Subsidence, extension and thermal history of the West African margin in Senegal

The subsidence of the Atlantic margin in Senegal clearly shows two rapid stages related to the formation of (1) the Central Atlantic during the early Jurassic (around 200 Ma), and (2) the Equatorial Atlantic during the Cretaceous (100 Ma). A simple model of extension is used to interpret the subsidence history and to derive the thermal evolution of this basin. The present-day gravity, bathymetry, bottom hole temperatures (BHT) in oil exploration boreholes and heat flow density are used to control the validity of the model. Two cross sections from the outcropping basement to oceanic crust are used, one in Casamance and the other one at the south to latitude of Dakar. The model can fully explain the first-order subsidence history as well as the present-day observations, and therefore can provide valuable information about the thermal evolution of sediments and about the structure of the continental crust along the margin. Comparisons with the opposite margin in North America (Blake Plateau and Carolina trough) indicate a rather different evolution (the North American margin did not undergo the second stage of rifting) and a different crustal structure (crustal thinning is less important on the African margin).     

Seasonal fluctuations in the deep central equatorial Atlantic Ocean: a data–model comparison

Low-frequency current fluctuations in the deep central equatorial Atlantic are analyzed using current meter measurements recorded from November 1992 to November 1994. Current meters were located at about 14°W of longitude and 1° of latitude on both sides of the equator between 1,700 m depth and the ocean bottom. At all sampling depths, the velocity fluctuations are dominantly zonal and symmetrical with respect to the equator. At 1,700 and 2,000 m, the flow is dominated by annual period fluctuations, at 3,000 m, the velocity field amplitude presents a minimum, and at 3,750 and 3,950 m, the flow is modulated by annual and semiannual period variability. The annual signal exhibits an apparent upward phase propagation. When considering the phase and the amplitude of the seasonal fluctuations, the data compare well with the outputs of a realistic numerical simulation of the Atlantic Ocean. Together with a previous analysis of the model simulations, this supports the idea that the observed annual fluctuations are due to wind-forced vertically propagating Kelvin and Rossby waves. Data and model do not provide deciding evidences of the presence of semiannual equatorial waves deeper than 3,500 m depth in the central equatorial Atlantic Ocean.     

Estimating Flow Using Tracers and Hydraulics in Synthetic Heterogeneous Aquifers

Regional ground water flow is most usually estimated using Darcy's law, with hydraulic conductivities estimated from pumping tests, but can also be estimated using ground water residence times derived from radioactive tracers. The two methods agree reasonably well in relatively homogeneous aquifers but it is not clear which is likely to produce more reliable estimates of ground water flow rates in heterogeneous systems. The aim of this paper is to compare bias and uncertainty of tracer and hydraulic approaches to assess ground water flow in heterogeneous aquifers. Synthetic two-dimensional aquifers with different levels of heterogeneity (correlation lengths, variances) are used to simulate ground water flow, pumping tests, and transport of radioactive tracers. Results show that bias and uncertainty of flow rates increase with the variance of the hydraulic conductivity for both methods. The bias resulting from the nonlinearity of the concentration–time relationship can be reduced by choosing a tracer with a decay rate similar to the mean ground water residence time. The bias on flow rates estimated from pumping tests is reduced when performing long duration tests. The uncertainty on ground water flow is minimized when the sampling volume is large compared to the correlation length. For tracers, the uncertainty is related to the ratio of correlation length to the distance between sampling wells. For pumping tests, it is related to the ratio of correlation length to the pumping test's radius of influence. In regional systems, it may be easier to minimize this ratio for tracers than for pumping tests.     

