Wakefieldite‐(Nd), a New Neodymium Vanadate Mineral in the Arase Stratiform Ferromanganese Deposit,Kochi Prefecture,Japan

Wakefieldite‐(Nd), NdVO₄, is a new mineral found from the Arase stratiform ferromanganese deposit in Kochi Prefecture, Shikoku Island, Japan. It is the Nd‐dominant analogue of wakefieldite‐(Y) and wakefieldite‐(Ce). The ferromanganese ore specimen mainly consists of hematite and caryopilite, and wakefieldite‐(Nd) is typically enclosed in caryopilite. Wakefieldite‐(Nd) is tetragonal, I4₁/amd, a = 7.338(16) Å, c = 6.509(19) Å, V = 350.5(18) ų, Z = 4. The four strongest lines in the X‐ray diffraction pattern [d(Å), I/I₀, hkl] using a Gandolfi camera are (3.67, 100, 200); (2.74, 51, 112); (4.84, 27, 101) and (1.89, 25, 312). Chemical composition of wakefieldite‐(Nd) are V₂O₃ 35.25, As₂O₃ 0.93, SiO₂ 0.14, MnO 1.45, Fe₂O₃ 0.41, Y₂O₃ 2.87, La₂O₃ 7.61, Ce₂O₃ 7.37, Pr₂O₃ 6.04, Nd₂O₃ 26.79, Sm₂O₃ 4.41, Eu₂O₃ 1.36, Gd₂O₃ 3.41, Tb₂O₃ 0.22, Dy₂O₃ 1.41, Er₂O₃ 0.10, total 99.77 wt.%. The empirical formula is (Nd_0.403La_0.118Ce_0.114Pr_0.093Y_0.064Sm_0.064Mn_0.052Gd_0.048Eu_0.020Dy_0.019Fe_0.013Tb_0.003Er_0.001)_1.012(V_0.981As_0.020Si_0.006)_1.007O₄ on the basis of O = 4. The calculated density is 4.782 g/cm³. Microtexture and co‐existing relationship between wakefieldite‐(Nd) and caryopilite suggest that recrystallization and dehydration of Fe‐ and Mn‐oxyhydroxide led to the generation of hematite, caryopilite, rhodochrosite and wakefieldite‐(Nd) by the metamorphism during the accretion of the host unit of the Arase deposit. Chondrite‐normalized REE pattern of the host ferromanganese ore, which is regarded as oceanic metalliferous sediment in origin, shows negative Ce anomaly. Chemical composition of wakefieldite‐(Nd) reflects Ce‐depleted bulk composition of REE‐enriched ferromanganese ore.     

Experimental constraints on permeable gas transport in crystalline silicic magmas

The gas and fluid transport in magmas via permeable flow through interconnected bubble networks controls the rate of outgassing from magmas ascending in volcanic conduits and the fluid transport in the mushy boundary layer of magma reservoirs. Hence, clarifying its mechanism and rate is crucial to understanding the explosivity of volcanic eruptions and the evolution and dynamics of a magma reservoir. Recent experimental studies have determined the gas permeabilities in crystal-free rhyolite and basalt. However, no experimental study has investigated the effect of the crystal contents on the permeable gas transport in magmas. In this study, we performed decompression experiments for hydrous rhyolitic melts having crystallinities of 30 and 50 vol% to examine the effect of crystals on the bubble microstructure and gas permeability during magma vesiculation. Size-controlled (100-meshed) corundum crystals were used as an analog of the phenocrysts in silicic magmas. Microstructural analyses using X-ray CT showed that bubbles coalesce and their connectivity increases with a decrease in the final pressure after the decompression, that is, an increase in the vesicularity. As long as the vesicularities of melt part in the crystal-free basis (melt vesicularity) were similar, no clear effect of the crystallinity on the degree of bubble coalescence and connectivity was observed at melt vesicularities <68 vol%. The corundum showed a large contact angle with aqueous fluid as well as plagioclase and alkaline feldspar; this failed to induce the efficient heterogeneous nucleation and coalescence of bubbles on its surface. The gas permeabilities of all the run products were lower than the detection limits of the present analysis (the order of 10⁻¹⁶ m²) at melt vesicularities <68 vol%. These results show that silicic magmas containing 30 and 50 vol% phenocrysts with a large contact angle have low gas permeabilities until the vesicularity becomes large (at least >68 vol%). This result indicates that the permeable fluid transport through a deep volcanic conduit, which has been proposed on the basis of the observations of volcanic gases and natural products, is so slow that other processes, like shear deformation or magma convection, may be needed to explain the observations.     

