U‐Pb Geochronological and Thermochronological Time–Temperature Constraints of 40Ar/39Ar Hornblende Reference Material HB3gr

Hornblende from the Lone Grove Pluton, Llano Uplift, Texas, has served as an irradiation reference material in ⁴⁰Ar/³⁹Ar studies for decades. In order to evaluate the apparent age bias that currently exists between the U‐Pb and ⁴⁰Ar/³⁹Ar systems, zircon and titanite were dated by isotope dilution‐thermal ionisation mass spectrometry (ID‐TIMS) from the same rock from which the hornblende ⁴⁰Ar/³⁹Ar reference material HB3gr is derived. Zircon U‐Pb data indicate initial crystallisation at 1090.10 ± 0.16 Ma (2s), a date that is 1.7% older than the accepted K‐Ar date (1072 ± 14 Ma, 2s) for HB3gr; an offset that exceeds the typical 0.5–1% bias between the two systems, though remaining within uncertainty due to the large uncertainties in the ⁴⁰K decay constant. Zircon data are presented using both EARTHTIME tracers ET535 and ET2535 and are statistically indistinguishable. Single grain titanite analyses range between 1082 ± 0.75 and 1086 ± 0.81 Ma (2s) and are interpreted to record the subsequent cooling following crystallisation at rates between 30 and 50 °C Ma^?1. This is supported by the observation that hornblende ⁴⁰Ar/³⁹Ar dates corrected for decay constant bias are resolvably younger than the zircon U‐Pb date and in good agreement with titanite U‐Pb dates, permitting the conclusion that both titanite U‐Pb and hornblende ⁴⁰Ar/³⁹Ar systems provide a record of cooling.     

A composed index of critical accessibility (CICA) to healthcare services in a traditional African City

While empirical works that analyse rural–urban differentials in accessibility to health services are common in the developing countries, systematic studies focusing on intra-urban variations in accessibility to overall healthcare resources remain scant. Yet, many urban dwellers especially in the Sub-Saharan Africa have to travel long distances within the urban space to access basic health services. This study employs composed index of critical accessibility (CICA) to analyse differentials in access to health resources in Ibadan, a traditional African City. Data on healthcare centre location, ownership, doctors’ population were collected through field survey while spatial data on the administrative units and populated places were obtained from archival sources. Also, data on road networks was collected. Results show that the distribution of health facilities across local administrative units varies. In terms health facilities, Ibadan South West has 26 (36 %) of the total number while Ibadan South east has only 7 (9.8 %). The Doctor-Population Ratio also exhibits similar variations as Ibadan North has 20.5 as against 2.2, 1.9 and 0.3 for Ibadan SW, Ibadan NW and Ibadan NE respectively. The CICA analysis shows that 228,938 inhabitants are in high risk of negative accessibility while 49,234 are faced with condition of low risk of negative accessibility, which implies that a significant proportion of the population still finds it difficult to access basic health services as and when needed. The variations in the distribution of this deprived population are also noteworthy as the largest proportion of this group was localized in Ibadan NW. This has grave implication for the health and wellbeing of the population and raises once again the question of spatial equity in the delivery of urban public service. Curiously, these differences in the level of accessibility cut across administrative boundaries which brings to the fore the role of jurisdictional partitioning in ensuring equity in the delivery of urban public services. This opens a vista of research opportunity into the role jurisdictional partitioning in service provision in the urban centres.     

Equilibrium and Fractional Crystallization Experiments at 0{middle dot}7 GPa; the Effect of Pressure on Phase Relations and Liquid Compositions of Tholeiitic Magmas

