The recognition of multiple magmatic events and pre-existing deformation zones in metamorphic rocks as illustrated by CL signatures and numerical modelling: examples from the Ballachulish contact aureole, Scotland

The combination of cathodoluminescence (CL) analysis, temperature and temperature–time calculations, and microstructural numerical modelling offers the possibility to derive the time-resolved evolution of a metamorphic rock. This combination of techniques is applied to a natural laboratory, namely the Ballachulish contact aureole, Scotland. Analysis of the Appin Quartzite reveals that the aureole was produced by two distinct magmatic events and infiltrated by associated fluids. Developing microstructures allow us to divide the aureole into three distinct regions. Region A (0–400?m, 663°C?<?T _max?<?714°C) exhibits a three-stage grain boundary migration (GBM) evolution associated with heating, fluid I and fluid II. GBM in region B (400–700?m, 630°C?<?T _max?<?663°C) is associated with fluid II only. Region C (>700?m of contact, T _max?<?630°C) is characterised by healed intragranular cracks. The combination of CL signature analysis and numerical modelling enables us to recognise whether grain size increase occurred mainly by surface energy-driven grain growth (GG) or strain-induced grain boundary migration (SIGBM). GG and SIGBM result in either straight bands strongly associated with present-day boundaries or highly curved irregular bands that often fill entire grains, respectively. At a temperature of ~620°C, evidence for GBM is observed in the initially dry, largely undeformed quartzite samples. At this temperature, evidence for GG is sparse, whereas at ~663°C, CL signatures typical for GG are commonplace. The grain boundary network approached energy equilibrium in samples that were at least 5?ka above 620°C.     

Estuarine ecological risk based on hepatic histopathological indices from laboratory and in situ tested fish

Juvenile Senegalese soles were exposed through 28-day laboratory and field (in situ) bioassays to sediments from three sites of the Sado estuary (W Portugal): a reference and two contaminated by metallic and organic contaminants. Fish were surveyed for ten hepatic histopathological alterations divided by four distinct reaction patterns and integrated through the estimation of individual histopathological condition indices. Fish exposed to contaminated sediments sustained more damage, with especial respect to regressive changes like necrosis. However, differences were observed between laboratory- and field-exposed animals, with the latest, for instance, exhibiting more pronounced fatty degeneration and hepatocellular eosinophilic alteration. Also, some lesions in fish exposed to the reference sediment indicate that in both assays unaccounted variables produced experimental background noise, such as hyaline degeneration in laboratory-exposed fish. Still, the field assays yielded results that were found to better reflect the overall levels of contaminants and physico-chemical characteristics of the tested sediments.     

Forest–savanna–morichal dynamics in relation to fire and human occupation in the southern Gran Sabana (SE Venezuela) during the last millennia

The southern Gran Sabana (SE Venezuela) holds a particular type of neotropical savanna characterized by the local occurrence of morichales (Mauritia palm swamps), in a climate apparently more suitable for rain forests. We present a paleoecological analysis of the last millennia of Lake Chonita (4°39′N–61°0′W, 884 m elevation), based on biological and physico-chemical proxies. Savannas dominated the region during the last millennia, but a significant vegetation replacement occurred in recent times. The site was covered by a treeless savanna with nearby rainforests from 3640 to 2180 cal yr BP. Water levels were higher than today until about 2800 cal yr BP. Forests retreated since about 2180 cal yr BP onwards, likely influenced by a higher fire incidence that facilitated a dramatic expansion of morichales. The simultaneous appearance of charcoal particles and Mauritia pollen around 2000 cal yr BP supports the potential pyrophilous nature of this palm and the importance of fire for its recent expansion. The whole picture suggests human settlements similar to today – in which fire is an essential element – since around 2000 yr ago. Therefore, present-day southern Gran Sabana landscapes seem to have been the result of the synergy between biogeographical, climatic and anthropogenic factors, mostly fire.     

Water relations and hydraulic architecture of two Patagonian steppe shrubs: Effect of slope orientation and microclimate

On a local scale, topography influences microclimate, vegetation structure and the morpho-physiological attributes of plants. We studied the effects of microclimatic differences between NE- and SW-facing slopes on the water relations and hydraulic properties of two dominant shrubs of the Patagonian steppe in Argentina (Retanilla patagonica and Colliguaja integerrima). The NE-facing slope had higher irradiance and air saturation deficits and lower soil water availability and wind speed than the SW-facing slope. Predawn and midday Ψ_L and osmotic potentials were significantly lower in shrubs on the NE-facing slope. Osmotic adjustment and more elastic cell walls helped the plants to cope with a more xeric environment on NE-facing slope. Higher water deficits on NE-facing slope were partially compensated by a higher leaf and stem water storage. While stem hydraulic efficiency did not vary between slopes, leaf hydraulic conductance was between 40% and 300% higher on the NE-facing slope. Changes observed in leaf size and in SLA were consistent with responses to mechanical forces of wind (smaller and scleromorphic leaves on SW-facing slope). Morpho-physiological adjustments observed at a short spatial scale allow maintenance of midday Ψ_L above the turgor loss point and demonstrate that leaves are more responsive to microclimatic selective pressures than stems.     