Temporal variability in physicochemical properties,phytoplankton standing crop and primary production for 7 years (2002–2008) in the neritic area of Sagami Bay,Japan

Seasonal and interannual variations in physicochemical properties (i.e., temperature, salinity, dissolved oxygen and dissolved inorganic nutrients), chlorophyll a (Chl-a), particulate carbon and nitrogen (PC and PN, respectively), and primary production were investigated in the neritic area of Sagami Bay, Kanagawa, Japan, from January 2002 to December 2008. These abiotic/biotic variables, except for NH₄ ⁺–N, repeated similar seasonal variations for all 7 years. On the basis of the analysis of data obtained on 167 sampling dates, depth-integrated primary production in this water can be easily estimated from Chl-a at the surface using the regression equations obtained in the present study. Intermittently high values of dissolved inorganic nutrients, Chl-a, PC, PN and primary productivity at the surface during the summer stratified period were induced by high freshwater discharge from the rivers after rainfalls and by the expansion of nutrient-rich Tokyo Bay Water. Temperature, salinity and dissolved inorganic nutrients showed drastic variations within a scale of a few days and/or weeks, and these variations were related to sea levels that represent the intrusion of the Kuroshio Water, Intermediate Oyashio Water or deep water from the continental slope. However, there was no consistent trend in the variations in Chl-a, PC, PN and primary production due to the complex effects of these waters.     

Active tectonics around the junction of Southwest Japan and Ryukyu arcs: Control by subducting plate geometry and pre‐Quaternary geologic structure

The origin of active faults in the Inner zone of the western part of Southwest Japan was explained by a decrease of the minimum principal stress and reactivation of ancient geologic structures. Although the E–W maximum principal stress in Southwest Japan due to the collision of the Southwest and Northeast Japan arcs along the Itoigawa–Shizuoka Tectonic Line is assumed to decrease westward, the density of active strike‐slip faults increases in the western margin of the Southwest Japan Arc (western Chugoku and northern Kyushu) where the subducting Philippine Sea Plate dips steeply. The E–W maximum compressional stress is predominant throughout Southwest Japan, while the N–S minimum principal stress that is presumably caused by coupling between Southwest Japan arc and Philippine Sea Plate decreases due to the weak plate coupling as the plate inclination increases under the western margin of Southwest Japan. The increase of the fault density in the western margin of the arc is attributed to a decrease of the minimum principal stress and consequent increase of shear stress. Low slip rates of the active faults in this region support the view that the westward increase of fault density is not a response to increasing maximum stress. These faults of onshore and offshore lie in three distinct domains defined on the basis of fault strike. They are defined domains I, II, and III which are composed of active faults striking ENE–WSW, NW–SE, and NE–SW, respectively. Faulting in domains I, II, and III is related to Miocene rift basins, Eocene normal faults, and Mesozoic strike‐slip faults, respectively. Although these active faults are strike‐slip faults due to E–W maximum stress, it is unclear whether their fault planes are the same as those of pre‐Quaternary dip‐slip faults.     

Sea surface ichthyoplankton off southeastern New Zealand,summer 1977–78

Plankton samples from the Chatham Rise, Pukaki Rise, and Campbell Plateau provided information on the young stages of a number of poorly known New Zealand fish species, and on the presence of a large spawning area of barracouta, Thyrsites atun, over the Mernoo Bank, The Chatham Rise was more important as a spawning area than the areas further south.     

Concentrations of 222 Rn, Its Short-Lived Daughters And 212 Pb And Their Ratios Under Complex Atmospheric Conditions And Topography

Atmospheric activity concentrations of ²¹²Pb and short-lived ²²²Rndaughters, together with meteorological elements, have been observed continuously atthree sites at Kamisaibara Village in Japan. In addition, atmospheric activity concentrationof ²²²Rn, equilibrium-equivalent concentration of ²²²Rn and conditionsof the lower atmosphere were observed for three intensive observation periods at Akawase,one of the three sites in Kamisaibara Village. The equilibrium-equivalent concentration of²²²Rn is almost the same as the atmospheric activity concentration of short-lived²²²Rn daughters.The activity concentrations of ²¹²Pb and the short-lived ²²²Rn daughtersand their ratio were low in the daytime owing to convective mixing, and high at nightowing to the surface-based inversion during periods of no precipitation. Their variationshave several patterns corresponding to the scale of the drainage wind or weak mixing.Mechanical mixing due to strong winds through both day and night during the first andsecond observation periods made the atmospheric activity concentrations of ²¹²Pb and the short-lived ²²²Rn daughters continuously low. However, their ratios werecontinuously high during the first period yet continuously low during the second period.This difference can be explained by the effect ofextraction of ²²⁰Rn and ²²²Rndue to strong winds and snow cover. There were also cases in which the ratio of theatmospheric activity concentration of ²¹²Pb to that of the short-lived ²²²Rndaughters at night was equal to or less than the ratio in the daytime. Thisinverse trend, asin the periods of no precipitation mentioned above, is considered to be due to near-neutralconditions on these nights.We find a difference in the ratio of the equilibrium-equivalent concentration of²²²Rn (the activity concentration of short-lived ²²²Rn daughters) tothe activity concentration of ²²²Rn during the first observation period and thatduring the second. The difference can be explained by snow cover on the ground. Wealso find differences among the ratios of the activity concentration of the short-lived²²²Rn daughters to that of ²²²Rn during the three observation periods.These differences can be explained by the submergence of paddy fields.     

渤海西岸平原海平面上升危害性评估

本文按照ＩＰＣＣ第三工作组海岸管理小组拟定的国际共同研究大纲与方法，在对渤海西岸平原海平面上升的危害性进行评估时，应用ＴＭ遥感影像与地理信息系统，由土地利用类型、海岸蚀积动态叠加１─６ｍ等高线编制成环境地形图，再与地面形变图等辅助图件对照分析，预测海平面上升对环境和社会经济的危害。