Effects of natural and calcined poultry waste on Cd, Pb and As mobility in contaminated soil

The reuse of waste materials as soil additives could be a welcome development in soil remediation. The mobility of Cd, Pb and As in a contaminated soil was investigated using natural and calcined poultry wastes (eggshell and chicken bone), CaCO₃ and CaO at different application rates (0, 1, 3 and 5 %). The chemical composition accompanied with mineralogical composition indicated that CaCO₃ and CaO were the major components in natural and calcined eggshells, respectively, while hydroxyapatite (HAP) dominated the natural and calcined chicken bones. The results showed that soil pH tended to increase in response to increasing application rates of all soil additives. The effectiveness of the additives in reducing Cd, Pb and As mobility was assessed by means of chemical extractions with 0.1 N HCl for Cd and Pb or 1 N HCl for As, according to Korean Standard Test (KST) method. Both calcined eggshell and chicken bone were equally effective with CaO or CaCO₃ in reducing the concentration of 0.1 N HCl-extractable Cd from 6.17 mg kg^?1 to below warning level of 1.5 mg kg^?1, especially at the highest application rate. The application of calcined eggshell, CaO and CaCO₃ also decreased the concentration of 0.1 N HCl-extractable Pb from 1,012 mg kg^?1 to below warning level of 100 mg kg^?1. The Pb concentration decreased significantly with an increasing application rate of chicken bone, but remained above warning level even at the highest application rate. On the contrary, natural and calcined chicken bones led to a significant increase in the mobility of As when compared with the control soil. These findings illustrate that calcined eggshell in particular is equally effective as pure chemical additives in stabilizing Cd and Pb in a contaminated agricultural soil. The presence of As in metal-contaminated soils should be taken into consideration when applying phosphate-containing materials as soil additives, because phosphate can compete with arsenate on adsorption sites and result in As mobilization.     

新疆库车地区秋里塔格构造带成因分析

秋里塔格构造带位于库车前陆逆冲带前锋,区域构造位置介于库车坳陷三叠-侏罗系烃源岩生排烃中心与塔北前缘隆起带之间,第三系广泛分布两套膏盐岩层,发育多套储盖组合和复杂的构造样式,石油地质条件非常优越.本文在分析3个区带的变形特征基础上,探讨了盐上层和盐下层的构造成因,认为盐上层的构造成因与盐层的流动性有关,西段变形比东段强烈;盐下层构造成因东、西差异较大,东段与盐层的塑性变形无关,西段则受其影响.     

小尺度地形引起的切变重力波

在大气边界层中,特别是山区的边界层中,经常可以观测到重力波的活动。例如Bull和Neisser分析了1974年4月至7月的2300时的微气压计记录。他们发现约38％的观测时间里都存在振幅至少为10—20 dPa的重力波活动,其中大多数重力波的振幅为25—70 dPa。由于风速切变和温度层结的不同,重力波引起的垂直位移的大小可能为百米,也可能达到整个夜间边界层厚度的量级。 很多大气活动都可能引起重力波,例如锋面、低空急流、局地风切变、逆温及强对流等等。地形特别是在夜间也是产生重力波的重要来源。当稳定度随高度急剧减少或风速随高度急剧增加时,在山脊的背风坡经常可以发现一系列的波动活动。     

长白山火山喷发物的堆积类型及火山活动机理

本文对长白山火山地质发展过程中的两大喷发期和七个喷发阶段作了系统阐述,详细划分、描述了喷发物堆积类型及特征,论述了火山活动机理及演化历程。首次指出长白山火山基浪堆积,对新发现的侵入相和次火山岩相岩百与喷出相岩石做了对比,指出同源于一个碱性岩浆房。     

准噶尔盆地玛湖凹陷西斜坡三叠系百口泉组扇三角洲优质储集层预测

针对准噶尔盆地玛湖凹陷西斜坡风南地区三叠系百口泉组扇三角洲砂岩物性空间变化大、优质储集层(孔隙度大于7.4%,渗透率大于0.05×10^-3μm²)预测难的问题,在沉积岩石学、地震沉积学以及地震反演和解释理论指导下,综合利用测井、岩心和三维地震等资料开展了高精度层序地层划分、沉积微相描述和优质储集层地震反演研究。建立了风南井区四级层序地层格架,明确了扇三角洲多期水进水退的充填过程,指出SSQ3和SSQ5是优质储集层的发育层系;识别出扇三角洲平原分流河道、河道间和扇三角洲前缘水下分流水道、河口坝、席状砂等沉积微相,指出扇三角洲平原是优质储集层发育相带;通过应用高分辨层序地层纵向边界和沉积相横向边界约束,进行分层相控叠后地震波阻抗反演,提升储集层预测精度,在SSQ3和SSQ5预测5个优质储集层发育区,提出3口井的井位建议,钻探均获工业油流。     

