Nanoscale occurrence of Pb in an Archean zircon

We report, for the first time, a direct, atomic-scale characterization of Pb in zircon (4.4-3.1 Ga) from the early Archean Yilgarn craton in Australia using high-resolution HAADF-STEM. Two forms of Pb have been identified: Pb concentrated at ∼3 atom% as a nanoscale patch in zircon structure, and Pb concentrated within the amorphous domain created by fission fragment damage. The first result suggests that the Pb atoms directly substitute for Zr⁴⁺ in the zircon structure, and the latter observation demonstrates that Pb diffusion can occur through amorphous regions created by radiation damage, although volume diffusion is typically considered to be the dominant mechanism for Pb diffusion. Beyond the first percolation point, i.e., when the amorphous domains overlap and form a fully interconnected network of amorphous domains, there is a new pathway for the diffusion of Pb that is faster than volume diffusion through crystalline zircon.     

Radiolarian Age of Chert-hosted Bedded Manganese Deposits from the Gen-otani Mine in the Tamba District, Northern Kyoto City, Japan

Abstract. Numerous bedded manganese deposits sporadically distributed throughout the Tamba district, southwestern Japan are intercalated within chert sequence. It is well known that radiolarian remains are commonly included in both bedded manganese deposits and host cherts. The Gen‐otani mine, one of these deposits, is located at Otani, Keihoku‐Shimonaka, northern Kyoto City. Chemical composition and age of the chert sequence at the mine were examined. Mainly according to SiO₂ and MnO contents together with lithology, the chert sequence is divided into three sections; lower massive chert, middle bedded manganese deposit and upper bedded chert sections. Radiolarian faunas consisting of middle Jurassic species such as Eucyrtidiellum unumaense, Dictyomitrella(?) kamoensis, Parvicingula dhimenaensis, Sethocapsa aitai, Sethocapsa kodrai, Transhsuum brevicostatum, Tricolocapsa plicarum, Unuma echinatus and others were extracted from both the middle manganese section and overlying bedded chert of the upper section. This examination reveals that the bedded manganese deposit at the Gen‐otani mine formed until Bajocian to early Bathonian (middle Middle Jurassic) in age.     

Liquefied soil pressures on vertical walls with adjacent embankments

Horizontal earth pressures on rigid vertical walls in liquefied soils have extensively been studied by many researchers for the level ground surface condition. In this paper, a series of centrifuge tests was conducted to investigate the effects of embankments resting on ground surfaces on the pressure on the rigid vertical walls. In the tests, earth pressures on the rigid walls were successfully measured with built-in earth pressure cells with small accelerometers attached on them. The earth pressure cells are capable of measuring both normal and shear stresses simultaneously with a good accuracy. It appears that dynamic component of the earth pressure of liquefied sand is in proportion to the acceleration of the rigid wall irrespective of amplitude and frequency of the input motion, and increases with increasing average embankment load. On the other hand, the residual component of the earth pressure is found to be well estimated from FEM assuming the liquefied soil as an incompressible elastic body. A practical formula of the earth pressures is established for the purpose of practical use.Another series of centrifuge tests was carried out on models with solidification or densification zones below embankment toes as a remedial countermeasure against liquefaction-induced embankment failure. It was found that the proposed formulae holds valid independently of the movement of walls as long as the liquefied soil behaves as a heavy fluid, and the countermeasure does not soften significantly.     

High-Speed Data Acquisition System Messia for Subaru

We have developed a high-speed data acquisition system, Messia-III (Modularized Extensible SyStem for Image Acquisition) for Subaru, Japanese 8.2m telescope. Messia has a direct 1-Gbps link to a host UNIX workstation. Messia is a VMEbus-based system but it does not have local OS nor CPU's in order to minimize software development and maintenance.     

A momentum distribution of high energy particles around Crab pulsar

We determine the momentum distribution of the relativistic particles near the Crab pulsar from the observed X- and -ray spectra (10³10⁹ eV), provided that the curvature radiation is responsible for it. The power law spectrum for the relativistic electrons,f() ^–5, reproduces a close fit to the observed high-energy photon spectrum. The theoretically determined upper limit to the momentum (due to radiation damping), _M 8×10⁶, corresponds to the upper cut-off energy of the -ray spectrum, 10⁹ eV. The lower limit to the momentum, _m 1.8×10⁵, is chosen such that flattening of the X-ray spectrum below 10 keV is simulated. The number density of these electrons is found to be much higher than the Goldreich-Julian density. We also discuss pulse shape and polarization of high-energy photons. The extremely high density of particles and the steep momentum spectrum are difficult to understand. This may imply that another, more efficient, mechanism is in operation.     

