The extent of oxygen isotope exchange between clay minerals and sea water

The extent of oxygen isotopic exchange between detrital clay minerals and sea water was investigated by analyzing $\text{O}{}^{18}\text{O}{}^{16}$ ratios of separated fine-grained size fractions of deep-sea sediments from three North Pacific ocean cores. Isotopic results were interpreted according to models based on the assumption that the extent of isotopic exchange should increase with decreasing particle size and increasing time of exchange between the sediment and sea water. The data indicate that information concerning the provenance and mode of formation of detrital clay minerals can be obtained from the $\text{O}{}^{18}\text{O}{}^{16}$ ratios of the coarser-than-0.1 μm fraction of deep-sea sediments younger than several million years and the finer-than-0.1 μm fraction of deep-sea sediments younger than several tens of thousands of years. Furthermore, if the extent of chemical reaction between detrital clays and sea water is similar to the extent of oxygen isotopic exchange, such reaction may be important in regulating the chemistry of sea water.     

Stratigraphy and geochemical characterization of the Oligocene–Miocene Maikop series: Implications for the paleogeography of Eastern Azerbaijan

The Oligocene–Miocene Maikop Series is a world-class source rock responsible for much of the oil and gas found in the South Caspian Basin. It is composed of up to 3 km of marine mudstone, and contains a nearly continuous record of deposition during progressive tectonic closure of the basin as the Arabian Peninsula converged northward into Eurasia. Historically, the stratigraphy of this interval has been difficult to define due to the homogenous nature of the fine-grained, clay-dominated strata. Outcrop exposures in eastern Azerbaijan allow direct observation and detailed sampling of the interval, yielding a more comprehensive stratigraphic context and a more advanced understanding of syndepositional conditions in the eastern Paratethys Sea. Specifically, the present investigation reveals that coupling field-based stratigraphic characterization with geochemical analyses (e.g., bulk elemental geochemistry, Rock-Eval pyrolysis, bulk stable isotope geochemistry) yields a more robust understanding of internal variations within the Maikop Series. Samples from seven sections located within the Shemakha–Gobustan oil province reveal consistent stratigraphic and spatial geochemical trends. It is proposed that the Maikop Series be divided into three members based on these data along with lithostratigraphic and biostratigraphic data reported herein. When comparing Rupelian (Early Oligocene) and Chattian (Late Oligocene) strata, the Rupelian-age strata commonly possess higher TOC values, more negative δ¹⁵N_tot values, more positive δ¹³C_org values, and higher radioactivity relative to Chattian-age rocks. The trace metals Mo and V (normalized to Al) are positively correlated with TOC, with maximum values occurring at the Rupelian–Chattian boundary and overall higher average values in the Rupelian. Across the Oligocene–Miocene boundary, a slight drop in V/Al, Mo/Al ratios is observed, along with drops in %S and TOC. These results indicate that geochemical signatures of the Maikop Series are regional in nature, and furthermore that analogous fine-grained sections may be better characterized and subdivided using similar techniques. In general, geochemical indicators suggest that the basin was in limited communication with the Tethys Sea throughout the Oligocene–Early Miocene, with suboxic to anoxic conditions present during the Oligocene and to a lesser extent in the Miocene. This increased isolation was likely due to tectonic uplift to both the south and north of the study area, and greatly enhanced by global sea-level fluctuations. These data serve as the basis for a more detailed understanding of the tectonic evolution of the region, and support a standardized chemostratigraphic division of the important petroleum source interval.     

Petrology and CHIME geochronology of Pan-African high K and Sr/Y granitoids in the Nkambe area, Cameroon

The Central African Belt in the Nkambe area, northwestern Cameroon represents a collisional zone between the Saharan metacraton and the Congo craton during the Pan-African orogeny, and exposes a variety of granitoids including foliated and massive biotite monzogranites in syn- and post-kinematic settings. Foliated and massive biotite monzogranites have almost identical high-K calc-alkaline compositions, with 73–67 wt.% SiO₂, 17–13 wt.% Al₂O₃, 2.1–0.9 wt.% CaO, 4.4–2.7 wt.% Na₂O and 6.3–4.4 wt.% K₂O. High concentrations of Rb (264–96 ppm), Sr (976–117 ppm), Ba (3680–490 ppm) and Zr (494–99 ppm), with low concentrations of Y (mostly< 20 ppm with a range 54–6) and Nb (up to 24 ppm) suggest that the monzogranites intruded in collisional and post-collisional settings. The Sr/Y ratio ranges from 25 to 89. K, Rb and Ba resided in a single major phase such as K-feldspar in the source. Garnet was present in the source and remained as restite at the site of magma generation. This high K₂O and Sr/Y granitic magma was generated by partial melting of a granitic protolith under high-pressure and H₂O undersaturated conditions where garnet coexists with K-feldspar, albitic plagioclase. CHIME (chemical Th–U-total Pb isochron method) dating of zircon yields ages of 569 ± 12–558 ± 24 Ma for the foliated biotite monzogranite and 533 ± 12–524 ± 28 Ma for the massive biotite monzogranite indicating that the collision forming the Central African Belt continued in to Ediacaran (ca 560 Ma).     

