Determination of Trace Elements in Geological Reference Materials G‐3, GSP‐2 and SGD‐1a by Low‐Dilution Glass Bead Digestion and ICP‐MS

We present a revised alkali fusion method for the determination of trace elements in geological samples. Our procedure is based on simple acid digestion of powdered low‐dilution (flux : sample ≈ 2 : 1) glass beads where large sample dilution demanded by high total dissolved solids, a main drawback of conventional alkali fusion, could be circumvented. Three geological reference materials (G‐3 granite, GSP‐2 granodiorite and SGD‐1a gabbro) decomposed by this technique and routine tabletop acid digestion were analysed for thirty trace elements using a quadrupole ICP‐MS. Results by conventional acid digestion distinctly showed poor recoveries of Zr, Hf and rare earth elements due to incomplete dissolution of resistant minerals. On the other hand, results obtained by our method were in reasonable agreement with reference data for most analytes, indicating that refractory minerals were efficiently dissolved and volatile loss was insignificant.     

On the periodicity hypothesis of the ages of large impact craters

An analysis is made of the periodicity hypothesis of the ages of large craters, based on the compilation by Grieve with the addition of recently identified craters. A method earlier proposed by Broadbent is used to derive a period, and the significance of the derived period is tested by a Monte Carlo experiment. In accordance with the result of Stothers, the ages of large craters  ( D >30 km)  are shown to exhibit a period close to 37.5 Myr. Monte Carlo experiments show, however, that the derived period is far from being statistically significant. A subset of crater data earlier adopted by Napier for the purpose of similar investigation is also tested, and it is shown that they also exhibit a similar period at an almost identical level of confidence. A brief discussion is made of the relation between the derived period and that associated with faunal mass extinctions.     

Numerical simulations of heavy rainfall over central Korea on 21 September 2010 using the WRF model

On 21 September 2010, heavy rainfall with a local maximum of 259 mm d-1occurred near Seoul, South Korea. We examined the ability of the Weather Research and Forecasting(WRF) model in reproducing this disastrous rainfall event and identified the role of two physical processes: planetary boundary layer(PBL) and microphysics(MPS) processes. The WRF model was forced by 6-hourly National Centers for Environmental Prediction(NCEP) Final analysis(FNL) data for 36 hours form 1200 UTC 20 to 0000 UTC 22 September 2010. Twenty-five experiments were performed, consisting of five different PBL schemes—Yonsei University(YSU), Mellor-Yamada-Janjic(MYJ), Quasi Normal Scale Elimination(QNSE),Bougeault and Lacarrere(Bou Lac), and University of Washington(UW)—and five different MPS schemes—WRF SingleMoment 6-class(WSM6), Goddard, Thompson, Milbrandt 2-moments, and Morrison 2-moments. As expected, there was a specific combination of MPS and PBL schemes that showed good skill in forecasting the precipitation. However, there was no specific PBL or MPS scheme that outperformed the others in all aspects. The experiments with the UW PBL or Thompson MPS scheme showed a relatively small amount of precipitation. Analyses form the sensitivity experiments confirmed that the spatial distribution of the simulated precipitation was dominated by the PBL processes, whereas the MPS processes determined the amount of rainfall. It was also found that the temporal evolution of the precipitation was influenced more by the PBL processes than by the MPS processes.     

The Effect of the CCD Gate Structure in the Determination of the Undersampled Point Spread Function

Using numerical simulations, we evaluated the gate structure effect of the front-illuminated (FI) charge-coupled device (CCD) on determining the point spread function (PSF) from the analysis of undersampled experimental data. The PSF of the Soft X-ray Telescope onboard Yohkoh was studied as a model case. Its full-width at half-maximum is about one pixel size, and the FI CCD was equipped in the telescope as a detector. Of the three emission lines used during the pre-launch experiment, the data from the lowest-energy line (carbon K-line, 0.28 keV) were significantly influenced by the gate structure. The results from previous studies regarding the analysis of pre-launch data were examined and compared with the results from our simulation, and the expected error ranges of the gate structure effect are discussed. We found that the error caused by the effect of the gate structure is significant; at an energy of 0.28 keV, the error may lead to a too sharp PSF by about a few tens of percent.     

