Palaeoenvironmental significance of Late Permian palaeosols in the South‐Eastern Iberian Ranges,Spain

The Late Permian (Wuchiapingian) Alcotas Formation in the SE Iberian Ranges consists of one red alluvial succession where abundant soil profiles developed. Detailed petrographical and sedimentological studies in seven sections of the Alcotas Formation allow six different types of palaeosols, with distinctive characteristics and different palaeogeographical distribution, to be distinguished throughout the South‐eastern Iberian Basin. These characteristics are, in turn, related to topographic, climatic and tectonic controls. The vertical distribution of the palaeosols is used to differentiate the formation in three parts from bottom to top showing both drastic and gradual vertical upwards palaeoenvironmental changes in the sections. Reconstruction of palaeoenvironmental conditions based on palaeosols provides evidence for understanding the events that occurred during the Late Permian, some few millions of years before the well‐known Permian‐Triassic global crisis.     

Microbial activity and chemical weathering in the Middendorf aquifer,South Carolina

We use reactive transport modeling to better understand the kinetics of chemical weathering in the Cretaceous Middendorf aquifer of South Carolina, USA, and the relationship of this process to subsurface microbial activity. We constructed a model accounting for the kinetics of mineral dissolution and precipitation, ion exchange, and the CO₂ and bicarbonate produced by iron reducing and sulfate reducing bacteria in the aquifer. We then fit the model to observed trends in the chemical composition of groundwater along the aquifer by adjusting the rate constants for the kinetic reactions considered. The modeling portrays weathering in the Middendorf as a slow process by which groundwater gradually reacts toward equilibrium with minerals in the aquifer. The rate constants predicted are 6 to 7 orders of magnitude smaller than measured in laboratory experiments and 3 to 4 orders of magnitude less than those inferred from weathering rates in soils. The rate constants are smaller even than expected by projecting observed trends with the duration of weathering to the geologic age of the Middendorf. Weathering is driven largely by biological activity: about half the acid consumed is CO₂ derived from the recharge area, and about half is supplied by iron reducing bacteria in the aquifer; only about 1% of the acid is of atmospheric origin, from CO₂ dissolved in rainwater.     

Evaluating the use of 3'-(p-Aminophenyl) fluorescein for determining the formation of highly reactive oxygen species in particle suspensions

Background  

Given the importance of highly reactive oxygen species (hROS) as reactants in a wide range of biological, photochemical, and environmental systems there is an interest in detection and quantification of these species. The extreme reactivity of the hROS, which includes hydroxyl radicals, presents an analytical challenge. 3'-(p-Aminophenyl) fluorescein (APF) is a relatively new probe used for measuring hROS. Here, we further evaluate the use of APF as a method for the detection of hydroxyl radicals in particle suspensions.     

Soft X-ray diagnostics of the kinematics of high-velocity clouds

We have made near-infrared photometric observations of nine β-Cephei and eight δ-Scuti stars inJ, H, andK bands. The observed fluxes are in good agreement with those expected according to their spectral types. We conclude that these stars do not have any anomalous emission in these near-infrared bands.     

The influence of wind and river pulses on an estuarine turbidity maximum: Numerical studies and field observations in Chesapeake Bay

The effect of pulsed events on estuarine turbidity maxima (ETM) was investigated with the Princeton Ocean Model, a three-dimensional hydrodynamic model. The theoretical model was adapted to a straight-channel estuary and enhanced with sediment transport, erosion, deposition, and burial components. Wind and river pulse scenarios from the numerical model were compared to field observations before and after river pulse and wind events in upper Chesapeake Bay. Numerical studies and field observations demonstrated that the salt front and ETM had rapid and nonlinear responses to short-term pulses in river flow and wind. Although increases and decreases in river flow caused down-estuary and up-estuary (respectively) movements of the salt front, the effect of increased river flow was more pronounced than that of decreased river flow. Along-channel wind events also elicited non-linear responses. The salt front moved in the opposite direction of wind stress, shifting up-estuary in response to down-estuary winds and vice-versa. Modeled pulsed events affected suspended sediment distributions by modifying the location of the salt front, near-bottom shear stress, and the location of bottom sediment in relation to stratification within the salt front. Bottom sediment accumulated near the convergent zone at the tip of the salt front, but lagged behind the rapid response of the salt front during wind events. While increases in river flow and along-channel winds resulted in sediment transport down-estuary, only reductions in river flow resulted in consistent up-estuary movement of bottom sediment. Model predictions suggest that wind and river pulse events significantly influence salt front structure and circulation patterns, and have an important role in the transport of sediment in upper estuaries.     

Blowing in the wind. II. Creation and redistribution of refractory inclusions in a turbulent protoplanetary nebula

Ca-Al rich refractory mineral inclusions (CAIs) found at 1-6% mass fraction in primitive chondrites appear to be 1-3 million years older than the dominant (chondrule) components which were accreted into the same parent bodies. A prevalent concern is that it is difficult to retain CAIs for this long against gas-drag-induced radial drift into the Sun. We reassess the situation in terms of a hot inner (turbulent) nebula context for CAI formation, using analytical models of nebula evolution and particle diffusion. We show that outward radial diffusion in a weakly turbulent nebula can overcome inward drift, and prevent significant numbers of CAI-size particles from being lost into the Sun for times on the order of 10⁶ years. CAIs can form early, when the inner nebula was hot, and persist in sufficient abundance to be incorporated into primitive planetesimals at a much later time. Small (?0.1 mm diameter) CAIs persist for longer times than large (?5 mm diameter) ones. To obtain a quantitative match to the observed volume fractions of CAIs in chondrites, another process must be allowed for: a substantial enhancement of the inner hot nebula in silicate-forming material, which we suggest was caused by rapid inward drift of meter-sized objects. This early in nebula history, the drifting rubble would have a carbon content probably an order of magnitude larger than even the most primitive (CI) carbonaceous chondrites. Abundant carbon in the evaporating material would help keep the nebula oxygen fugacity low, plausibly solar, as inferred for the formation environment of CAIs. The associated production of a larger than canonical amount of CO₂ might also play a role in mass-independent fractionation of oxygen isotopes, leaving the gas rich in ¹⁶O as inferred from CAIs and other high temperature condensates.     

