Impact of ancient metal smelting on arsenic pollution in the Pecora River Valley,Southern Tuscany,Italy

A significant As anomaly has been reported in the literature for stream sediments and unlithified Quaternary deposits of the Pecora River valley in Southern Tuscany, extending from the “Colline Metallifere” pyrite-base metals district to the Tyrrhenian Sea. The As anomaly spreads over several square kilometers around a core that exceeds 500 ppm. Several source contributions (from natural to anthropogenic) have been invoked to explain the observed As distribution in the Pecora Valley, including the metal-working industry which was active in this area, particularly in Etrusco-Roman times and in the Middle Ages. In order to evaluate the contribution of ancient mining and metallurgical activities in the Pecora Valley to elevated As concentrations in the environment, a detailed mineralogical and geochemical survey of metallurgical slags and smelted ore minerals was undertaken from six different sites through the Pecora Valley: Poggio Butelli (Etrusco-Roman iron slags); Sata Creek, Arialla, Marsiliana, Forra and Cascata sites (all Medieval base metals slags). The As content of Etrusco-Roman slags is relatively low (few tens of ppm), whereas Medieval slags show variable, but higher amounts of base metals (±Ag) (ranging from tens to tens of thousands ppm) and As (up to 267 ppm, with average contents of about 40 ppm). Arsenic is mostly partitioned in sulfides disseminated through the glassy groundmass rather than in solid solution with the glassy matrix. Remnants of the ore used for base metal and Ag smelting during the Middle Ages had the highest As contents (up to about 1000 ppm).     

Paleontology,sedimentology and paleoenvironment of a new fossiliferous locality of the Jurassic Cañadón Asfalto Formation,Chubut Province,Argentina

A new Late Jurassic assemblage of “conchostracans”, ostracods, bivalves and caddisfly cases from the locality “Estancia La Sin Rumbo”, Chubut Province (Patagonia, Argentina) is recorded. The fossils occur in the upper part of an outcropping 45 m thick volcaniclastic lacustrine sequence of yellowish tuffs and tuffites of the Puesto Almada Member, which is the upper member of the Cañadón Asfalto Formation with U/Pb age of 161 ± 3 Ma. The sequence represents one sedimentary cycle composed of a (lower) hemicycle of expansion and a (higher) hemicycle of contraction of the water body. The invertebrates lived in small freshwater bodies during the periods of expansion of the lake. The occurrence of a great number of small spinicaudatans, associated with mud-cracks, is evidence of dry climatic conditions and suggests several local mortality events. The spinicaudatan record of the fushunograptid–orthestheriid (component of the Eosestheriopsis dianzhongensis fauna) and the presence of Congestheriella rauhuti Gallego and Shen, suggest a Late Jurassic (Oxfordian to Tithonian) age. Caddisfly cases are recorded for the first time in the Cañadón Asfalto Basin.     

The formation and evolution of an isolated submarine valley in the North Channel,Irish Sea: an investigation of Beaufort's Dyke

Beaufort's Dyke is a submarine depression located in the North Channel of the Irish Sea. With a maximum depth of 312 m, the dyke is one of the deepest areas within the European continental shelf. Integration and interpretation of 450 km of sparker seismic data and full‐coverage bathymetric data derived from multi‐beam echo sounder surveys allow for the investigation of the formation processes of Beaufort's Dyke and the evolution of geomorphological features within it. The dyke, formed by composite subglacial processes dominated by subglacial meltwater discharge, is interpreted as a tunnel valley. The regional isolation of Beaufort's Dyke may be explained by the bounding of the North Channel by the bedrock masses of Ireland and Scotland, coupled with the exploitation of structural weakness along a fault plane and presence of halite in the eroded substrate enhancing the erosive potential of the overlying glacier. Beaufort's Dyke has probably been maintained as an open feature by strong rectilinear tidal currents. The morphology of lunate sediment waves and a large parabolic bedform towards the south of the dyke contradict the observed dominant S–N mean hydrodynamic flow recorded within the North Channel, suggesting an alternative hydrodynamic regime either within the dyke or during bedform creation. Copyright © 2011 John Wiley & Sons, Ltd.     

