River network travel time is correlated with dissolved organic matter composition in rivers of the contiguous United States

Most terrestrial allochthonous organic matter enters river networks through headwater streams during high flow events. In headwaters, allochthonous inputs are substantial and variable, but become less important in streams and rivers with larger watersheds. As allochthonous dissolved organic matter (DOM) moves downstream, the proportion of less aromatic organic matter with autochthonous characteristics increases. How environmental factors converge to control this transformation of DOM at a continental scale is less certain. We hypothesized that the amount of time water has spent travelling through surface waters of inland systems (streams, rivers, lakes, and reservoirs) is correlated to DOM composition. To test this hypothesis, we used established river network scaling relationships to predict relative river network flow-weighted travel time (FWTT) of water for 60 stream and river sites across the contiguous United States (3090 discrete samples over 10 water years). We estimated lentic contribution to travel times with upstream in-network lake and reservoir volume. DOM composition was quantified using ultraviolet and visible absorption and fluorescence spectroscopy. A combination of FWTT and lake and reservoir volume was the best overall predictor of DOM composition among models that also incorporated discharge, specific discharge, watershed area, and upstream channel length. DOM spectral slope ratio (R² = 0.77) and Freshness Index (R² = 0.78) increased and specific ultraviolet absorbance at 254 nm (R² = 0.68) and Humification Index (R² = 0.44) decreased across sites as a function of FWTT and upstream lake volume. This indicates autochthonous-like DOM becomes continually more dominant in waters with greater FWTT. We assert that river FWTT can be used as a metric of the continuum of DOM composition from headwaters to rivers. The nature of the changes to DOM composition detected suggest this continuum is driven by a combination of photo-oxidation, biological processes, hydrologically varying terrestrial subsidies, and aged groundwater inputs.     

Flow of Canadian basin deep water in the Western Eurasian Basin of the Arctic Ocean

The LOMROG 2007 expedition targeted the previously unexplored southern part of the Lomonosov Ridge north of Greenland together with a section from the Morris Jesup Rise to Gakkel Ridge. The oceanographic data show that Canadian Basin Deep Water (CBDW) passes the Lomonosov Ridge in the area of the Intra Basin close to the North Pole and then continues along the ridge towards Greenland and further along its northernmost continental slope. The CBDW is clearly evident as a salinity maximum and oxygen minimum at a depth of about 2000 m. The cross-slope sections at the Amundsen Basin side of the Lomonosov Ridge and further south at the Morris Jesup Rise show a sharp frontal structure higher up in the water column between Makarov Basin water and Amundsen Basin water. The frontal structure continues upward into the Atlantic Water up to a depth of about 300 m. The observed water mass division at levels well above the ridge crest indicates a strong topographic steering of the flow and that different water masses tend to pass the ridge guided by ridge-crossing isobaths at local topographic heights and depressions. A rough scaling analysis shows that the extremely steep and sharply turning bathymetry of the Morris Jesup Rise may force the boundary current to separate and generate deep eddies.     

An excess of damped Lyman α galaxies near quasi-stellar objects

We present a sample of 33 damped Lyman α systems (DLAs) discovered in the Sloan Digital Sky Survey (SDSS) whose absorption redshifts ( z _abs) are within 6000 km s⁻¹ of the quasi-stellar object's (QSO) systemic redshift ( z _sys). Our sample is based on  731 2.5 < z _sys < 4.5  non-broad absorption line (non-BAL) QSOs from Data Release 3 (DR3) of the SDSS. We estimate that our search is ≈100 per cent complete for absorbers with N (H  i )  ≥ 2 × 10²⁰ cm⁻²  . The derived number density of DLAs per unit redshift, n ( z ), within  Δ v < 6000 km s⁻¹  is higher (3.5σ significance) by almost a factor of 2 than that of intervening absorbers observed in the SDSS DR3, i.e. there is evidence for an overdensity of galaxies near the QSOs. This provides a physical motivation for excluding DLAs at small velocity separations in surveys of intervening 'field' DLAs. In addition, we find that the overdensity of proximate DLAs is independent of the radio-loudness of the QSO, consistent with the environments of radio-loud and radio-quiet QSOs being similar.     

