Thermal decomposition of NH<Subscript>4</Subscript><Superscript>+</Superscript>-vermiculite from Santa Olalla (Huelva,Spain) and its relation to the metal ion distribution in the octahedral sheet

The investigation of the NH₃ loss in the NH₄⁺-vermiculite (Santa Olalla) by thermogravimetry, evolved gas analysis, chemical analysis, X-ray diffraction and IR spectroscopy is reported here. The mass loss during heating takes place in two steps at about 650 and 825 °C. Additionally, the releases of H₂O and NH₃ occurs simultaneously. The experimental results indicate that the protons remaining in the interlayer space after NH₃ removal trigger the H₂O release. X-ray diffraction shows that during the decomposition of NH₄⁺-vermiculite there are two domains with different interlayer spaces at ~9 and ~10 Å. As the decomposition proceeds, the intensity of the 9 Å peak increases at the expense of the second one. The change in the IR-stretching modes of the structural OH groups during heating indicates that the OH groups surrounded by 3Mg²⁺ or 2Mg²⁺Fe²⁺ are released at lower temperatures than those with environments like 2Mg²⁺Fe³⁺, 2Mg²⁺Al³⁺ or more complex ones.     

Influence of harbour constructions on morphosedimentary changes in the Tinto-Odiel estuary mouth (south-west Spain)

The Odiel-Tinto estuary is one of the most significant estuarine systems along the mesotidal Huelva Coast. The dynamics of this coastal sector are controlled by the interaction of ebb-tidal currents and the prevailing southwesterly waves. The main sediment supply is provided by an intensive west-to-east longshore current, transporting sand from Portuguese cliffs and discharge from the River Guadiana. The tidal range is mesotidal (2.0 m) and the mean significant wave height is 0.6 m with an average period of 3.6 s. This estuary mouth comprises three different barriers separated by the main estuary channel, and another marginal one that drains a significant part of the system. Saltés Island can be found between these two channels, which is composed of sandy barriers separated by muddy salt marshes that form a protected natural park. East of the main channel is Mazagón Beach, one of the most important tourist resorts on this coast. Recent papers have demonstrated that Saltés Island evolved as a chenier plain over the last 3000 years. The cause of this evolution was a special wave refraction scheme caused by two ebb-tidal delta systems located at the end of the two tidal channels. Three important harbour infrastructures have been constructed at the estuary mouth: a) a jetty at the end of Saltés Island, finished in 1977; b) a second and shorter jetty bordering the marginal channel constructed in 1984, and; c) a dock for sailing activities built on Mazagón Beach. These three structures have modified the natural dynamic scheme. The first consequence was to inhibit the functioning of the chenier plain, affecting the natural environment; the second was to intensively erode Mazagón Beach, endangering this tourist site.This paper analyses the causal relationships that exist between the harbour infrastructures and the resultant modifications.     

Comparative analysis of continuous radon sensors in underground environments

Four different continuous radon (²²²Rn)-detection systems have been compared in underground environments, namely three subhorizontal tunnels excavated for groundwater exploitation. Within observational uncertainties, all sensors detected the same concentrations of radon in the air of the tunnels, regardless of the methodology used to measure this radioactive gas. In this sense, the choice of continuous long-term radon monitoring sensors in underground tunnels is constrained by factors such as robustness of the instrumentation, power supply and cost, rather than the sensitivity of the detection methodology. This is particularly important for the monitoring of radon in the context of seismo-volcanic surveillance, where the harsh environmental conditions of the monitoring sites and the absence of electrical power supply are key factors to take into account.     

Changes in groundwater chemistry due to metallurgical activities in an alluvial aquifer in the Moa area (Cuba)

The aim of this work is to evaluate the changes in groundwater chemistry in an alluvial aquifer in the Moa area. Surface and ground water, metallurgical waste and various geological material samples were collected in order to evaluate groundwater composition. The results show that the alluvial aquifer is polluted with SO₄^2-, Mg²⁺and heavy metals. According to its major components in the alluvial aquifer, two types of groundwater are identified: magnesi-bicarbonated and sulphate-magnesic. Maximum SO₄^2– and Mg²⁺ contents are more than 1000 mg/L, and are four times higher than the acceptable levels for human consumption of water. The high values of Cr(VI), Ni(II), Mn(II) Fe_(total), SO₄^2– and Mg²⁺ in alluvial aquifers are due to polluted recharge from metallurgical waste from the tailing dam. This recharge is favoured by the preferential flow due to desiccation cracks in metallurgical waste. Geochemical modelling showed that potentially toxic heavy metals might exist largely in the forms of MSO₄^2– and M²⁺ in pore water of SAL metallurgical waste. All samples were supersaturated in goethite and hematite. Results from batch testing indicate that the heavy metals have two origins: natural, due to the existing ultramaphic rocks and laterites, and anthropogenic, by metallurgical waste rich in sulphate and (oxy)hydroxide minerals. These results highlight the need to locate and evaluate a new water source to supply the population of the city of Moa.     

