Size distribution of detrital mineral grains suspended in surface waters of the Yellow Sea and East China sea

Anisotropic detrital mineral grains were segregated microscopically from the suspended matter in surface waters of the Yellow Sea and East China Sea. Microscopic grain-size measurements of the anisotropic minerals were carried out for more than 80 slide specimens which are distributed homogeneously in the Yellow Sea and East China Sea. The distribution maps of mean grain size and sorting coefficients indicate that the mean size becomes coarser as one goes offshore, and the sorting coefficients are larger in the southern portion and smaller in the northern portion of this region. The clay-sized minerals in the suspended sediments carried out by the deltaic rivers of the continent were deposited in the nearshore area while coarser silt-sized minerals were suspended in offshore waters. The larger sorting coefficients (standard deviations) in the southern portion may imply that the silt-sized grains of offshore waters contain coarser sand-sized grains. The sand-sized grains may be supplied from offshore Taiwan and the Bashi Channel and transported by the main flow of the Kuroshio current.     

Seismic response of a cut‐and‐cover tunnel isolated by polymer material

An effective method for the seismic retrofitting of the sidewalls of cut‐and‐cover tunnels has not yet been established. Thus, a new method of seismic retrofitting for cut‐and‐cover tunnels, called the ‘polymer isolation method’, is developed here. In this method, thin walls made of polymer materials, called ‘isolation walls’, are inserted between the ground and the sidewalls of a tunnel. We demonstrate the effectiveness of the proposed method in reducing the seismic response of tunnels by using some numerical simulations. It is found that the proposed method depends on the thickness of the soil cover over the tunnel and the ratio of the stiffness between the soil and the structure. Furthermore, a simple chart is proposed for convenience to represent the applicability of the polymer isolation method to the design of seismic retrofits for cut‐and‐cover tunnels. Although this particular chart has been obtained through a limited case, some other typical cases in which the chart can also be implemented for special conditions are addressed, and the applicability and the limitations of this chart are suggested for possible conditions of the ground and of tunnel structures. Copyright © 2012 John Wiley & Sons, Ltd.     

Resistivity exploration for altered zone at otake geothermal area — Japan

Geothermal electric power plant with a capacity of 10 mw has been now constructed by the Kyushu Electric Power Co. Ltd. at Otake, northern part of the Kyushu Island. Resistivity exploration, one of geophysical prospecting applied to this field in order to investigate the subsurface structure accompanied with natural steams, indicated low resistivity layer corresponding to altered zone of andesite due to hydrothermal agents. For the rapid interpretation of resistivity sounding curves, a method of calculating the standard curve for the multiple layered earth is developed in the utilization of an electronic digital computer. Some examples to show the application of this method are given, and tinally the result is described of resistivity measurement at Otake geothermal area.     

Nanoscale occurrence of Pb in an Archean zircon

We report, for the first time, a direct, atomic-scale characterization of Pb in zircon (4.4-3.1 Ga) from the early Archean Yilgarn craton in Australia using high-resolution HAADF-STEM. Two forms of Pb have been identified: Pb concentrated at ∼3 atom% as a nanoscale patch in zircon structure, and Pb concentrated within the amorphous domain created by fission fragment damage. The first result suggests that the Pb atoms directly substitute for Zr⁴⁺ in the zircon structure, and the latter observation demonstrates that Pb diffusion can occur through amorphous regions created by radiation damage, although volume diffusion is typically considered to be the dominant mechanism for Pb diffusion. Beyond the first percolation point, i.e., when the amorphous domains overlap and form a fully interconnected network of amorphous domains, there is a new pathway for the diffusion of Pb that is faster than volume diffusion through crystalline zircon.     