Mineralogical and Genetical Aspects of the Doyashiki Kuroko Deposits, Hokuroku Basin, Japan

Abstract. A detail investigation of ore and gangue minerals was performed on the Doyashiki Kuroko deposits, Hokuroku basin, Japan for the first time. Main ore minerals are sphalerite, galena, pyrite, chalcopyrite, tetrahedrite-tennantite and digen-ite. Small amounts of enargite, wittichenite, electrum, covellite, bornite, marcasite and hematite are also observed. Quartz, barite and gypsum are common gangue minerals. Homogenization temperatures and salinities of fluid inclusions in quartz, sphalerite and barite range from 190 to 240C and 3.0 to 5.5 wt% NaCl equivalent, respectively. The FeS contents of sphalerite and Ag contents of electrum were 0.12 to 0.18 mol %, 39.0 to 39.6 atom %, respectively. The chemical composition of digenite as a primary mineral shows high sulfur contents.
These data indicate that ore fluid responsible for digenite and associated ore minerals was characterized by a range of high sulfur fugacity with a moderate formation temperature. This is concordant with the mineral assemblage of bornite-pyrite and chalcopyrite, which shows high sulfur fugacity conditions. It seems that the mineralization closely associated with acidic volcanism has occurred around 13 Ma of Middle Miocene on the seafloor at the depth of about 1500 m.     

Unstable forearc stress in the eastern Nankai subduction zone for the last 2 million years

Transpressional tectonics characterizes the SW Japan arc. However, we will show in this article that offshore seismic profiles and onshore mesoscale faults indicate that the eastern part of the forearc was subject to transtensional tectonics since ca. 2.0 Ma. Offshore normal faults imaged on the profiles run parallel to the Nankai Trough, and started activity at 1.0 Ma, but transtensional tectonics commenced the onshore area earlier. In order to understand the stress history in the forearc region, we collected fault-slip data from onshore mesoscale faults in Plio-Pleistocene sedimentary rocks in the Kakegawa area at the northeastern extension of the offshore normal faults. Most of the mesoscale faults are oblique-normal, indicating that the area was subject to transtensional tectonics. The faults suggest that the compressional tectonic regime was followed by the transtensional one at 2.0 Ma, in agreement with regional tectonostratigraphic data, which indicate that folding ceased at that time. Present compressional stress followed the transtensional tectonic regime sometime in the late Pleistocene. Transtensional or extensional tectonic zone shifted from the Kakegawa area to the offshore region.These observations indicate that the state of stress just behind the accretionary prism of the eastern Nankai subduction zone has been unstable in the last 2 million years, suggesting that the forearc wedge has been at critical state in that gravitational force and basal shear traction on the wedge have been balanced, but the forearc tectonics has been susceptible to small perturbations. Possible factors compatible with the observed stress history include the change of subduction direction of the plate at 1.0 Ma, and the rapid uplift of Central Japan thereafter.     

Iron oxidation state of a 2.45-Byr-old paleosol developed on mafic volcanics

The 2.45-Byr-old weathering profile developed on early Proterozoic mafic volcanics located near Cooper Lake, Ontario, Canada, was examined geochemically and mineralogically for a better understanding of the atmospheric oxygen evolution. Ferrous to ferric ion, Fe(II) and Fe(III), respectively, ratios of the bulk rock samples were analyzed by Mössbauer spectrometry. The total Fe (Fe(T)) and Fe(II) concentrations decrease from 12.0 and 11.2 wt.% to 1.85 and 0.89 wt.%, respectively, from the bottom to the top of the weathering profile. The Fe(T) and Fe(II) concentrations normalized to Ti and Zr, as well as the Fe(II)/Fe(III) ratio of raw data, linearly decrease with depth toward the top, while the Fe(III) concentration remains nearly constant throughout the profile. The linear decrease of Fe(II), accompanied by the nearly constant distribution of Fe(III), is difficult to be explained by the scenario of oxidizing weathering and subsequent reducing hydrothermal alteration. The behaviors of Fe(II) and Fe(III) can be simply explained by anoxic weathering. The anoxic weathering suggests that the 2.45-Ga atmosphere was anoxic. The slight increase of Fe/(Fe+Mg) in the octahedral sites of chlorite toward the top and no Ce anomaly in the REE patterns are also consistent with anoxic weathering.     

Optical instruments for JNLT

The plan for optical instruments for the Japanese National Large Telescope is described. Performance of the first-generation instruments is computed on the basis of tentative designs, and the capability of the telescope is demonstrated.Paper presented at the Symposium on the JNLT and Related Engineering Developments, Tokyo, November 29–December 2, 1988.