Iron(II) oxide determination in rocks and minerals

The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H₃PO₄ mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.     

A hypoplastic macroelement formulation for single batter piles in sand

Batter piles are widely used in geotechnical engineering when substantial lateral resistance is needed or to avoid the interference with existing underground constructions. Nevertheless, there is a lack of fast numerical tools for nonlinear soil‐structure interactions problems for this type of foundation. A novel hypoplastic macroelement is proposed, able to reproduce the nonlinear response of a single batter pile in sand under monotonic and cyclic static loadings. The behavior of batter piles (15°, 30°, and 45°) is first numerically investigated using 3D finite element modeling and compared with the behavior of vertical piles. It is shown that their response mainly depends on the pile inclination and the loading direction. Then, starting from the macroelement for single vertical piles in sand by Li et al (Acta Geotechnica, 11(2):373‐390, 2016), an extension is proposed to take into account the pile inclination introducing simple analytical equations in the expression describing the failure surface. 3D finite element numerical models are adopted to validate the macroelement that is proven able to reproduce the nonlinear behavior in terms of global quantities (forces‐displacements) and to significantly reduce the necessary computational time.     

Storylines: an alternative approach to representing uncertainty in physical aspects of climate change

Investigating the relationships between climate extremes and crop yield can help us understand how unfavourable climatic conditions affect crop production. In this study, two statistical models, multiple linear regression and random forest, were used to identify rainfall extremes indices affecting wheat yield in three different regions of the New South Wales wheat belt. The results show that the random forest model explained 41–67% of the year-to-year yield variation, whereas the multiple linear regression model explained 34–58%. In the two models, 3-month timescale standardized precipitation index of Jun.–Aug. (SPI_JJA), Sep.–Nov. (SPI_SON), and consecutive dry days (CDDs) were identified as the three most important indices which can explain yield variability for most of the wheat belt. Our results indicated that the inter-annual variability of rainfall in winter and spring was largely responsible for wheat yield variation, and pre-growing season rainfall played a secondary role. Frequent shortages of rainfall posed a greater threat to crop growth than excessive rainfall in eastern Australia. We concluded that the comparison between multiple linear regression and machine learning algorithm proposed in the present study would be useful to provide robust prediction of yields and new insights of the effects of various rainfall extremes, when suitable climate and yield datasets are available.     

Elastic and visco-elastic stress triggering in the South Iceland Seismic Zone due to large earthquakes since 1706

Damaging earthquakes in the South Iceland Seismic Zone (SISZ) occur fairly regularly and often as a series of events with a few days only between individual events. Tolerably reliable information on epicentre locations and mechanisms are available for 13 M ≥ 6 events between 1706 and 2000. For these events, we computed the co- and post-seismic stress fields, hereby approximating the SISZ by a mixed elastic/visco-elastic layered half-space. The horizontal shear stress and the Coulomb stress changes were analysed to detect possible trigger mechanisms, which may aid future earthquake mitigation efforts. We tested several criteria but must conclude that the start of an earthquake series in the SISZ cannot be explained by triggering through previous events. Inside an individual series, however, one may infer triggering. Our results are in contradiction with the findings in other regions of the world. The reason might be related to the fact that the SISZ is not a mature fault zone, in which old faults are re-activated if a certain stress level threshold is passed. In addition, uncertainties in the model parameters as well as the neglect of horizontal variations in the model and of possible stress transfer due to volcanic activity further complicate the evaluation of our results and need to be taken into account in future studies.     

Channel avulsion and river metamorphosis: The case of the Thomson River,Victoria, Australia

Channel avulsion occurred on the Thomson River in Victoria, Australia, in 1952 along a 12 km length of the valley. A comparison of the old and new channels reveals considerable differences in channel characteristics. The old channel was perched above the floodplain on an alluvial ridge such that when bankfull capacity was exceeded, floodwaters concentrated on the lowest part of the floodplain some distance away. This is where the new channel formed. It is an incised channel with larger capacity and longer meander wavelength than the old channel and is also shorter and steeper. The new channel is subject to larger floodflows and a more variable flood regime than the old course because of the differences in the channel/floodplain relationship and channel capacity. The resulting concentration of stream power along the new course is responsible for the contrast in channel characteristics and for the more rapid meander migration. This example shows that river metamorphosis can occur without major environmental changes. Measures of channel geometry such as gradient, sinuosity, and meander wavelength therefore cannot be used in palaeohydrological work to infer climatic or other environmental changes without independent supporting evidence. Differences in channel geometry can arise simply from changes in the relationship between the channel and its loodplain.