A carbon and nitrogen isotope study of diamond from primitive chondrites

Abstract Diamonds isolated from primitive chondrites of the carbonaceous, ordinary and enstatite groups have been analysed by high-resolution stepped combustion, followed by measurement of their C and N isotopes using a newly adapted technique that allows quantitative measurements of C/N ratios. The δ¹³C of the diamond is shown to vary between meteorite groups from ?32 to ?38%0, and the measured C/N ratios suggest that the N concentration of diamond ranges over a factor of 7 from 1800 ppm (Tieschitz) to 13,000 ppm (Adrar 003). The δ¹⁵N of N released from diamond is constrained to ?348 ± 7%. The complexity of the C release pattern and C/N ratio during combustion implies the presence of more than one component, which suggests that either more than one type of diamond is present in the samples, or unidentified additional phases are located in the acid-resistant residue. The components are present in varying proportions between meteorite groups. The data are compatible with a model of a mix of different diamond populations (some probably presolar and some possibly solar) existing in the early solar nebula, where each population originally contributed a roughly equal amount to chondrites of every class. Subsequent metamorphism has resulted in overall variations in δ¹³C and C/N ratios in diamond isolated from meteorites of differing petrologic grade without significantly altering the N isotopic composition. Possible ways for this to be achieved are explored.     

Vulnerability to environmental hazards in the Ciudad Juárez (Mexico)–El Paso (USA) metropolis: A model for spatial risk assessment in transnational context

The purpose of this paper is to present a geographic information system (GIS)-based method for mapping risk to environmental hazards. Framed by the hazards literature, the method has been developed to specifically overcome issues of data compatibility associated with transnational contexts. The approach is elaborated in reference to a project in which risk was spatially characterized, using a suite of biophysical and social indicators, for the Ciudad Juárez (Mexico)–El Paso (USA) metropolis. Results reveal clear spatial disparities in hazard vulnerability, both within and between the two cities, based on the differential allocation of selected risk factors. The case indicates that future international analyses will be advanced by the clear definition of concepts, the systematic mining of compatible variables, and the selection of valid risk indicators based on criteria that balance the need to incorporate contextual specificity with general comparability.     

Pronounced increase in slope instability linked to global warming: A case study from the eastern European Alps

In recent decades, slope instability in high-mountain regions has often been linked to increase in temperature and the associated permafrost degradation and/or the increase in frequency/intensity of rainstorm events. In this context we analyzed the spatiotemporal evolution and potential controlling mechanisms of small- to medium-sized mass movements in a high-elevation catchment of the Italian Alps (Sulden/Solda basin). We found that slope-failure events (mostly in the form of rockfalls) have increased since the 2000s, whereas the occurrence of debris flows has increased only since 2010. The current climate-warming trend registered in the study area apparently increases the elevation of rockfall-detachment areas by approximately 300 m, mostly controlled by the combined effects of frost-cracking and permafrost thawing. In contrast, the occurrence of debris flows does not exhibit such an altitudinal shift, as it is primarily driven by extreme precipitation events exceeding the 75th percentile of the intensity-duration rainfall distribution. Potential debris-flow events in this environment may additionally be influenced by the accumulation of unconsolidated debris over time, which is then released during extreme rainfall events. Overall, there is evidence that the upper Sulden/Solda basin (above ca. 2500 m above sea level [a.s.l.]), and especially the areas in the proximity of glaciers, have experienced a significant decrease in slope stability since the 2000s, and that an increase in rockfalls and debris flows during spring and summer can be inferred. Our study thus confirms that “forward-looking” hazard mapping should be undertaken in these increasingly frequented, high-elevation areas of the Alps, as environmental change has elevated the overall hazard level in these regions.     