Iron oxidation state of a 2.45-Byr-old paleosol developed on mafic volcanics

The 2.45-Byr-old weathering profile developed on early Proterozoic mafic volcanics located near Cooper Lake, Ontario, Canada, was examined geochemically and mineralogically for a better understanding of the atmospheric oxygen evolution. Ferrous to ferric ion, Fe(II) and Fe(III), respectively, ratios of the bulk rock samples were analyzed by Mössbauer spectrometry. The total Fe (Fe(T)) and Fe(II) concentrations decrease from 12.0 and 11.2 wt.% to 1.85 and 0.89 wt.%, respectively, from the bottom to the top of the weathering profile. The Fe(T) and Fe(II) concentrations normalized to Ti and Zr, as well as the Fe(II)/Fe(III) ratio of raw data, linearly decrease with depth toward the top, while the Fe(III) concentration remains nearly constant throughout the profile. The linear decrease of Fe(II), accompanied by the nearly constant distribution of Fe(III), is difficult to be explained by the scenario of oxidizing weathering and subsequent reducing hydrothermal alteration. The behaviors of Fe(II) and Fe(III) can be simply explained by anoxic weathering. The anoxic weathering suggests that the 2.45-Ga atmosphere was anoxic. The slight increase of Fe/(Fe+Mg) in the octahedral sites of chlorite toward the top and no Ce anomaly in the REE patterns are also consistent with anoxic weathering.     

High thallium content in Kuroko-type ore

Tl, Ga and Ge contents of Kuroko and other types of ore deposits were analysed semiquantitatively and quantitatively. The results show that Tl content is extremely high in Kuroko-type deposits compared to other types of mineralization. The T1 content is especially high in yellow ore and pyrite crystals; thus this element is considered to be incorporated in pyrite.     

Differential timing of vertical-axis block rotations in the northern Ryukyu Arc: Paleomagnetic evidence from the Koshikijima Islands,Japan

Over 300 samples for paleomagnetic analysis and K–Ar dating were collected from 27 sites at NW–SE and NE–SW trending dike swarms (herein, NW dikes and NE dikes, respectively) in the Koshikijima Islands, northern Ryukyu Arc. The NW dikes are Middle Miocene in age and have directions (D = ? 37.7^°, I = 51.8^°, α₉₅ = 9.6^°, and κ = 40.8) that are deflected westward relative to the stable eastern Asian continent. Conversely, the NE dikes, of Late Miocene age, have directions (D = 16.1^°, I = 57.7^°, α₉₅ = 7.1^°, and κ = 41.9) that show no such deflection. These differences are interpreted as indicating that the Koshikijima Islands underwent approximately 40^° of counter-clockwise rotation during the Middle to Late Miocene. A synthesis of the paleomagnetic and structural data suggests a three-stage history of extensional deformation: (1) displacement upon normal faults (F₁ faults) without vertical-axis block rotation, (2) strike-slip reactivation of F₁ faults and oblique-normal displacement on NE–SW-trending faults (F₂ faults) with vertical-axis block rotation, and (3) oblique-normal displacement on F₂ faults without vertical-axis block rotation. Regional differences in the timing and amount of counter-clockwise vertical-axis block rotations indicate that the northern Ryukyu Arc rotated as several distinct rigid blocks.     

Sound velocity measurements in dhcp-FeH up to 70 GPa with inelastic X-ray scattering: Implications for the composition of the Earth's core

We have determined the density evolution of the sound velocity of dhcp-FeH_x (x ≈ 1) up to 70 GPa at room temperature, by inelastic X-ray scattering and by X-ray diffraction. We find that the variation of V_P with density is different for the ferromagnetic and nonmagnetic dhcp-FeH_x, and that only nonmagnetic dhcp-FeH_x follows Birch's law. Combining our results with Birch's law for iron and assuming an ideal two-component mixing model, we obtain an upper bound of the hydrogen content in the Earth's inner core, 0.23(6) wt.% H, corresponding to FeH_0.13(3). The iron alloy with 0.23(6) wt.% H can satisfy the density, and compressional and shear sound velocities of the PREM inner core, assuming that there are no other light elements in the inner core.