Using multiple‐variable indicator kriging to assess groundwater quality for irrigation in the aquifers of the Choushui River alluvial fan

This work attempted to locate clean and safe groundwater for irrigation use in the Choushui River alluvial fan. Multiple‐variable indicator kriging (MVIK) was adopted to evaluate numerous hydrochemical parameters for a standard of water quality for irrigation in Taiwan. Many hydrochemical parameters in groundwater were distinguished into three main categories—salinity/sodium hazard, nitrogen hazard and heavy metal hazard. Safe and potential hazardous regions of groundwater for irrigation were delineated according to different probabilities estimated by MVIK. The probabilistic results of the classifications gave an opportunity to explore the spatial uncertainty of the hazards and helped government administrators establish a sound policy associated with the development and management of groundwater resources. Analysis of the results indicate that the central distal‐fan and mid‐fan aquifers are the best places to extract clean and safe groundwater for irrigation, and the deep aquifer (exceeding 200 m depth) has wider regions with clean and safe groundwater for irrigation than shallow aquifers. The northern and southern aquifers, with multiple hazards, limit groundwater use for irrigation. Although the proximal‐fan aquifer is a zone of groundwater recharge, the high nitrogen content seriously affects the environment and is not suitable for irrigation use. Copyright © 2008 John Wiley & Sons, Ltd.     

On computation of strain‐dependent permeability of rocks and rock‐like porous media

Determination of transport properties of geomaterials is an important issue in many fields of engineering analysis and design. For example, in petroleum engineering, in situ permeability of an oil reservoir may be crucial in establishing its viability for exploitation, whilst prevention of leakage from underground storage facilities for oil and gas, nuclear waste as well as viability of CO₂ sequestration projects crucially depends on its long‐term values. Permeability is indirectly related to the porosity, pore‐size distribution and pore architecture of the porous media. These parameters evolve when a strain field is imposed. Physical measurement of permeability under a strain field in laboratory conditions is difficult, expensive and prone to a number of uncertainties. In the past, pore network models have been used to compute permeability of materials under stress/strain‐free conditions. In this paper, we propose an enhanced pore network model to compute permeability of rocks and rock‐like porous media under a stress/strain field. Data of pore‐size distribution obtained from mercury intrusion porosimetry are used to compute permeability of rock samples from various unspecified oilfields in the world. It is shown that the two permeabilities can be predicted from the model with sufficient accuracy. A hypothesis for change in porosity, pore‐size distribution and pore architecture as a result of imposed mechanical strains is then proposed. Based on this, permeability is computed again for one of the rock samples under uniaxial and triaxial compressive and tensile strain fields. It is shown that depending on the state of strain field imposed, permeability evolves in an anisotropic manner. Permeability under tensile strain field increases dramatically compared with the reduction that takes place under compressive strain field of the same magnitude. Copyright © 2014 John Wiley & Sons, Ltd.     

Property-based redevelopment and gentrification: The case of Seoul, South Korea

The urban experiences of South Korea in times of its rapid urbanisation and economic growth show that wholesale redevelopment had been a dominant approach to urban renewal, leading to redevelopment-induced gentrification. This was led by a programme known as the Joint Redevelopment Programme, transforming urban space that was once dominated by informal settlements into high-rise commercial housing estates. This paper tries to explain how this approach was possible at city-wide scale in its capital city, Seoul. Through the examination of redevelopment processes in a case study neighbourhood, it puts forward three arguments. First, the development potential arising from the rent gap expansion through under-utilisation of dilapidated neighbourhoods provided material conditions for the sustained implementation of property-based redevelopment projects. Second, this paper critically examines the dynamics of socio-political relations among various property-based interests embedded in redevelopment neighbourhoods, and argues that external property-based interests have enabled the full exploitation of development opportunities at the expense of poor owner-occupiers and tenants. Third, South Korea had been noted for its strong developmental state with minimum attention to redistributive social policies. The Joint Redevelopment Programme in Seoul was effectively a market-oriented, profit-led renewal approach, in line with a national housing strategy that favoured increased housing production and home-ownership at the expense of local poor residents’ housing needs.     