宁夏冬季负积温变化特征

对宁夏20个测站1961—2004年的冬季负积温EOF分析表明,冬季的冷趋势具有明显的大尺度特征,在近40 a逐渐变暖。据累积距平显示,l986年出现了突变,之前,冬季气温偏低,具体表现为冷冬年全部分布在此时段,之后偏暖,90年代以后出现暖冬的频次明显增加。≤0℃持续日数具有明显的年代际变化,2001—2004年比60年代平均减少了13.5 d。在80%保证率下,全区≤0℃持续日数和负积温依地势自北向南增多,引黄灌区最少,中部干旱带次之,南部黄土丘陵区相对最多。     

哀牢山-红河构造带古新世以来多期活动的构造和年代学证据

哀牢山—红河构造带哀牢山段可划分为东部高级变质带和西部低级变质带。构造分析表明:该构造带由3个不同变形域组成,可能代表其经历的3期左行走滑。第1期走滑发生在整个高级变质带,为拉张性左行走滑,形成角闪岩相L型构造岩。第2期走滑形成高级变质带中的高应变带,变形体制接近简单剪切,形成绿片岩相L-S型糜棱岩。第3期主要发生在低级变质带,为挤压性走滑,形成左行逆冲构造格局,并形成低绿片岩相千糜岩。地质年代学数据证明,3期左行走滑的形成时代分别是:距今58~56Ma、27~22Ma和13~12Ma±。哀牢山—红河构造带第1期左行走滑可能对应于印度与欧亚大陆距今60Ma左右的初始碰撞;第2期变形与青藏高原最强的挤压隆升期一致;第3期事件可能代表距今16~13Ma开始的青藏高原物质进一步东挤。哀牢山—红河构造带的3期主要左行走滑均发生在新生代印度与欧亚大陆的汇聚过程中。     

不稳定边界层下地形重力内波

水槽实验及线性理论研究表明,当低层大气处于近中性或不稳定时,如果地形引起的动力扰动足够强,地形扰动可在上部稳定层结中激发出重力内波,波动反过来影响低层流场,引起动量输送。低层大气处于近中性或不稳定时,地形波同样对大气运动可产生波阻,这应引起模式工作者的重视。最后讨论了大气粘性对中性或不稳定层结下地形波的影响。     

A Laboratory Model for the Flow in Urban Street Canyons Induced by Bottom Heating

Water tank experiments are carried out to investigate the convection flow induced by bottom heating and the effects of the ambient wind on the flow in non-symmetrical urban street canyons based on the PIV (Particle Image Visualization) technique. Fluid experiments show that with calm ambient wind,the flows in the street canyon are completely driven by thermal force, and the convection can reach the upper atmosphere of the street canyon. Horizontal and vertical motions also appear above the roofs of the buildings. These are the conditions which favor the exchange of momentum and air mass between the street canyon and its environment. More than two vortices are induced by the convection, and the complex circulation pattern will vary with time in a wider street canyon. However， in a narrow street canyon， just one vortex appears. With a light ambient wind, the bottom heating and the associated convection result in just one main vortex. As the ambient wind speed increases, the vortex becomes more organized and its center shifts closer to the leeward building.     

北京及周边地区雷暴阵风锋特征统计分析

为全面和系统研究北京及周边地区阵风锋各方面特征,使用2006—2015年暖季（5—9月）北京多普勒雷达探测资料及北京、河北、天津自动气象站观测资料对北京及周边地区的阵风锋过程进行综合统计分析。结果表明,346次阵风锋过程有232次触发了对流,占总数的67%,表明阵风锋对雷暴具有较强的抬升触发能力。阵风锋在6—8月出现的日数占5—9月阵风锋总日数的85%;出现的时段主要是午后至傍晚（12—21时,北京时）,维持时间0.5—3 h;阵风锋在北京东南方向生成的数量最多,且触发对流的次数也最多;其次为偏东和东北方向;偏南和西南方向生成阵风锋数量居中,而偏北、偏西和西北地区阵风锋个例相对较少,触发对流的比例也相对较低。产生阵风锋的母风暴中48%为孤立雷暴（包括孤立多单体和超级单体风暴）,31%为雷暴群,21%为飑线;97%的母风暴最强回波在50 dBz以上,阵风锋的回波强度为10—25 dBz。91%的阵风锋移动速度集中在10—60 km/h,84%的阵风锋与母风暴的最大距离为1—60 km;在母风暴回波强度减弱到30 dBz以下时,80%的阵风锋能够继续维持的时间不超过2 h。阵风锋母风暴向东南方向移动的个例最多,从阵风锋和母风暴移动方向的关系来看,阵风锋与母风暴移向一致的情况占比最高,为32%,其次为母风暴无移动及阵风锋弧形扩散情况,各占17%;阵风锋与母风暴移向相反情况所占比例最低,只有3%。最后统计了阵风锋经过地面自动气象站时,自动观测量的变化情况。结果显示,阵风锋在经过地面自动气象站时会造成风速增大、温度降低、相对湿度增大、气压升高。