Modelling the influence of environmental factors on the physiological status of the Pacific oyster Crassostrea gigas in an estuarine embayment; The Baie des Veys (France)

It is well known that temporal changes in bivalve body mass are strongly correlated with temporal variations in water temperature and food supply. In order to study the influence of the year-to-year variability of environmental factors on oyster growth, we coupled a biogeochemical sub-model, which simulates trophic resources of oysters (i.e. phytoplankton biomass via chlorophyll a), and an ecophysiological sub-model, which simulates growth and reproduction (i.e. gametogenesis and spawning), using mechanistic bases. The biogeochemical sub-model successfully simulated phytoplankton dynamics using river nutrient inputs and meteorological factors as forcing functions. Adequate simulation of oyster growth dynamics requires a relevant food quantifier compatible with outputs of the biogeochemical sub-model (i.e. chlorophyll a concentration). We decided to use the phytoplankton carbon concentration as quantifier for food, as it is a better estimator of the energy really available to oysters. The transformation of chlorophyll a concentration into carbon concentration using a variable chlorophyll a to carbon ratio enabled us to improve the simulation of oyster growth especially during the starvation period (i.e. autumn and winter). Once validated, the coupled model was a suitable tool to study the influence of the year-to-year variability of phytoplankton dynamics and water temperature on the gonado-somatic growth of the Pacific oyster. Four years with highly contrasted meteorological conditions (river inputs, water temperature and light) 2000, 2001, 2002 and 2003, were simulated. The years were split into two groups, wet years (2000 and 2001) and dry years (2002 and 2003). Significant variability of the response of oysters to environmental conditions was highlighted between the four scenarios. In the wet years, an increase in loadings of river nutrients and suspended particulate matter led to a shift in the initiation and the magnitude of the phytoplanktonic spring bloom, and consequently to a shift in oyster growth patterns. In contrast, in the dry years, an increase in water temperature—especially during summer—resulted in early spawning. Thus, the gonado-somatic growth pattern of oysters was shown to be sensitive to variations in river loadings and water temperature. In this context, the physiological status of oysters is discussed using a relevant indicator of energy needs.     

Techniques for mode separation in Rayleigh wave testing

The spectral analysis of surface wave (SASW) developed in the early eighties has opened the way to the use of surface waves for the definition of shear wave velocity profiles in soil deposits or pavement structures without the need of any borings or intrusion. The SASW testing procedure was designed to minimize the contribution of higher modes and thus assumes that the Rayleigh waves which propagate at the surface belong only to the fundamental mode. Several studies have however demonstrated that, in some conditions, higher Rayleigh modes can contribute significantly to the dispersion curve. Different tests configurations exist today to deal with Rayleigh mode problem by the use of an array of receivers. In spite of that, the SASW configuration remains attractive due to the limited number of receivers, as well as, the Rayleigh modes contributing in SASW records configuration can be identified by multiple-filter technique and isolated using time-variable filters. The proposed techniques are first validated by simulated records and then applied to SASW records obtained in the field. The study confirms that higher modes can participate and even dominate in SASW records. An important contribution of higher Rayleigh modes can also exist, even if the shear wave velocity increases regularly with depth. The higher Rayleigh modes can significantly affect the accuracy of the shear wave velocity profile if they are not properly identified and separated. A multi-mode inversion process is shown to be important to have an accurate soil characterization.     

Archaeological reconstruction of medieval lead production: Implications for ancient metal provenance studies and paleopollution tracing by Pb isotopes

The identification of metal provenance is often based on chemical and Pb isotope analyses of materials from the operating chain, mainly ores and metallic artefacts. Such analyses, however, have their limits. Some studies are unable to trace metallic artefacts or ingots to their ore sources, even in well-constrained archaeological contexts. Possible reasons for this difficulty are to be found among a variety of limiting factors: (i) problems of ore signatures, (ii) mixing of different ores (alloys), (iii) the use of additives during the metallurgical process, (iv) metal recycling and (v) possible Pb isotopic fractionation during metal production. This paper focuses on the issue of Pb isotope fractionation during smelting to address the issue of metal provenance. Through an experimental reconstruction of argentiferous Pb production in the medieval period, an attempt was made to better understand and interpret the Pb isotopic composition of ore smelting products. It is shown that the measured differences (outside the total external uncertainties of 0.005 (2*sd) for ²⁰⁶Pb/²⁰⁴Pb ratios) in Pb signatures measured between ores, slag and smoke are not due to Pb mass fractionation processes, but to (1) ore heterogeneity (Δ²⁰⁶Pb/²⁰⁴Pb_slag-ores = 0.066) and (2) the use of additives during the metallurgical process (Δ²⁰⁶Pb/²⁰⁴Pb_slag-ores = 0.083). Even if these differences are due to causes (1) and/or (2), smoke from the ore reduction appears to reflect the ore mining area without a significant disturbance of its Pb signature for all the isotopic ratios (Δ²⁰⁶Pb/²⁰⁴Pb_smokes-ores = 0.026). Thus, because the isotopic heterogeneity of the mining district and additives is averaged in slags, slag appears as the most relevant product to identify ancient metal provenance. Whereas aiming at identifying a given mine seems beyond the possibilities provided by the method, searching for the mining district through analysis of the smelting workshop materials should provide a more appropriate approach in cases where no archaeological evidence of ancient mining is available. Furthermore, smoke Pb isotopic composition does not seem to be significantly affected by the metallurgical process. Paleopollution recorded in peat deposits could help to detect ancient mining production and workshops. Integrated collaboration between mining archaeologists and geochemists appears crucial to achieve this goal.     

