Intercontinental response to variations in the Arabia-Eurasia Plate convergence,calcite e-twin evidence of the Kuhbanan Fault system,Central Iran

Variations in the plate convergence direction have generally reflected on the kinematics of the major fault zones developed in the intercontinental parts of the collision zones. The Kuhbanan Fault system is one of the most important intercontinental faults in the Arabia-Eurasia collision zone with a dextral strike slip mechanism. This fault system is composed of three fault strands including Kuhbanan, Bazargan, and Kerman Faults. Here we used calcite e-twin analysis of the vein samples developed in these fault zones to reconstruct deformation condition and the paleodifferential stress direction and magnitude at the Kuhbanan Fault system. Our results represent 190°C-200°C of the deformation temperature and related 5–6 ± 1 km of deformation depth at the Kuhbanan Fault system. Calculated paleodifferential stress magnitude in the Kuhbanan Fault system using e-twin parameters ranges from 169-196 MPa similar to the inner parts of the orogenic systems. Comparing the data set of the Kuhbanan Fault system with previous studies at the Zagros orogen represents an increase of deformation depth and paleodifferential stress magnitudes from the foreland of the Zagros orogen to its hinterland and finally northward around the Kuhbanan Fault system in the central Iranian blocks. We have also proposed a shift of the stress direction from paleo NE to recent N directed by comparing paleostress direction deduced from the calcite e-twin and recent stress direction calculated from GPS and earthquake data analysis around the Kuhbanan Fault system. This kinematics change due to plate reorganization is in agreement with the observed regional variation in convergence direction all in the Arabia-Eurasia collision zone.     

U–Pb geochronology,Sr–Nd isotopic compositions,geochemistry and petrogenesis of Shah Soltan Ali granitoids,Birjand, Eastern Iran

The Shah Soltan Ali area (SSA) is located in the eastern part of the Lut Block metallogenic province. In this area different types of sub-volcanic intrusions including diorite porphyry, monzonite porphyry and monzodiorite porphyry have intruded into basaltic and andesitic rocks. Zircon U–Pb dating and field observations indicate that intermediate to mafic volcanic rocks (38.9 Ma) are older than subvolcanic units (38.3 Ma). The subvolcanic intrusions show high-K calc-alkaline to shoshonitic affinity and are metaluminous. Based on mineralogy, high values of magnetic susceptibility [(634 to 3208) × 10^?5 SI], and low initial ⁸⁷Sr/⁸⁶Sr ratios, they are classified as belonging to the magnetite-series of oxidant I-type granitoids and are characterized by an enrichment in LREEs relative to HREEs, with negative Nb, Ti, Zr and Eu anomalies. These granitoids are related to volcanic arc (VAG) and were generated in an active continental margin. Low initial ⁸⁷Sr/⁸⁶Sr ratios (0.7043 to 0.7052) and positive εNd values (+1.48 to +3.82) indicate that the parental magma was derived from mantle wedge. Parental magma was probably formed by low degree of partial melting and metasomatized by slab derived fluids. Then assimilation and fractional crystallization processes (AFC) produced the SSA rocks. This magma during the ascent was contaminated with the crustal material.All data suggest that Middle-Late Eocene epoch magmatism in the SSA area, occurred during subduction of Neo-Tethys Ocean in east of Iran (between Afghan and Lut Blocks).     

Impact of ancient metal smelting on arsenic pollution in the Pecora River Valley,Southern Tuscany,Italy

A significant As anomaly has been reported in the literature for stream sediments and unlithified Quaternary deposits of the Pecora River valley in Southern Tuscany, extending from the “Colline Metallifere” pyrite-base metals district to the Tyrrhenian Sea. The As anomaly spreads over several square kilometers around a core that exceeds 500 ppm. Several source contributions (from natural to anthropogenic) have been invoked to explain the observed As distribution in the Pecora Valley, including the metal-working industry which was active in this area, particularly in Etrusco-Roman times and in the Middle Ages. In order to evaluate the contribution of ancient mining and metallurgical activities in the Pecora Valley to elevated As concentrations in the environment, a detailed mineralogical and geochemical survey of metallurgical slags and smelted ore minerals was undertaken from six different sites through the Pecora Valley: Poggio Butelli (Etrusco-Roman iron slags); Sata Creek, Arialla, Marsiliana, Forra and Cascata sites (all Medieval base metals slags). The As content of Etrusco-Roman slags is relatively low (few tens of ppm), whereas Medieval slags show variable, but higher amounts of base metals (±Ag) (ranging from tens to tens of thousands ppm) and As (up to 267 ppm, with average contents of about 40 ppm). Arsenic is mostly partitioned in sulfides disseminated through the glassy groundmass rather than in solid solution with the glassy matrix. Remnants of the ore used for base metal and Ag smelting during the Middle Ages had the highest As contents (up to about 1000 ppm).     