Entropy inference of recurrence models for variability analysis of extreme events

A complete methodology is developed to analyze the recurrence of extreme environmental events and its variability as time without further events elapses. Firstly we investigate the conditioned recurrence inference problem consisting in the selection of a probability model for the interarrival time between extreme events, given a contexto-factual evidence conditioned by the time elapsed since the last of such events. Two ways to include this condition can be considered, which yield alternative conditioned evidences and convert the former problem into two distinct ones, thus giving rise to a possible consistency violation. These problems are formalized within the logical probability framework, in a plausible logic language that allows a suitable expression of the available observational data. They are solved using the REF relative entropy method with fractile constraints, and their solutions are compared at all inference levels. It is concluded that the two conditioning ways are not really mutually exclusive and that a unique global solution to the conditioned inference can be obtained using this procedure. An example illustrates an application of the methodology to the variability analysis of the recurrence time between historical inundations of the Guadalquivir river in Spain, as time elapses with no new floods.Acknowledgments. Support for this work was provided by DGI of Spain as the grant REN2000-2988-E/CLI and the research project REN2002-01337/CLI.     

Recent Tectonic Structures in a Transect of the Central Betic Cordillera

—The Betic Cordillera has undergone recent Alpine deformations related to the Eurasian-African plate interaction boundary. Most of the present-day relief has been built up since Tortonian times, and is related to the development of folds and faults that are overprinted on older deformations, and some of the faults may be considered as out-of-sequence. The combination of geophysical and geological data makes it possible to determine the main features of the recent tectonic structures, or those recently active, in its central transect. The main fault is a crustal detachment that separates a footwall constituted by the Iberian Massif and a hanging wall formed by the rocks of the Betic Cordillera. While the footwall is practically undeformed, the hanging wall has been folded and faulted. The folds are mainly E-W to NE-SW and have larger sizes and higher related relieves towards the South. The reverse faults are mainly concentrated in the northern mountain front. However, normal faults affect the southern part of the Cordillera and are associated with the development of large asymmetrical basins such as the Granada Depression. In this setting, the slip along the crustal detachment is variable and should increase southwards. The model of the recent tectonics in the central transect of the Cordillera is compatible with the presence of an active subduction in the Alboran Sea, and contrasts notably with the setting of the eastern Betic Cordillera, mainly deformed by transcurrent faults.     

Duration Magnitude Scale and Site Residuals for Northern Morocco

— The first empirical duration magnitude (M_D) formula is developed and tested for the Northern Morocco Seismic Network (NMSNET). This relationship is obtained by relating the IGN (Instituto Geografico National, Madrid) body-waves mbLg^IGN to the duration (), and the epicentral distance (), at 25 analogue stations of the NMSNET for 479 earthquakes with 2.5 mb 5.4, from March 1992 to February 2001. M_D estimates are significantly more precise while introducing a correction term for each of these stations, cSta_j. The magnitude for the i^th event (M_D)_i is the mean value of individual M_Dij=–0.14+1.63log₁₀(_ij)+0.031(_ij)+cSta_j. The cSta_j corrections reduce considerably the local site effects which influence the recorded durations and cause stations to either overestimate, or underestimate M_D up to 0.5 magnitude units. Average station M_D residuals (–cSta_j) are found to be independent of the distance from the epicenter to at least 10 degrees. It seems evident that regional geological features in the immediate behavior of stations have a systematic effect on the corresponding obtained residuals: older well-consolidated Precambrian crystalline rocks produce high negative residuals (shorter durations), younger unconsolidated sediments produce high positive residuals (longer durations), whereas, intermediate M_D site residuals appear to be the result of the effect of various factors, principally age and state of consolidation of the bedrock, combined with the local tectonic.     

Optimization of Time Data Codification and Transmission Schemes: Application to Gaia

Gaia is an ambitious space observatory devoted to obtain the largest and most precise astrometric catalogue of astronomical objects from our Galaxy and beyond. On-board processing and transmission of the huge amount of data generated by the instruments is one of its several technological challenges. The measurement time tags are critical for the scientific results of the mission, so they must be measured and transmitted with the highest precision – leading to an important telemetry channel occupation. In this paper we present the optimization of time data, which has resulted in a useful software tool. We also present how time data is adapted to the packet telemetry standard. The several communication layers are illustrated and a method for coding and transmitting the relevant data is described as well. Although our work is focused on Gaia, the timing scheme and the corresponding tools can be applied to any other instrument or mission with similar operational principles.