The 3:2 spin-orbit resonant motion of Mercury

Our purpose is to build a model of rotation for a rigid Mercury, involving the planetary perturbations and the non-spherical shape of the planet. The approach is purely analytical, based on Hamiltonian formalism; we start with a first-order basic averaged resonant potential (including J ₂ and C ₂₂, and the first powers of the eccentricity and the inclination of Mercury). With this kernel model, we identify the present equilibrium of Mercury; we introduce local canonical variables, describing the motion around this 3:2 resonance. We perform a canonical untangling transformation, to generate three sets of action-angle variables, and identify the three basic frequencies associated to this motion. We show how to reintroduce the short-periodic terms, lost in the averaging process, thanks to the Lie generator; we also comment about the damping effects and the planetary perturbations. At any point of the development, we use the model SONYR to compare and check our calculations.     

Observations of the Solar Limb Shape Distortions

Two new campaigns devoted to the observation of the solar limb distortions were made at the Pic-du-Midi Observatory, in September 2000 and September 2001, by means of the scanning heliometer. This apparatus can be used now routinely to accurately determine solar limb profiles (at two wavelengths), at any heliographic latitudes. Each measurement is made within 44 milliseconds (of time) which permits to record a limb profile together with the seeing. Scans are automatically rejected for seeing larger than 1.3 arc sec. Such conditions are essential to perform high-quality observations necessary to obtain the quadrupole term (l=2) in the polynomial expansion of the radius contour R() _{= constant} = R ₀ left(1+_l c _l P _l()right). Exceptional meteorological conditions in September 2001 (seeing of the order of 18 cm, for a 50 cm clear aperture of the refractor) enabled us to determine c ₂ and c ₄ (see Table I) with an accuracy of a few milli-arc-sec. Results indicate a distorted solar shape, the departures from a pure spherical body not exceeding 20 milli-arc-sec. We propose a model to interpret such results (the combination of a nearly uniform rotating core with a prolate solar tachocline and an oblate surface), which is briefly discussed. Our results are confronted to those obtained from space. We conclude that measurements of the quadrupole term from the ground are possible, but of high difficulty and can be obtained only during excellent weather conditions. The hexadecapole term should be only obtained from space. We show that an astrometric satellite would be required, whose mission would be also to accurately determine the solar rotation profiles (both surface and in depth) in order to unambiguously determine the inertia moments of the Sun through the J _n terms. Such values are also briefly discussed.     

Vertical and meridional distribution of ethane, acetylene and propane in Saturn’s stratosphere from CIRS/Cassini limb observations