Hydrogeologic Characterization of a Fault-Related Dome Using Outcrop,Borehole and Electrical Resistivity Data

Geological structures introduce heterogeneity along deformed strata, which in turn exert a strong control on regional groundwater occurrences and water flow. We developed and applied procedures of structural, borehole and direct current resistivity (DCR) data to (1) figure out a reliable structural model of a fault-related dome, (2) visualize the relationship between structural complexity and aquifers geometry and (3) characterize the fault damage zones and its related sealing potentialities. The present approach was applied at the northern Eastern Desert, Egypt, considering its complex deformation history. To alleviate the uncertainties and artifacts in solving the DCR inverse problem, advanced and non-conventional inversion schemes were applied. Moreover, fault seal potentialities were assessed by applying the shale gouge ratio (SGR) estimation to predict the groundwater pathway flow. The main findings include: (a) The DCR measurements can be considered as a complementary tool to visualize the relationship between subsurface structures and aquifers geometry at highly deformed areas; (b) detailed surface structural data analysis combined with sophisticated inversion algorithms application can increase the reliability of the constructed geo-electrical cross sections for deep and large-scale geological surveys; and (c) the structural modeling of geological units and faults distribution contributes to clarify hydrogeological settings and aquifers connectivity. The approach can be readily applied elsewhere, as long as detailed structural analysis, geometric parameters and high-resolution DCR resistivity data are available.

     

Stock structure and demographic history of the Indo-West Pacific mud crab Scylla serrata

The increasing exploitation of mangrove forests, without any sustainable planning, has been seriously compromising the survival of this ecosystem and of its exclusive resources. Scylla serrata is one of the most commercially exploited crabs inhabiting mangroves and estuaries of the Indo-Pacific region. This species is extensively harvested, mainly for selling to the tourist market, and, as a consequence, its populations are in constant decline. The aim of the present study was to assess the level of genetic exchange of S. serrata within the Western Indian Ocean (WIO), using a population genetic structure approach. To achieve this goal, we reconstructed the intra-specific geographic pattern of genetic variation by partial sequencing the mitochondrial DNA cytochrome oxidase subunit I, in samples from seven mangrove sites of the WIO. Our data set then encompassed all the sequences for the same genetic marker deposited in Genbank and corresponding to samples from South East Asia, Australia and some Pacific Islands: this allowed us to estimate the level of connectivity among S. serrata populations within its distribution area.     

Stormwater management network effectiveness and implications for urban watershed function: A critical review

Deleterious effects of urban stormwater are widely recognized. In several countries, regulations have been put into place to improve the conditions of receiving water bodies, but planning and engineering of stormwater control is typically carried out at smaller scales. Quantifying cumulative effectiveness of many stormwater control measures on a watershed scale is critical to understanding how small‐scale practices translate to urban river health. We review 100 empirical and modelling studies of stormwater management effectiveness at the watershed scale in diverse physiographic settings. Effects of networks with stormwater control measures (SCMs) that promote infiltration and harvest have been more intensively studied than have detention‐based SCM networks. Studies of peak flows and flow volumes are common, whereas baseflow, groundwater recharge, and evapotranspiration have received comparatively little attention. Export of nutrients and suspended sediments have been the primary water quality focus in the United States, whereas metals, particularly those associated with sediments, have received greater attention in Europe and Australia. Often, quantifying cumulative effects of stormwater management is complicated by needing to separate its signal from the signal of urbanization itself, innate watershed characteristics that lead to a range of hydrologic and water quality responses, and the varying functions of multiple types of SCMs. Biases in geographic distribution of study areas, and size and impervious surface cover of watersheds studied also limit our understanding of responses. We propose hysteretic trajectories for how watershed function responds to increasing imperviousness and stormwater management. Even where impervious area is treated with SCMs, watershed function may not be restored to its predevelopment condition because of the lack of treatment of all stormwater generated from impervious surfaces; non‐additive effects of individual SCMs; and persistence of urban effects beyond impervious surfaces. In most cases, pollutant load decreases largely result from run‐off reductions rather than lowered solute or particulate concentrations. Understanding interactions between natural and built landscapes, including stormwater management strategies, is critical for successfully managing detrimental impacts of stormwater at the watershed scale.     