Frontal dynamics boost primary production in the summer stratified Mediterranean sea

Bio-physical glider measurements from a unique process-oriented experiment in the Eastern Alboran Sea (AlborEx) allowed us to observe the distribution of the deep chlorophyll maximum (DCM) across an intense density front, with a resolution (～ 400 m) suitable for investigating sub-mesoscale dynamics. This front, at the interface between Atlantic and Mediterranean waters, had a sharp density gradient (Δρ ～ 1 kg/m³ in ～ 10 km) and showed imprints of (sub-)mesoscale phenomena on tracer distributions. Specifically, the chlorophyll-a concentration within the DCM showed a disrupted pattern along isopycnal surfaces, with patches bearing a relationship to the stratification (buoyancy frequency) at depths between 30 and 60 m. In order to estimate the primary production (PP) rate within the chlorophyll patches observed at the sub-surface, we applied the Morel and Andrè (J Geophys Res 96:685–698 1991) bio-optical model using the photosynthetic active radiation (PAR) from Argo profiles collected simultaneously with glider data. The highest production was located concurrently with domed isopycnals on the fresh side of the front, suggestive that (sub-)mesoscale upwelling is carrying phytoplankton patches from less to more illuminated levels, with a contemporaneous delivering of nutrients. Integrated estimations of PP (1.3 g C m^?2d^?1) along the glider path are two to four times larger than the estimations obtained from satellite-based algorithms, i.e., derived from the 8-day composite fields extracted over the glider trip path. Despite the differences in spatial and temporal sampling between instruments, the differences in PP estimations are mainly due to the inability of the satellite to measure DCM patches responsible for the high production. The deepest (depth > 60 m) chlorophyll patches are almost unproductive and probably transported passively (subducted) from upper productive layers. Finally, the relationship between primary production and oxygen is also investigated. The logarithm of the primary production in the DCM interior (chlorophyll (Chl) > 0.5 mg/m³) shows a linear negative relationship with the apparent oxygen utilization, confirming that high chlorophyll patches are productive. The slope of this relationship is different for Atlantic, mixed interface waters and Mediterranean waters, suggesting the presence of differences in planktonic communities (whether physiological, population, or community level should be object of further investigation) on the different sides of the front. In addition, the ratio of optical backscatter to Chl is high within the intermediate (mixed) waters, which is suggestive of large phytoplankton cells, and lower within the core of the Atlantic and Mediterranean waters. These observations highlight the relevance of fronts in triggering primary production at DCM level and shaping the characteristic patchiness of the pelagic domain. This gains further relevance considering the inadequacy of optical satellite sensors to observe DCM concentrations at such fine scales.     

Comparative risk assessment of permethrin, chlorothalonil, and diuron to coastal aquatic species

The precise application of risk assessment can lead to different conclusions about risk depending on how species are grouped in the assessment. We compared the use of different risk assessment methods for three different classes of pesticide, the herbicide diuron, the fungicide chlorothalonil, and the insecticide permethrin for marine and estuarine species. Permethrin was the most toxic pesticide to marine and estuarine crustaceans. Diuron was the most toxic pesticide to algae, and chlorothalonil was most toxic to early life stages of molluscs and other invertebrates. Toxicity data (96 h LC50/EC50 values) were analyzed using a probability distribution on the ranked toxicity values and 10th centile values were calculated based on different groups of species and for all species combined. Our results indicate that an assessment of risk based on smaller taxonomic groups can be informative, especially for pesticides of less specific modes of action such as chlorothalonil.     

SCALES: a large‐scale assessment model of soil erosion hazard in Basse‐Normandie (northern‐western France)

The cartography of erosion risk is mainly based on the development of models, which evaluate in a qualitative and quantitative manner the physical reproduction of the erosion processes (CORINE, EHU, INRA). These models are mainly semi‐quantitative but can be physically based and spatially distributed (the Pan‐European Soil Erosion Risk Assessment, PESERA). They are characterized by their simplicity and their applicability potential at large temporal and spatial scales. In developing our model SCALES (Spatialisation d'éChelle fine de l'ALéa Erosion des Sols/large‐scale assessment and mapping model of soil erosion hazard), we had in mind several objectives: (1) to map soil erosion at a regional scale with the guarantee of a large accuracy on the local level, (2) to envisage an applicability of the model in European oceanic areas, (3) to focus the erosion hazard estimation on the level of source areas (on‐site erosion), which are the agricultural parcels, (4) to take into account the weight of the temporality of agricultural practices (land‐use concept). Because of these objectives, the nature of variables, which characterize the erosion factors and because of its structure, SCALES differs from other models. Tested in Basse‐Normandie (Calvados 5500 km²) SCALES reveals a strong predisposition of the study area to the soil erosion which should require to be expressed in a wet year. Apart from an internal validation, we tried an intermediate one by comparing our results with those from INRA and PESERA. It appeared that these models under estimate medium erosion levels and differ in the spatial localization of areas with the highest erosion risks. SCALES underlines here the limitations in the use of pedo‐transfer functions and the interpolation of input data with a low resolution. One must not forget however that these models are mainly focused on an interregional comparative approach. Therefore the comparison of SCALES data with those of the INRA and PESERA models cannot result on a convincing validation of our model. For the moment the validation is based on the opinion of local experts, who agree with the qualitative indications delivered by our cartography. An external validation of SCALES is foreseen, which will be based on a thorough inventory of erosion signals in areas with different hazard levels. Copyright © 2010 John Wiley & Sons, Ltd.     