Measuring the spatial distribution of chemical compounds in Saturn’s stratosphere is critical to better understand the planet’s photochemistry and dynamics. Here we present an analysis of infrared spectra in the range 600-1400 cm⁻¹ acquired in limb geometry by the Cassini spacecraft between March 2005 and January 2008. We first determine the vertical temperature profiles from 3 to 0.01 hPa, at latitudes ranging from 70°N to 80°S. We infer a similar meridional temperature gradient at 1-2 hPa as in recent previous studies [Fletcher, L.N., Irwin, P.G.J., Teanby, N.A., Orton, G.S., Parrish, P.D., de Kok, R., Howett, C., Calcutt, S.B., Bowles, N., Taylor, F.W., 2007. Icarus 189, 457-478; Howett, C.J.A., Irwin, P.G.J., Teanby, N.A., Simon-Miller, A., Calcutt, S.B., Fletcher, L.N., de Kok, R., 2007. Icarus 190, 556-572]. We then retrieve the vertical profiles of C₂H₆ and C₂H₂ from 3 to 0.01 hPa and of C₃H₈ around 1 hPa. At 1 hPa, the meridional variation of C₂H₂ is found to follow the yearly averaged solar insolation, except for a strong equatorial mole fraction of 8×10^-7, nearly two times higher than expected. This enhancement in abundance can be explained by the descent of hydrocarbon-rich air, with a vertical wind speed at the equator of 0.25±0.1 mm/s at 1 hPa and 0.4±0.15 mm/s at 0.1 hPa. The ethane distribution is relatively uniform at 1 hPa, with only a moderate 25% increase from 35°S to 80°S. Propane is found to increase from north to south by a factor of 1.9, suggesting that its lifetime may be shorter than Saturn’s year at 1 hPa. At high altitudes (1 Pa), C₂H₂ and C₂H₆ abundances depart significantly from the photochemical model predictions of Moses and Greathouse [Moses, J.I., Greathouse, T.K., 2005. J. Geophys. Res. 110, 9007], except at high southern latitudes (62, 70 and 80°S) and near the equator. The observed abundances are found strongly depleted in the 20-40°S region and enhanced in the 20-30°N region, the latter coinciding with the ring’s shadow. We favor a dynamical explanation for these anomalies.     

Wind wave measurements and modelling in a fetch-limited semi-enclosed lagoon

The south-west reef lagoon of New Caledonia is a semi-enclosed basin where, on first approximation, dominating sea state component corresponds to locally generated wind waves. This study aims to evaluate the ability of the wave model WAVEWATCH III to simulate wind wave distribution in this particular fetch-limited context, with a given parameterisation. In order to evaluate the consistency of the simulation results, wave parameters were measured in situ by a wave and tide recorder (WTR9 Aanderaa) and by an acoustic Doppler velocimeter (ADV Sontek). This study underlines specific constrains for the deployment of instruments to assess the characteristic parameters of low amplitude and high frequency wind-waves. Special care was taken in the comparison step as, on one hand the wave model did not simulate the propagation of low-frequency oceanic waves inside the lagoon, and on the other hand the measured spectra bear an intrinsic limitation for high frequencies. The approximation of a sea state dominated by wind waves is verified on the study site. The accuracy of the simulation results is discussed with regards to the wind forcing applied to the model.     

A sandwiched denitrifying biocathode in a microbial fuel cell for electricity generation and waste minimization

A denitrifying biocathode in a microbial fuel cell was developed to investigate the replacement of the costly Pt-coated abiotic cathodes for electricity generation. The denitrifying biocathode was sandwiched between the dual-anode systems. The study investigated the performance for simultaneous treatment of wastewater on the anode, biological denitrification on the cathode and the potential recovery of electrical energy. Autotrophic biofilms performed denitrification on the cathode using supplied electrons by the biodegradation of organics on the anode. Graphite granules were used as electrodes for biofilm attachment, and nafion membranes were used as separators between electrodes. The system achieved a volumetric power of 7 ± 0.4 W m^?3 net cathodic compartment (NCC) with the simultaneous removal of 229.5 ± 18 mg L^?1 COD on anode and 88.9 g m^?3 NCC day^?1 nitrogen on cathode, respectively. The columbic efficiency for cathodic and anodic reactions was 98.9 ± 0.57 and 23.54 ± 0.87 %, respectively. This is a combined study for domestic wastewater treatment and biological denitrification in a compact MFC reactor. Further optimization of the system is desired to improve its performance and applicability.     

Preliminary study on the preservation of giant clam (Tridacnidae) shells from the Balobok Rockshelter archaeological site,south Philippines

Tridacnidae shells, a valuable archive of past environments, are common in the Balobok Rockshelter archaeological site on Sanga‐Sanga Island in the south Philippines. This site was occupied during the mid‐Holocene (ca. 5000–8800 ¹⁴C yr B.P.), a period of Neolithic cultural expansion in the Philippines. This paper focuses on the preservation of two shell specimens, Hippopus hippopus and Tridacna maxima, unearthed from two mid‐Holocene layers within the rockshelter. The shells' mineralogy and microstructure (prismatic and crossed‐lamellar) were studied using micro‐Fourier transform infrared spectroscopy and scanning electron microscopy to determine if the samples were suitable as paleoenvironmental records. Both shells are still aragonitic but aragonite crystals of both microstructure types are partly dissolved. This dissolution, characteristic of meteoric water alteration, precludes their utility in paleoenvironmental geochemical studies. Nevertheless, these shells are abundant in archaeological sites in the region and may be better preserved in other depositional contexts; more studies on Philippine Tridacnidae shell diagenesis are needed. © 2011 Wiley Periodicals, Inc.