Mapping potential surface ponding in agriculture using UAV-SfM

Among the environmental problems that could affect agriculture, one of the most critical is ponding. This may be defined as water storage on the surface in concavities and depressions due to soil saturation. Stagnant water can seriously affect crops and the management of agricultural landscapes. It is mainly caused by prolonged rainfall events, soil type, or wrong mechanization practices, which cause soil compaction. To better understand this problem and thus provide adequate solutions to reduce the related risk, high-resolution topographic information could be strategically important because it offers an accurate representation of the surface morphology. In the last decades, new remote sensing techniques provide interesting opportunities to understand the processes on the Earth's surface based on geomorphic signatures. Among these, Uncrewed Aerial Vehicles (UAVs), combined with the structure-from-motion (SfM) photogrammetry technique, represent a solid, low-cost, rapid, and flexible solution for geomorphological analysis. This study aims to present a new approach to detect the potential areas exposed to water stagnation at the farm scale. The high-resolution digital elevation model (DEM) from UAV-SfM data is used to do this. The potential water depth was calculated in the DEM using the relative elevation attribute algorithm. The detection of more pronounced concavities and convexities allowed an estimation and mapping of the potential ponding conditions. The results were assessed by observations and field measurements and are promising, showing a Cohen's k(X) accuracy of 0.683 for the planimetric extent of the ponding phenomena and a Pearson's r_xy coefficient of 0.971 for the estimation of pond water depth. The proposed workflow provides a useful indication to stakeholders for better agricultural management in lowland landscapes.     

Locating diversity: race,nativity and place in health disparities research

Nancy Krieger has been one of the leading voices in documenting how social ‘axes of difference’, including race, ethnicity and class make people vulnerable to poor health and limit their access to effective health care. We discuss the importance of ‘locating’ diversity in health inequalities research. This includes critically dissecting racial and ethnic axes into more nuanced social categories that incorporate differences based on immigration and other factors. It also involves considering how diverse population groups vary in their perception and use of space for health-related activities and exposures. Examples relating to immigrant populations’ health and access to health care are discussed.     

Reflected light from 3D exoplanetary atmospheres and simulation of HD 209458b

We present radiation transfer models that demonstrate that reflected light levels from 3D exoplanetary atmospheres can be more than 50 per cent lower than those predicted by models of homogeneous or smooth atmospheres. Compared to smooth models, 3D atmospheres enable starlight to penetrate to larger depths resulting in a decreased probability for the photons to scatter back out of the atmosphere before being absorbed. The increased depth of penetration of starlight in a 3D medium is a well-known result from theoretical studies of molecular clouds and planetary atmospheres. For the first time we study the reflectivity of 3D atmospheres as a possible explanation for the apparent low geometric albedos inferred for extrasolar planetary atmospheres. Our models indicate that 3D atmospheric structure may be an important contributing factor to the non-detections of scattered light from exoplanetary atmospheres. We investigate the self-shadowing radiation transfer effects of patchy cloud cover in 3D scattered light simulations of the atmosphere of HD 209458b. We find that, for a generic planet, geometric albedos can be as high as 0.45 in some limited situations, but that in general the geometric albedo is much lower. We conclude with some explanations on why extrasolar planets are likely dark at optical wavelengths.     

Modal abundances of CAIs: Implications for bulk chondrite element abundances and fractionations

Abstract— Modal abundances of Ca,Al‐rich inclusions (CAIs) are poorly known and reported data scatter across large ranges. CAIs are Poisson distributed, and if only small areas (<1000 mm²) are studied, the data are probably not representative of the true CAI modal abundances, explaining their reported large scatter in a single chondrite group. We combine reported CAI modal abundances and our own set, and present a complete list of CAI modal abundances in carbonaceous chondrites. This includes (in area%): CV: 2.98, CM: 1.21, Acfer 094: 1.12, CO: 0.99, CK/CV (Ningqiang and Dar al Gani [DaG] 055): 0.77, CK: 0.2, CR: 0.12 and CB: 0.1. CAIs are Poisson distributed and if only small areas are studied, the data are probably not representative of the true CAI modal abundances, Carbonaceous chondrites have excess bulk Al concentrations when compared to the CI‐chondritic value. We find a correlation between this excess and CAI modal abundances and conclude that the excess Al was delivered by CAIs. The excess Al is only a minor fraction (usually ?10 rel%, but 25 rel% in case of CVs) of the bulk chondrite Al and cannot have contributed much ²⁶Al to heat the chondrite parent body. Ordinary, enstatite, R and K chondrites have an Al deficit relative to CI chondrites and only very low CAI modal abundances, if any are present at all. Carbonaceous chondrites also had an initial Al deficit if the contribution of Al delivered by CAIs is subtracted. Therefore all chondrites probably lost a refractory rich high‐T component. Only minor amounts of CAIs are present in the matrix or have been present in the chondrule precursor aggregates. Most CAI size distributions contain more than one size population, indicating that CAIs from within a single meteorite group had different origins.