Two series of anhydrous experiments have been performed in anend-loaded piston cylinder apparatus on a primitive, mantle-derivedtholeiitic basalt at 0·7 GPa pressure and temperaturesin the range 1060–1270°C. The first series are equilibriumcrystallization experiments on a single basaltic bulk composition;the second series are fractionation experiments where near-perfectfractional crystallization was approached in a stepwise mannerusing 30°C temperature increments and starting compositionscorresponding to that of the previous, higher temperature glass.At 0·7 GPa liquidus temperatures are lowered and thestability of olivine and plagioclase is enhanced with respectto clinopyroxene compared with phase equilibria of the samecomposition at 1·0 GPa. The residual solid assemblagesof fractional crystallization experiments at 0·7 GPaevolve from dunites, followed by wehrlites, gabbronorites, andgabbros, to diorites and ilmenite-bearing diorites. In equilibriumcrystallization experiments at 0·7 GPa dunites are followedby plagioclase-bearing websterites and gabbronorites. In contrastto low-pressure fractionation of tholeiitic liquids (1 bar–0·5GPa), where early plagioclase saturation leads to the productionof troctolites followed by (olivine) gabbros at an early stageof differentiation, pyroxene still crystallizes before or withplagioclase at 0·7 GPa. The liquids formed by fractionalcrystallization at 0·7 GPa evolve through limited silicaincrease with rather strong iron enrichment following the typicaltholeiitic differentiation path from basalts to ferro-basalts.Silica enrichment and a decrease in absolute iron and titaniumconcentrations are observed in the last fractionation step afterilmenite starts to crystallize, resulting in the productionof an andesitic liquid. Liquids generated by equilibrium crystallizationexperiments at 0·7 GPa evolve through constant SiO₂ increaseand only limited FeO enrichment as a consequence of spinel crystallizationand closed-system behaviour. Empirical calculations of the (dry)liquid densities along the liquid lines of descent at 0·7and 1·0 GPa reveal that only differentiation at the baseof the crust (1·0 GPa) results in liquids that can ascendthrough the crust and that will ultimately form granitoid plutonicand/or dacitic to rhyodacitic sub-volcanic to volcanic complexes;at 0·7 GPa the liquid density increases with increasingdifferentiation as a result of pronounced Fe enrichment, renderingit rather unlikely that such differentiated melt will reachshallow crustal levels. KEY WORDS: tholeiitic magmas; experimental petrology; equilibrium crystallization; fractional crystallization     

Influence of diet on the distribution of nitrogen isotopes in animals

The influence of diet on the distribution of nitrogen isotopes in animals was investigated by analyzing animals grown in the laboratory on diets of constant nitrogen isotopic composition.The isotopic composition of the nitrogen in an animal reflects the nitrogen isotopic composition of its diet. The δ₁₅N values of the whole bodies of animals are usually more positive than those of their diets. Different individuals of a species raised on the same diet can have significantly different δ¹⁵N values. The variability of the relationship between the δ¹⁵N values of animals and their diets is greater for different species raised on the same diet than for the same species raised on different diets. Different tissues of mice are also enriched in ¹⁵N relative to the diet, with the difference between the δ¹⁵N values of a tissue and the diet depending on both the kind of tissue and the diet involved. The δ¹⁵N values ofcollagen and chitin. biochemical components that are often preserved in fossil animal remains, are also related to the δ¹⁵N value of the diet.The dependence of the δ¹⁵N values of whole animals and their tissues and biochemical components on the δ¹⁵N value of diet indicates that the isotopic composition of animal nitrogen can be used to obtain information about an animal's diet if its potential food sources had different δ¹⁵N values. The nitrogen isotopic method of dietary analysis probably can be used to estimate the relative use of legumes vs non-legumes or of aquatic vs terrestrial organisms as food sources for extant and fossil animals. However, the method probably will not be applicable in those modern ecosystems in which the use of chemical fertilizers has influenced the distribution of nitrogen isotopes in food sources.The isotopic method of dietary analysis was used to reconstruct changes in the diet of the human population that occupied the Tehuacan Valley of Mexico over a 7000 yr span. Variations in the δ¹⁵C and δ¹⁵N values of bone collagen suggest that C₄ and/or CAM plants (presumably mostly corn) and legumes (presumably mostly beans) were introduced into the diet much earlier than suggested by conventional archaeological analysis.     

The concentration and isotopic composition of hydrogen,carbon and nitrogen in carbonaceous meteorites

Concentrations and isotopic compositions were determined for H₂, N₂ and C extracted by stepwise pyrolysis from powdered meteorites, from residues of meteorites partially dissolved with aqueous HF, and from residues of meteorites reacted with HF-HCl solutions. The meteorites treated were the carbonaceous chondrites, Orgueil, Murray, Murchison, Renazzo and Cold Bokkeveld. Data determined for whole rock samples are in approximate agreement with previously published data. Acidification of the meteorites removed the inorganic sources of H₂, so that H₂ in the HF-HCl acid residues came primarily from insoluble organic matter, which makes up 70–80% fraction of the total carbon in carbonaceous meteorites. The δD in the organic matter differs markedly from previously determined values in organic matter in meteorites. The δD values of organic matter from acid residues of C1 and C2 carbonaceous chondrites range from +650 to + 1150%. The acid residues of the Renazzo meteorite, whose total H₂ has a δD of +930‰, gave a δD value of +2500‰. Oxidation of the HF-HCl residue with H₂O₂ solution removes the high δD and the low δ¹⁵N components. The δ¹³C values range between ?10 and ?21 and δ¹⁵N values range between +40 and ?11. The δ¹⁵N of Renazzo is unusual; its values range between +150 and ?190.There is good correlation between δD and the concentration of H₂ in the acid residues, but no correlation exists between δD, δ¹³C and δ¹⁵N in them. A simple model is proposed to explain the high δD values, and the relationships between δD values and the concentration of H₂. This model depends on the irradiation of gaseous molecules facilitating reaction between ionic molecules, and indicates that an increase in the rate of polymerization and accumulation of organic matter on grains would produce an increase in the deuterium concentration in organic matter.     