Primary production of Inner Mongolia, China, between 1982 and 1999 estimated by a satellite data-driven light use efficiency model

Declining biological production as a part of an ongoing land degradation process is considered a severe environmental problem in the dry northern and northwestern regions of China. The aim of this study is to develop and adapt a satellite data-driven gross primary production model called Lund University light use efficiency model (LULUE) to temperate conditions in order to map gross primary production (GPP) for the Grasslands of Inner Mongolia Autonomous Region (IMAR), China, from 1982 to 1999. The water stress factor included in the original model has been complemented with two temperature stress factors. In addition, algorithms that allocate the proportions of C3/C4 photosynthetic pathways used by plants and that compute temperature-based C3 maximum efficiency values have been incorporated in the model.The applied light use efficiency (LUE) model is using time series of the Normalized Difference Vegetation Index (NDVI), CLouds from AVHRR (CLAVR) from the 8-km resolution NOAA Pathfinder Land Data Set (PAL). Quasi-daily rainfall and monthly minimum and maximum temperatures, together with soil texture information, are used to compute water limitations to plant growth. The model treats bare soil evaporation and actual transpiration separately, a refinement that is more biophysically realistic, and leads to enhanced precision in our water stress term, especially across vegetation gradients.Based on ground measurements of net primary production (NPP) at one site, the LULUE reproduces the variability of primary production better than CENTURY or NDVI alone. Mean annual GPP between 1982 and 1999 range from about 100 g/m² in desert regions in the west to about 4000 g/m² in the northeast of IMAR, and the coefficient of variation for GPP is highest near the margins of the deserts in the west where rainfall is erratic. Linear trends fitted through the 18-year time series reveal that the western regions have encountered no change, while a large area in the center of the IMAR shows marked increases in GPP. In the northeast, negative trends in GPP are noted and coincide with rainfall trends. Though the high inter-annual variability in primary production undermines the identification of significant trends, we could not isolate any general decline in grassland primary production.     

Intercontinental response to variations in the Arabia-Eurasia Plate convergence,calcite e-twin evidence of the Kuhbanan Fault system,Central Iran

Variations in the plate convergence direction have generally reflected on the kinematics of the major fault zones developed in the intercontinental parts of the collision zones. The Kuhbanan Fault system is one of the most important intercontinental faults in the Arabia-Eurasia collision zone with a dextral strike slip mechanism. This fault system is composed of three fault strands including Kuhbanan, Bazargan, and Kerman Faults. Here we used calcite e-twin analysis of the vein samples developed in these fault zones to reconstruct deformation condition and the paleodifferential stress direction and magnitude at the Kuhbanan Fault system. Our results represent 190°C-200°C of the deformation temperature and related 5–6 ± 1 km of deformation depth at the Kuhbanan Fault system. Calculated paleodifferential stress magnitude in the Kuhbanan Fault system using e-twin parameters ranges from 169-196 MPa similar to the inner parts of the orogenic systems. Comparing the data set of the Kuhbanan Fault system with previous studies at the Zagros orogen represents an increase of deformation depth and paleodifferential stress magnitudes from the foreland of the Zagros orogen to its hinterland and finally northward around the Kuhbanan Fault system in the central Iranian blocks. We have also proposed a shift of the stress direction from paleo NE to recent N directed by comparing paleostress direction deduced from the calcite e-twin and recent stress direction calculated from GPS and earthquake data analysis around the Kuhbanan Fault system. This kinematics change due to plate reorganization is in agreement with the observed regional variation in convergence direction all in the Arabia-Eurasia collision zone.     

Curation protocol of Phobos sample returned by Martian Moons eXploration

Japan Aerospace Exploration Agency's Martian Moons eXploration (MMX) mission will launch a spacecraft in 2024 to return samples from Phobos in 2029. Curatorial work for the returned Phobos samples is critical for the sample allocation without degrading the sample integrity and subsequent sample analysis that will provide new constraints on the origin of Phobos and the evolution of the circum-Mars environment. The Sample Analysis Working Team of the MMX is designing the sample curation protocol. The curation protocol consists of three phases: (1) quick analysis (extraction and mass spectrometry for gases), (2) pre-basic characterization (bulk-scale observation), and (3) basic characterization (grain-by-grain observation and allocation of the sample aliquots). Nondestructive analyses within the clean chamber (e.g., visible and near-infrared spectral imaging) and outside the chamber (e.g., gas mass spectrometry) are incorporated into the curation flow in coordination with the MMX mission instrument teams for ground-truthing the remote-sensing data sets. The MMX curation/sample analysis flow enables the seamless integration between the sample and remote-sensing data sets to maximize the scientific value of the collected Phobos samples.     

