Mineralogical and textural variation of silica minerals in hydrothermal flow-through experiments: Implications for quartz vein formation

We conducted hydrothermal flow-through experiments at 430 °C and 31 MPa to investigate the mechanism of silica precipitation on granite under crustal conditions. Two experiments were performed using different input solutions: a single-component Si solution, and a multi-component solution with minor Al, Na, and K. The degree of supersaturation with respect to quartz, Ω = C_Si/C_Si,Qtz,eq, where C_Si and C_Si,Qtz,eq indicate Si concentration in solutions and the solubility of quartz within water, respectively, decreased from 3-3.5 to <1.1 along the flow path. A variety of silica minerals formed during the experiments (opal-A, opal-C, chalcedony, and quartz), and their occurrences and modal abundances changed in response to Ω and the presence of additives in the solution.For near-equilibrium solutions (Ω < ∼1.2), silica precipitation occurred in a simple way in both experiments, being restricted to overgrowths on pre-existing quartz surfaces in the granite. At higher saturation levels (Ω > ∼1.2), silica minerals were deposited on other surfaces in addition to quartz. In the single-component experiment, the dominant silica minerals changed in the order of opal-A → opal-C → quartz with decreasing Si concentration along the flow path. In contrast, in the multi-component experiment, quartz and minor chalcedony formed throughout the entire reaction vessel. This finding indicates that impurities (Na, K, and Al) in the solutions inhibited the precipitation of opal and enhanced the direct nucleation of quartz. The systematic appearance of metastable silica minerals were examined by nucleation processes and macroscopic precipitation kinetics. Our experimental results indicate that different precipitation mechanisms yield contrasting textures, which in turn suggests that vein textures can be used as indicators of solution chemistry within the fracture.     

Hortonian overland flow from Japanese forest plantations—an aberration,the real thing,or something in between?

There is a growing opinion that poorly managed plantation forests in Japan are contributing to increased storm runoff and erosion. Here we present evidence to the contrary from runoff plots at two scales (hillslope and 0·5 × 2 m plots) for several forest conditions in the Mie and Nariki catchments. Runoff coefficients from small plots in untended hinoki forests were variable but typically higher than from better managed or deciduous forests during small storms at Nariki; at Mie, runoff during small events was highly variable from all small plots but runoff coefficients were similar for hinoki plots with and without understory vegetation, while the deciduous plot had lower runoff coefficients. Storm runoff was less at the hillslope scale than the plot scale in Mie; these results were more evident at sites with better ground cover. During the largest storms at both sites, differences in runoff due to forest condition were not evident regardless of scale. Dynamic soil moisture tension measurements at Nariki indicated that during a large storm, flow in the upper organic‐rich and root‐permeated soil horizons was 3·2 times higher than measured overland runoff from a small hinoki plot with poor ground cover and 8·3 times higher than runoff from a deciduous forest plot. On the basis of field observations during storms, at least a portion of the monitored ‘Hortonian overland flow’ was actually occurring in this near‐surface ‘biomat’. Therefore our field measurements in both small and large plots potentially included biomat flow in addition to short‐lived Hortonian runoff. Because overland flow decreased with increasing scale, rill erosion did not occur on hillslopes. Additionally, runoff coefficients were not significantly different among cover conditions during large storms; thus, the ‘degraded’ forest conditions appear not to greatly enhance peak flows or erosion potential at larger scales, especially when biomat flow is significant. Copyright © 2007 John Wiley & Sons, Ltd.     

Garnet-amphibolites at Yokokawa in the Abukuma metamorphic belt,Japan

The mineralogy and petrochemistry of the garnet-amphibolites from the highgrade part of the Abukuma metamorphic belt have been studied, using five analyses of rocks, five of hornblendes, three of garnets and one analysis of cummingtonite, Garnetiferous amphibolites are rich in Fe, whereas non-garnetiferous ones are rich in Mg, especially in cummingtonite-amphibolite. The chemical composition of hornblendes associated with garnet is pargasitic and rich in FeO and poor in CaO, but that of non-garnetiferous rocks is rich in MgO. The garnets are rich in almandine molecule. Mg/Mg + Fe²⁺ ratios of both hornblendes and garnets correspond with those of the host rocks. The development of garnet in the Adirondack metabasites belonging to the upper almandine-amphibolite and granulite facies is observed in Mg-rich rocks as well as in Fe-rich rocks, in which both garnet and hornblende are rich in Mg respectively. However, under the conditions of the andalusite-sillimanite type metamorphism as shown in the Abukuma Plateau, Fe-rich garnet occurs in Fe-rich basic rocks, but cummingtonite occurs in Mg-rich ones instead of Mg-rich garnet. Finally, the problem of polymetamorphism is discussed. The cummingtonite-amphibolite may be the product of polymetamorphism, and Mg-rich garnet which had been present previously was decomposed to cummingtonite and plagioclase by the subsequent regional metamorphism of andalusite-sillimanite type.     