Conditional LAS stochastic simulation of regionalized variables in random fields

Ore reserves forecasts are required to aid in investment decisions, mine design and valuation, short and long term production plans and proper and efficient mill design. In random multivariable fields with limited data and high levels of uncertainty, the kriged block estimates produce a smoothing effect resulting in underestimating high values and overestimating low values. The modified conditional simulation (MCS) methodology solves these problems by simulating the random field to preserve its mean and the variance structure. The simulation model is conditioned to reproduce the data at known sample points to minimize the variability between the simulated data and the true field data. In this study, the authors develop the MCS methodology to simulate ore reserve grades using the best linear unbiased estimation (BLUE) and the local average subdivision (LAS) techniques. The MCS methodology is applied to simulate block grades in a section of the Sabi Gold Project in Zimbabwe. The results are compared with the kriged estimates for this section. Analysis of the results shows that the MCS methodology reproduces the known sample grades with minimum estimation error of 0.001 while the estimation error associated with the kriged estimates is 1.104, a 100% efficiency of the MCS method over the kriging technique.     

Daily rainfall erosivity as an indicator for natural disasters: assessment in mountainous regions of southeastern Brazil

Natural Hazards - Rainfall erosivity is defined as the rainfall potential to cause erosion. Its concept is based on the kinetic energy of rainfall, rainfall intensity, and maximum rainfall...     

Farming as a livelihood source for the urban poor of Nakuru, Kenya

Farming among urban dwellers in Sub-Saharan Africa is a common phenomenon. The present study, carried out in a medium-sized town in Kenya, not only confirmed this but also showed that farming by urban dwellers in the rural areas was even more important for these households’ livelihoods than farming in town. However, those who could benefit most from farming, i.e. the urban poor, appeared to be underrepresented among urban farming households and those urban poor who did farm, either in urban or in rural areas, performed worse than the farming non-poor. The importance of farming as a livelihood source is illustrated by the fact that in years with very little or no harvest due to drought, many of the poor farming households faced food shortages.     

Accretion of differentiated achondritic and aqueously altered chondritic materials in the early solar system—Significance of an igneous fragment in the CM chondrite NWA 12651

One approach to decipher the dynamics of material transport and planetary accretion in the early solar system is to investigate xenolithic fragments in meteorites. In this work, we examined an igneous fragment from the NWA 12651 meteorite—the first igneous fragment found in any CM chondrite—by analyzing its mineralogy, rare earth elements (REEs), and O‐isotopes. The study shows that the exsolution lamellae of the igneous fragment consist of Fe‐rich and Ca‐rich pyroxene. Thus, the fragment was part of a progressive crystallization in a closed system, such as in a depleted magma reservoir or mantle. In this environment, the pyroxene co‐crystallized with plagioclase, resulting in a negative Eu anomaly and enrichment of the heavy REEs compared to the light REEs. The O‐isotopes of the fragment are more ¹⁶O‐enriched than the mafic minerals in the matrix or in other bulk CM chondrites; therefore, the fragment was formed in a different region than the NWA 12651 parent body. The iron meteorites Tucson and Deep Springs, the pallasite Milton, and the CB chondrites have similar O‐isotopes as the igneous fragment. However, no direct connection can be drawn and it is questionable if the fragment shares a same parent body with one of these meteorites. The close formation region to the CB chondrites may suggest a formation of the fragment in the carbonaceous chondrite region. Thus, a wide transport through the nebula of the early solar system may not have been necessary to move the fragment to the CM chondrite formation region.     

Realization of Einstein’s Machian Program: the Pioneers and fly-by anomalies Part I

In a previous paper (Berman, in Astrophys. Space Sci., 2011), we showed how to prove the two Pioneers Anomalies, and now we add the fly-bys, by means of a rotating Universe. We discuss Einstein’s Machian program, which we find as being fullfilled. Godlowski et al. (Los Alamos Archives, 2003) idea for a rotating General Relativistic Universe, led us to the adopted model. Updated evidence on rotation is cited (Godlowski, in Los Alamos Archives, 2011; Ni in Phys. Rev. Lett. 107(5):051103, 2011). We conclude that a rotating and expanding Universe may be the unique solution to the apparent divergences between Einstein and Mach. This is cosmologically important.