The Bulgheria canyon-fan: a small-scale proximal system in the eastern Tyrrhenian Sea (Italy)

The Bulgheria canyon-fan system in the eastern Tyrrhenian Sea displays well-developed, small-scale, fluvial-like features and has formed alongside the northern slope of the Sapri peri-Tyrrhenian basin. This study reveals, for the first time, the morphology and course of the present-day system as well as the buried elements based on a Digital Terrain Model and high-resolution seismic profiles interpretation. Two adjacent canyons (Infreschi and Luna) originate in the Cilento outer shelf at a short distance from each other and feed an intraslope basin fan through two main sub-parallel channels that run about 12 and 8 km, respectively. Channel and levee development seems to be controlled primarily by the local slope gradient and by Coriolis forces that induce a faster vertical growth of the right-side features, as is often observed in the Northern Hemisphere. Centrifugal forces, on the other hand, have induced episodic flow-stripping at the meander loops and bends, causing local destruction of the main channel levees rather than new levee growth at the outer bends. Overbank deposits are associated with overspill turbidite deposition in the mid fan where a topographic constraint occurs, whereas large-sediment, low-angle wave fields are mainly developed on the outer fan. Buried features and relict morphologies suggest that the Infreschi channel experienced at least two phases of re-incision since the final stages of the middle Pleistocene. Local re-adjustment of outer lobe growth due to channel avulsion and meander abandonment is possibly a consequence of relative base-level fluctuations. The sedimentary record of the mid and outer fan includes outrun mass wasting deposits from extensive failures of the Sapri slope. Indeed, a marked scar is present on the eastern side of the modern outer lobe that indicates the persistency of mass flow passages up to recent times. In addition to the environmental factors that are currently considered to cause canyon formation on the shelf margin, this study proposes the possibility that the head canyon branch close to the mainland was incised by massive and persistent underground freshwater flow from the adjacent aquifer when the sea-level was lower than at present.     

Late-Stage Breast Cancer Diagnosis and Health Care Access in Illinois∗

The variations of breast cancer mortality rates from place to place reflect both underlying differences in breast cancer prevalence and differences in diagnosis and treatment that affect the risk of death. This article examines the role of access to health care in explaining the variation of late-stage diagnosis of breast cancer. We use cancer registry data for the state of Illinois by zip code to investigate spatial variation in late diagnosis. Geographic information systems and spatial analysis methods are used to create detailed measures of spatial access to health care such as convenience of visiting primary care physicians and travel time from the nearest mammography facility. The effects of spatial access, in combination with the influences of socioeconomic factors, on late-stage breast cancer diagnosis are assessed using statistical methods. The results suggest that for breast cancer, poor geographical access to primary health care significantly increases the risk of late diagnosis for persons living outside the city of Chicago. Disadvantaged population groups including those with low income and racial and ethnic minorities tend to experience high rates of late diagnosis. In Illinois, poor spatial access to primary health care is more strongly associated with late diagnosis than is spatial access to mammography. This suggests the importance of primary care physicians as gatekeepers in early breast cancer detection.     

U–Pb geochronology,Sr–Nd isotopic compositions,geochemistry and petrogenesis of Shah Soltan Ali granitoids,Birjand, Eastern Iran

The Shah Soltan Ali area (SSA) is located in the eastern part of the Lut Block metallogenic province. In this area different types of sub-volcanic intrusions including diorite porphyry, monzonite porphyry and monzodiorite porphyry have intruded into basaltic and andesitic rocks. Zircon U–Pb dating and field observations indicate that intermediate to mafic volcanic rocks (38.9 Ma) are older than subvolcanic units (38.3 Ma). The subvolcanic intrusions show high-K calc-alkaline to shoshonitic affinity and are metaluminous. Based on mineralogy, high values of magnetic susceptibility [(634 to 3208) × 10^?5 SI], and low initial ⁸⁷Sr/⁸⁶Sr ratios, they are classified as belonging to the magnetite-series of oxidant I-type granitoids and are characterized by an enrichment in LREEs relative to HREEs, with negative Nb, Ti, Zr and Eu anomalies. These granitoids are related to volcanic arc (VAG) and were generated in an active continental margin. Low initial ⁸⁷Sr/⁸⁶Sr ratios (0.7043 to 0.7052) and positive εNd values (+1.48 to +3.82) indicate that the parental magma was derived from mantle wedge. Parental magma was probably formed by low degree of partial melting and metasomatized by slab derived fluids. Then assimilation and fractional crystallization processes (AFC) produced the SSA rocks. This magma during the ascent was contaminated with the crustal material.All data suggest that Middle-Late Eocene epoch magmatism in the SSA area, occurred during subduction of Neo-Tethys Ocean in east of Iran (between Afghan and Lut Blocks).