Overview of the MITI Nankai Trough Wells: A Milestone in the Evaluation of Methane Hydrate Resources

Abstract. Bottom-simulating reflectors suggestive of the presence of methane hydrates are widely distributed below the ocean floor around Japan. In late 1999, drilling of the MITI Nankai Trough wells was conducted to explore this potential methane hydrate resource and a Tertiary conventional structure. The wells are located in the Northwest Pacific Ocean off Central Japan at a water depth of 945 m. A total of six wells were drilled, including the main well, two pilot wells, and three post survey wells at intervals of 10–100 m. All wells except the first confirmed the occurrence of hydrates based on logging-while-drilling, wire-line logging and/or coring using a pressure and temperature coring system in addition to conventional methods. Based on the various well profiles, four methane hydrate-bearing sand-rich intervals in turbidite fan deposits were recognized. Methane hydrates fill the pore spaces in these deposits, reaching saturation of up to 80 % in some layers. The methane hydrate-bearing turbiditic sand layers are less than 1 m thick, with a total thickness of 12–14 m. The bottom depth of high hydrate concentration correlates well with the depth of the bottom-simulating reflector. Based on these exploration results, the Japanese government inaugurated a 16-year methane hydrate exploitation program in 2001.     

Nanoscale occurrence of Pb in an Archean zircon

We report, for the first time, a direct, atomic-scale characterization of Pb in zircon (4.4-3.1 Ga) from the early Archean Yilgarn craton in Australia using high-resolution HAADF-STEM. Two forms of Pb have been identified: Pb concentrated at ∼3 atom% as a nanoscale patch in zircon structure, and Pb concentrated within the amorphous domain created by fission fragment damage. The first result suggests that the Pb atoms directly substitute for Zr⁴⁺ in the zircon structure, and the latter observation demonstrates that Pb diffusion can occur through amorphous regions created by radiation damage, although volume diffusion is typically considered to be the dominant mechanism for Pb diffusion. Beyond the first percolation point, i.e., when the amorphous domains overlap and form a fully interconnected network of amorphous domains, there is a new pathway for the diffusion of Pb that is faster than volume diffusion through crystalline zircon.     

Radiolarian Age of Chert-hosted Bedded Manganese Deposits from the Gen-otani Mine in the Tamba District, Northern Kyoto City, Japan

Abstract. Numerous bedded manganese deposits sporadically distributed throughout the Tamba district, southwestern Japan are intercalated within chert sequence. It is well known that radiolarian remains are commonly included in both bedded manganese deposits and host cherts. The Gen‐otani mine, one of these deposits, is located at Otani, Keihoku‐Shimonaka, northern Kyoto City. Chemical composition and age of the chert sequence at the mine were examined. Mainly according to SiO₂ and MnO contents together with lithology, the chert sequence is divided into three sections; lower massive chert, middle bedded manganese deposit and upper bedded chert sections. Radiolarian faunas consisting of middle Jurassic species such as Eucyrtidiellum unumaense, Dictyomitrella(?) kamoensis, Parvicingula dhimenaensis, Sethocapsa aitai, Sethocapsa kodrai, Transhsuum brevicostatum, Tricolocapsa plicarum, Unuma echinatus and others were extracted from both the middle manganese section and overlying bedded chert of the upper section. This examination reveals that the bedded manganese deposit at the Gen‐otani mine formed until Bajocian to early Bathonian (middle Middle Jurassic) in age.     

Kalman filtering in groundwater flow modelling: problems and prospects

The popularity of applying filtering theory in the environmental and hydrological sciences passed its first climax in the 1970s. Like so many other new mathematical methods it was simply the fashion at the time. The study of groundwater systems was not immune to this fashion, but neither was it by any means a prominent area of application. The spatial-temporal characteristics of groundwater flow are customarily described by analytical or, more frequently, numerical, physics-based models. Consequently, the state-space representations associated with filtering must be of a high order, with an immediately apparent computational over-burden. And therein lies part of the reason for the but modest interest there has been in applying Kalman filtering to groundwater systems, as reviewed critically in this paper. Filtering theory may be used to address a variety of problems, such as: state estimation and reconstruction, parameter estimation (including the study of uncertainty and its propagation), combined state-parameter estimation, input estimation, estimation of the variance-covariance properties of stochastic disturbances, the design of observation networks, and the analysis of parameter identifiability. A large proportion of previous studies has dealt with the problem of parameter estimation in one form or another. This may well not remain the focus of attention in the future. Instead, filtering theory may find wider application in the context of data assimilation, that is, in reconstructing fields of flow and the migration of sub-surface contaminant plumes from relatively sparse observations. Received: October 27, 1997     

High-Speed Data Acquisition System Messia for Subaru

We have developed a high-speed data acquisition system, Messia-III (Modularized Extensible SyStem for Image Acquisition) for Subaru, Japanese 8.2m telescope. Messia has a direct 1-Gbps link to a host UNIX workstation. Messia is a VMEbus-based system but it does not have local OS nor CPU's in order to minimize software development and maintenance.     

A momentum distribution of high energy particles around Crab pulsar

We determine the momentum distribution of the relativistic particles near the Crab pulsar from the observed X- and -ray spectra (10³10⁹ eV), provided that the curvature radiation is responsible for it. The power law spectrum for the relativistic electrons,f() ^–5, reproduces a close fit to the observed high-energy photon spectrum. The theoretically determined upper limit to the momentum (due to radiation damping), _M 8×10⁶, corresponds to the upper cut-off energy of the -ray spectrum, 10⁹ eV. The lower limit to the momentum, _m 1.8×10⁵, is chosen such that flattening of the X-ray spectrum below 10 keV is simulated. The number density of these electrons is found to be much higher than the Goldreich-Julian density. We also discuss pulse shape and polarization of high-energy photons. The extremely high density of particles and the steep momentum spectrum are difficult to understand. This may imply that another, more efficient, mechanism is in operation.