粉煤灰——漂珠复合低密度水泥浆固井试验与应用

针对吴起地区固井中一些低压地层由于破裂压力低,不能承受常规水泥浆液柱压力,出现固井水泥浆漏失、水泥返高达不到设计要求的问题,开展了低密度水泥浆体系研究。通过室内试验,对减轻材料粉煤灰、漂珠及二者复合体系进行了较系统的研究,确定了适合的配方。研究选用增稳剂ZW 加入低密度体系,提高了低密度水泥的强度。实验结果及现场实践表明: 用减轻材料配制低密度水泥浆及降低水泥浆液柱压力,是确保低压易漏地层固井水泥浆返高的有效途径,对提高固井质量和延长油井寿命都将起到积极作用。     

Reconsidering the physics of the Chesapeake Bay estuarine turbidity maximum

A series of cruises was carried out in the estuarine turbidity maximum (ETM) region of Chesapeake Bay in 1996 to examine physical and biological variability and dynamics. A large flood event in late January shifted the salinity structure of the upper Bay towards that of a salt wedge, but most of the massive sediment load delivered by the Susquehanna River appeared to bypass the ETM zone. In contrast, suspended sediments delivered during a flood event in late October were trapped very efficiently in the ETM. The difference in sediment trapping appeared to be due to increases in particle settling speed from January to October, suggesting that the fate of sediments delivered during large events may depend on the season in which they occur. The ETM roughly tracked the limit of salt (defined as the intersection of the 1 psu isohaline with the bottom) throughout the year, but it was often separated significantly from the limit of salt with the direction of separation unrelated to the phase of the tide. This was due to a lag of ETM sediment resuspension and transport behind rapid meteorologically induced or river flow induced motion of the salt limit. Examination of detailed time series of salt, suspended sediment, and velocity collected near the limit of salt, combined with other indications, led to the conclusion that the convergence of the estuarine circulation at the limit of salt is not the primary mechanism of particle trapping in the Chesapeake Bay ETM. This convergence and its associated salinity structure contribute to strong tidal asymmetries in sediment resuspension and transport that collect and maintain a resuspendable pool of rapidly settling particles near the salt limit. Without tidal resuspension and transport, the ETM would either not exist or be greatly weakened. In spite of this repeated resuspension, sedimentation is the ultimate fate of most terrigenous material delivered to the Chesapeake Bay ETM. Sedimentation rates in the ETM channel are at least an order of magnitude greater than on the adjacent shoals, probably due to focusing mechanisms that are poorly understood.     

The influence of episodic events on transport of striped bass eggs to the estuarine turbidity maximum nursery area

The estuarine turbidity maximum (ETM) is an important nursery area for anadromous fish where early-life stages can be retained in high prey concentrations and favorable salinities. Episodic freshwater flow and wind events could influence the transport of striped bass (Morone saxatilis) eggs to the ETM. This hypothesis was evaluated with regression analysis of observational data and with a coupled biological-physical model of a semi-idealized upper Chesapeake Bay driven by observed wind and freshwater flow. A particle-tracking model was constructed within a numerical circulation model (Princeton Ocean Model) to simulate the transport of fish eggs in a 3-dimensional flow field. Particles with the sinking speed of striped bass eggs were released up-estuary of the salt front in both 2-d event-scale and 60-d seasonal-scale scenarios. In event scenarios, egg-like particles with observed specific gravities (densities) of striped bass eggs were transported to the optimum ETM nursery area after 2 d, the striped bass egg-stage duration. Wind events and pulses in river discharge decreased the number of egg-like particles transported to the ETM area by 20.9% and 13.2%, respectively, compared to nonevent conditions. In seasonal scenarios, particle delivery to the ETM depended upon the timing of the release of egg-like particles. The number of particles transported to the ETM area decreased when particles were released before and during wind and river pulse events. Particle delivery to the ETM area was enhanced when the salt front was moving up-estuary after river pulse events and as base river flow receded over the spawning season. Model results suggest that the timing of striped bass spawning in relation to pulsed events may have a negative (before or during events) or positive (after river flow events) effect on egg transport. Spawning after river flow events may promote early-stage survival by taking advantage of improved transport, enhanced turbidity refuge, and elevated prey production that may occur after river pulse events. In multiple regression analysis of observed data, mean spring freshwater flow rates and the number of pulsed freshwater flow events during the striped bass spawning season explained 71% of the variability in striped bass juvenile abundance in upper Chesapeake Bay from 1986 to 2002. Positive parameter estimates for these effects support the hypothesis that pulsed freshwater flow events, coupled with spawning after the events, may enhance striped bass early-stage survival. Results suggest that episodic events may have an important role in controlling fish recruitment.