Evaluation of hydrogeochemical characteristics and the impact of weathering in seepage water collected within the sedimentary formation

A study was conducted by collecting eight seepage water samples that drain through the sedimentary rocks, mainly sandstone and shale, to evaluate the hydrogeochemical characteristics. The collected samples were analyzed for physico-chemical parameters using standard procedures. Three water types were identified in the Piper plot and the hydrogeochemical evolution starts from a Ca–Cl facies (type 1) via mixed Ca–Mg–Cl and Ca–Na–HCO₃ facies (type 2) to Na–Cl facies (type 3). Increasing trend of electrical conductivity (EC) values were observed from type 1 water to type 3 water. Lower ionic concentrations with an average EC value of 35.7 µs/cm in Ca–Cl facies indicate the recharge water by monsoonal rainfall, and ion exchange/weathering process is reflected in the mixing zone. Higher ionic concentration with an average EC value of 399 µs/cm is noted in Na–Cl facies, which indicates the ion exchange during water–rock interaction. Higher log pCO₂ values are also found in this facies, revealing the longer residence time of seepage water in the rock matrix, which release more ions into the water. The relative mobility of elements during weathering suggest that the order of mobility in both sandstone and shale is Na > Ca > Mg > K. It was observed that the hydrogeochemistry of seepage water is mainly controlled by the bedrock geology.     

Prioritization of subwatersheds based on quantitative morphometric analysis in lower Bhavani basin,Tamil Nadu,India using DEM and GIS techniques

Watershed prioritization is one of the most important processes in natural resource management system especially in areas of sustainable watershed development and planning. Morphometric characteristics are the viable entity to understand the hydrological behavior of the subwatershed. For prioritization of subwatershed, morphometric analysis was utilized by using the linear, areal, and relief aspects of the drainage basin. In this context, remote sensing and GIS has been proved to be an efficient tool to identify the morphological features. The Survey of India (SOI) topographical maps, satellite data IRS-LISS III, and Cartosat DEM data were utilized to understand the drainage pattern and also for prioritization of subwatershed areas. The prioritization of subwatershed has been attempted using novel and quantitative approaches based on compound parameter ranking for soil erosion. Lower compound factors were chosen as the most feasible for soil erosion. Based on the observation, eight subwatersheds with a higher degree of the slope were severely prone to soil erosion and remaining 21 subwatersheds occur in low-lying areas that can be developed as sustainable watersheds. The identified subwatershed requires immediate soil remediation and water conservation measures for efficient watershed planning and management. The proposed study might be helpful for resource planners, government agencies, private sectors, and other stake holders to take up soil conservation measures and fixation of water-harvesting structures for better decision making.