Converted‐wave beam migration with sparse sources or receivers

Gaussian beam depth migration overcomes the single‐wavefront limitation of most implementations of Kirchhoff migration and provides a cost‐effective alternative to full‐wavefield imaging methods such as reverse‐time migration. Common‐offset beam migration was originally derived to exploit symmetries available in marine towed‐streamer acquisition. However, sparse acquisition geometries, such as cross‐spread and ocean bottom, do not easily accommodate requirements for common‐offset, common‐azimuth (or common‐offset‐vector) migration. Seismic data interpolation or regularization can be used to mitigate this problem by forming well‐populated common‐offset‐vector volumes. This procedure is computationally intensive and can, in the case of converted‐wave imaging with sparse receivers, compromise the final image resolution. As an alternative, we introduce a common‐shot (or common‐receiver) beam migration implementation, which allows migration of datasets rich in azimuth, without any regularization pre‐processing required. Using analytic, synthetic, and field data examples, we demonstrate that converted‐wave imaging of ocean‐bottom‐node data benefits from this formulation, particularly in the shallow subsurface where regularization for common‐offset‐vector migration is both necessary and difficult.     

Texas environmental flow standards and the hydrology-based environmental flow regime methodology

Abstract

In 2007, the Texas legislature created a program to identify environmental flow standards statewide through the coordinated efforts of scientific and stakeholder groups and rulemaking by the Texas Commission on Environmental Quality. To aid in this task, a Hydrology-based Environmental Flow Regime (HEFR) method was developed that combines a suite of user-customizable hydrologic statistics with an implementation framework. Following the concepts of the Natural Flow Paradigm, the methodology includes the separation of a long-term hydrograph into key flow components (e.g. subsistence, base, high-flow pulse and overbank) defined by the Texas Instream Flow Program. Seasonal, annual and inter-annual flow component statistics were then coupled with biology, water quality and geomorphology overlays, where available, and with implementation rules applied to example large-scale water supply projects to support development of environmental flow standards for use in water rights permit conditions. The HEFR methodology and resulting flow recommendations are compared to two contemporary in-stream flow studies and adopted environmental flow standards. Subsistence flows were fairly similar. Baseflows were in a similar range, but fewer than three seasonal levels have sometimes been specified in in-stream flow studies. Episodic events are quite different in terms of magnitude, frequency, duration and applicable number.

Editor D. Koutsoyiannis; Guest editor M. Acreman

Citation Opdyke, D.R., Oborny, E.L., Vaugh, S.K., and Mayes, K.B., 2014. Texas environmental flow standards and the hydrology-based environmental flow regime methodology. Hydrological Sciences Journal, 59 (3–4), 820–830.     

Use of a Sodar to Improve the Forecast of Fogs and Low Clouds on Airports

A sodar was deployed at Roissy–Charles de Gaulle airport near Paris, France, in 2008 with the aim of improving the forecast of low visibility conditions there. During the winter of 2008–2009, an experiment was conducted that showed that the sodar can effectively detect and locate the top of fog layers which is signaled by a strong peak of acoustic reflectivity. The peak is generated by turbulence activity in the inversion layer that contrasts sharply with the low reflectivity recorded in the fog layer below. A specific version of the 1D-forecast model deployed at Roissy for low visibility conditions (COBEL-ISBA) was developed in which fogs’ thicknesses are initialized by the sodar measurements rather than the information derived from the down-welling IR fluxes observed on the site. It was tested on data archived during the winters of 2008–2009 and 2009–2010 and compared to the version of the model presently operational. The results show a significant improvement—dissipation times of fogs are better predicted.     

Vertical structure of the stable boundary layer detected by RASS-SODAR and in-situ measurements in SABLES 2006 field campaign

Data from the SABLES 2006 field campaign are used in order to analyse some of the main processes present along the nocturnal periods: surface-based inversions, low level jets, katabatic winds, wave-like motions, pressure perturbations, etc. These processes have an important influence on the vertical structure (both thermal and dynamical) of the atmospheric boundary layer, and can be better described with the synergetic combination of RASS-SODAR data and in-situ measurements (such as sonic anemometer data and high-resolution pressure series from microbarometers). It is shown how the different air masses and their evolution are easily identified when pressure and RASS-SODAR wind and temperature data are presented together. Likewise, periodic pressure fluctuations observed in the surface array of microbarometers reveal the existence of gravity wave motions whose propagation is better understood after locating the wave ducting layers with the help of RASS-SODAR average wind ant temperature profiles.