolvus reaction. Chemical trends in amphiboles and plagioclase feldspars, progressively more ferroan and more sodic respectively, are strong indications of mineral fractionation in the Koraput suite. Chemical trends in the variation diagrams are compatible with feldspar fractionation in the Koraput suite. A weak Fe-enrichment trend in the early stage of differentiation, as observed in the AFM diagram, is compatible with that of the alkali-basalt series. Nb anomalies, both positive and negative, are indicative of crustal contamination as expected in synkinematic plutons. In terms of Gondwana assembly and break up, the alkaline complexes are supposed to represent rift-related magmatism along the continental margin. In spite of petrological evidence of the magmatic character of the Koraput Complex, anorogenic setting is contra-indicated by mesoscopic and microscopic fabrics, more akin to synkinematic intrusion during F 2 folding in the host country rocks. The Proterozoic alkaline complexes in the Eastern Ghats Belt, could alternatively trace the path of moving Gondwana continent over mantle plumes.