Biogeochemical effects of disturbance in shallow water sediment by macroalgae harvesting boats

In the shallow water of Orbetello lagoon, macroalgae harvesting boats produce sediment disturbance. To evaluate the effect of this, during 2001-2002, a trial study was carried out in the lagoon in order to: verify seasonal and diurnal trends in nutrients and estimate the quantity of resuspended organic sediment. An unbalanced and balanced ANOVA (one and two way) analysis was applied. The disturbance did not produce strong and lasting eutrophication effects. In the seasonal survey, dissolved inorganic nitrogen (DIN) and soluble reactive phosphorus (SRP) showed significant decreases in disturbed areas at the end of the trial, while the control area showed a constant, significant increase. Dissolved organic nitrogen (DON) and phosphorus (DOP) significantly increased everywhere. In disturbed areas, sediment redox (Eh((NHE))) increased and porosity values decreased, contrary to the control area. Total organic carbon (TOC) remained unchanged in disturbed areas, but increased in the control area, where the C:P ration increased. The fall-out of sedimentary material resuspended by boat action for as far as 50 m from the boat route, was 189 g(dw)m(-2) made up mainly of organic matter. This disturbance could be the cause of change in vegetation in the lagoon.     

Three Decades of Seismic Activity at Mt. Vesuvius: 1972–2000

We analyse the seismic catalogue of the local earthquakes which occurred at Somma-Vesuvius volcano in the past three decades (1972–2000). The seismicity in this period can be described as composed of a background level, characterised by a low and rather uniform rate of energy release and by sporadic periods of increased seismic activity. Such relatively intense seismicity periods are characterised by energy rates and magnitudes progressively increasing in the critical periods. The analysis of the b value in the whole period evidences a well-defined pattern, with values of b progressively decreasing, from about 1.8 at the beginning of the considered period, to about 1.0 at present. This steady variation indicates an increasing dynamics in the volcanic system. Within this general trend it is possible to identify a substructure in the time sequence of the seismic events, formed by the alternating episodes of quiescence and activity. The analysis of the source moment tensor of the largest earthquakes shows that the processes at the seismic source are generally not consistent with simple double-couples, but that they are compatible with isotropic components, mostly indicating volumetric expansion. These components are shown to be statistically significant for most of the analysed events. Such focal mechanisms can be interpreted as the effect of explosion phenomena, possibly related to volatile exsolution from the crystallising magma. The availability of a reduced amount of high quality data necessary for the inversion of the source moment tensor, the still limited period of systematic observation of Vesuvius micro-earthquakes and, above all, the absence of eruptive events during such interval of time, cannot obviously permit the outlining of any formal premonitory signal. Nevertheless, the analysis reported in this paper indicates a progressively evolving dynamics, characterised by a generally increasing trend in the seismic activity in the volcanic system and by a significant volumetric component of recent major events, thus posing serious concern for a future evolution towards eruptive activity.     

Antioxidant efficiency and detoxification enzymes in spotted dogfish Scyliorhinus canicula

Although elasmobranchs are widely distributed species, commonly found on sandy, gravely or muddy bottoms, several biological aspects of their metabolism still remain poorly investigated. In this work the efficiency of antioxidant system and detoxification enzymes were investigated in the coastal spotted dogfish Scyliorhinus canicula and in the red mullet Mullus barbatus for comparison with a teleost species.Organisms were sampled during a bottom trawl survey and analyzed for the biotransformation activity (EROD), levels of metallothioneins, catalase, glutathione S-transferases and total oxyradical scavenging capacity (TOSC) toward peroxyl radicals and hydroxyl radicals.EROD activity in the elasmobranchs was more than one order of magnitude lower than in the red mullets, while similar levels of metallothioneins were measured in these species. S. canicula showed significantly lower antioxidant enzymes and a more reduced efficiency in neutralizing ^√OH; on the other hand the scavenging capability toward ROO^√ was comparable in S. canicula and M. barbatus.     

Social and Geographic Contexts of Water Concerns in Utah

Public concerns about water issues are key considerations in responding to changing hydrologic conditions. Literature is mixed on the social profiles associated with resource-related risks. Using data from a household survey, we compare concerns about water shortage, climate change impacts on water supply, poor water quality, and flooding. We assess the combined influence of social and locational factors on each concern and variations across three valleys in northern Utah. Generalized linear mixed modeling is used, given the ordinal nature of most variables. Water shortage was the greatest concern, and female, older, nonwhite, and recreationally active respondents were generally more concerned about water issues than their counterparts. Education, income, and religious identity presented more complicated relationships with water concerns, with significant interaction effects with valley geography. This study has implications for improving public involvement in risk management and engendering support for future water policy and planning strategies to address these risks.