Influence of Redox Mediators and Electron Donors on the Anaerobic Removal of Color and Chemical Oxygen Demand from Textile Effluent

Color removal was evaluated in anaerobic assays using synthetic (SE) and real (RE) effluents containing the dye Direct Black 22 (DB22). The focus was on the individual influence of two electron donors (EDs), sucrose and ethanol; and their combination with two redox mediators (RMs), lawsone and riboflavin. In addition to SE assays, the EDs were combined with sulfate which was present in the RE. Distinct behavior was observed with both assays. In the case of SE, using the EDs sucrose and ethanol resulted in DB22 removal efficiency of 93 and 83%, respectively; but only 27% in the control. The respective removal rates were 27.8‐ and 4.4‐fold higher than that of the control. Using the EDs with the RM lawsone resulted in color removal higher than that with riboflavin. Interestingly, in the ethanol + sulfate assay, late release of the last was observed, possibly due to the desulfonation reaction of the aromatic structures during the DB22 molecule breakdown. In the case of RE, no improvement was observed with either EDs; and some combinations with the RMs even resulted in decreased color removal. Therefore, the used EDs and RMs showed positive effect on color removal in SEs; but unexpectedly not in REs.     

Glacio-lacustrine stratigraphy,aquifer characterization and contaminant transport: a case study in South Lake Tahoe,California, USA

A hydrogeologic model that has been used by many researchers and consultants to describe an area of South Lake Tahoe, California, USA impacted by MTBE contamination describes a relatively homogeneous unconfined aquifer comprised of poorly sorted glacial outwash deposits, within which water-supply wells are able to exert significant alteration in natural groundwater flow. A re-examination of the area’s hydrogeology is presented, which supports a layered heterogeneous aquifer system constructed of alternating fine and coarser-grained glacio-lacustrine depositional units. This re-evaluation was accomplished through a review of lithologic logs across an area of approximately 1 km², combined with observations of significant hydraulic head differences and knowledge of the depositional environments controlled by Pleistocene Lake Tahoe high stands. Many of the fine-grained units observed at depths from 6 to 15 m, although relatively thin, are generally continuous and serve as significant barriers to groundwater flow. The vertical migration of contamination across these fine-grained units to deeper groundwaters was facilitated by cross-screened monitoring wells installed as part of site investigation activities. This conclusion highlights the importance of geologic characterization and proper monitoring well construction at contaminated site investigations.

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Catch Crop Known to Decrease N-leaching also Counteracts Soil CO2 Emissions

CO₂ emissions to the atmosphere were studied in a fertilized sandy agricultural soil with and without a catch crop sown into the main crop. The catch crop was grown primarily with the purpose to decrease N-leaching but this study also wanted to find out if the catch crop could have an effect in a climate change perspective. Plots with catch crop showed decreased CO₂ emissions from the soil. Since previous results have shown that catch crops effectively decrease N-leaching we recommend growing catch crops as an effective measure for helping both the climate and the eutrophication issue. Seasonal variations in CO₂ emissions were pronounced with maximum emissions from the fertilized agricultural soil in June and from an adjacent unmanaged grassland in August. From the plot with catch crop emissions decreased in July and August but somewhat increased later in the autumn. Fertilized agricultural soil showed a within-soil CO₂ sink after harvest, i.e. within-soil CO₂ uptake. Availability of NH₄⁺ or NO₃^- in the soil seems to influence the within-soil CO₂ sink, with NH₄⁺ enforcing the sink while the same amount of NO₃^- instead increased CO₂ emissions.