Sources of dissolved ions revealed by chemical and isotopic tracers in the Geum River,South Korea

Water samples were collected in the main channel of the Geum River, South Korea, and measured dissolved elemental concentrations and isotopic compositions of nitrate in order to identify the factors controlling water chemistry. Elemental concentrations significantly increased location-wise after the confluence from urban areas, indicating the changes in solute sources from chemical weathering to anthropogenic inputs such as manure, fertilizers, and sewage. In particular, the effect of sewage input is manifested in the concentrations of Cl^?, SO₄ ^2?, and Na⁺, while the NO₃ ^? concentration is influenced mainly by soil inputs with minor contributions from manure and fertilizer because both δ¹⁵N–NO₃ and δ¹⁸O–NO₃ indicate NO₃ ^? mostly consists of soil-derived nitrates in the upper reaches but manure/sewage nitrates in the lower reaches. The relative proportion of three factors, Cl^?, Ca²⁺+Mg²⁺, and NO₃ ^?, indicates that water chemistry in the upstream is controlled by the soil weathering but that in the downstream by the sewage. Seasonally, water chemistry during summer is dominated by the soil weathering due to the flushing effect but that during winter by the sewage. This study suggests that the relative proportion of three factors can be used for tracing natural and anthropogenic sources in water chemistry.     

Implementation of turbulent mixing over a stratocumulus-topped boundary layer and its impact in a GCM

The effect of a vertical diffusion scheme over a stratocumulus topped boundary layer (STBL) was investigated using the YONU AGCM (Yonsei University Atmospheric General Circulation Model). To consider the impact of clouds on the turbulence production, the turbulence mixing term, driven by radiative cooling at the cloud top, is implemented as an extended non-local diffiusion scheme. In the model with this new scheme, the STBL parameterization significantly influences the lower atmosphere over the tropical and...     

Component and shaking table tests for full‐scale multiple friction pendulum system

The use of base isolation in developed countries including the U.S. and Japan has already been recognized as a very effective method for upgrading the seismic resistance of structures. In this study, an advanced base‐isolation system called the multiple friction pendulum system (MFPS) is investigated to understand its performance on seismic mitigation through full‐scale component and shaking table tests. The component tests of the advanced Teflon composite coated on the sliding surface show that the friction coefficient of the lubricant material is a function of the sliding velocity in the range of 0.03–0.12. The experimental results also indicate that there were no signs of degradation of the sliding interface observed after 2000 cycles of sliding displacements. A full‐scale MFPS isolator under a vertically compressive load of 8830 KN (900 tf) and horizontally cyclic displacements was tested in order to assess the feasibility of the MFPS isolator for its practical use. After 248 cycles of horizontal displacement reversals, the behaviour of the base isolator was almost identical to its behaviour during the first few cycles. The experimental results of the shaking table tests of a full‐scale steel structure isolated with MFPS isolators show that the MFPS device can isolate seismic transmitted energy effectively under soft‐soil‐deposit site earthquakes with long predominant periods as well as strong ground motions with short predominant periods. These test results demonstrate that the MFPS isolator possesses excellent durability and outstanding earthquake‐proof capability. Furthermore, the numerical results show that the mathematical model proposed in this study can well predict the seismic responses of a structure isolated with MFPS isolators. Copyright © 2006 John Wiley & Sons, Ltd.