Heavy carbon in individual oxide grains from the Murchison meteorite

The carbon isotopic composition of individual oxide grains from Murchison HF—HCl acid residue CFOc has been measured in the ion microprobe. Many grains (Mg-spinel, Cr-spinel, and Fe-oxide) contain carbon with large¹³C excesses ranging to 7000‰ (corresponding to¹²C/¹³C= 11). In most cases the carbon is present as micron-sized subgrains. The association of silicon with the anomalous carbon points towards SiC as carrier. If this tentative identification is correct then the SiC grains most likely originated in the circumstellar atmospheres of red giants. Oxide grains in which the ¹⁸O/¹⁶O ratio has also been measured show variable¹⁶O excesses which are not correlated with the¹³C excesses. This indicates that the sources of the anomalous carbon and oxygen isotopic compositions of the oxide grains are unrelated.     

Pb-isotopic compositions of volcanic rocks in the West and East Philippine island arcs: presence of the Dupal isotopic anomaly

The Philippine islands are situated between two oppositely dipping zones of seismicity. With the exception of a few areas, such as in the west central Philippines where the North Palawan continental terrane (NPCT) has collided with the archipelago, these seismic zones are well defined to depths of 200 km. Active volcanic chains overlay segments in each of these zones, suggesting that subduction is presently taking place both east and west of the islands. Lavas we have studied are thus divided between what has been termed the West Philippine arc and the East Philippine arc.West Philippine arc volcanic rocks which were extruded before the Philippine archipelago collided with the NPCT, or which are younger than the collision but crop out hundreds of kilometers from the collision zone, and all but one of the rocks from the East Philippine arc fall in the MORB field on²⁰⁷Pb/²⁰⁴Pb versus²⁰⁶Pb/²⁰⁴Pb covariation diagrams. This is surprising considering the frequency with which arc materials have²⁰⁷Pb/²⁰⁴Pb ratios higher than those of MORB, the highBa/REE and Sr/REE ratios in the lavas and the possibility of sediment subduction given the small accretionary prisms. All of these rocks have high²⁰⁸Pb/²⁰⁴Pb ratios with respect to Pacific and Atlantic Ocean MORB, but are similar to Indian Ocean MORB and IOB. Thus the Philippines consist of island arcs with the peculiar Dupal isotopic anomaly documented between 0° and 60°S in the southern hemisphere and particularly in the Indian Ocean region. This demonstrates that the Dupal isotopic anomaly is not restricted to the southern hemisphere, or to MORB and OIB.Post-collision rocks cropping out near the NPCT, in the West Philippine arc, have elevated²⁰⁸Pb/²⁰⁴Pb and ²⁰⁷Pb/²⁰⁴Pb ratios that could be attributed to assimilation of the newly introduced continental crust (NPCT) by mantle-derived magmas or to the addition of a sedimentary component to mantle-derived magmas.     

Tectono-magmatic evolution of the 1.9-Ga great bear magmatic zone, Wopmay orogen, northwestern Canada

The 1875-1840-Ma Great Bear magmatic zone is a 100-km wide by at least 900-km-long belt of predominantly subgreenschist facies volcanic and plutonic rocks that unconformably overlie and intrude an older sialic basement complex. The basement complex comprises older arc and back-arc rocks metamorphosed and deformed during the Calderian orogeny, 5–15 Ma before the onset of Great Bear magmatism. The Great Bear magmatic zone contains the products of two magmatic episodes, separated temporally by an oblique folding event caused by dextral transpression of the zone: (1) a 1875-1860-Ma pre-folding suite of mainly calc-alkaline rocks ranging continuously in composition from basalt to rhyolite, cut by allied biotite-hornblende-bearing epizonal plutons; and (2) a 1.85-1.84-Ga post-folding suite of discordant, epizonal, biotite syenogranitic plutons, associated dikes, and hornblende-diorites, quartz diorites, and monzodiorites. The pre-folding suite of volcanic and plutonic rocks is interpreted as a continental magmatic arc generated by eastward subduction of oceanic lithosphere. Cessation of arc magmatism and subsequent dextral transpression may have resulted from ridge subduction and resultant change in relative plate motion. Increased heat flux due to ridge subduction coupled with crustal thickening during transpression may have caused crustal melting as evidenced by the late syenogranite suite. Final closure of the western ocean by collision with a substantial continental fragment, now forming the neoautochthonous basement of the northern Canadian Cordillera, is manifested by a major swarm of transcurrent faults found throughout the Great Bear zone and the Wopmay orogen.Although there is probably no single evolutionary template for magmatism at convergent plate margins, the main Andean phase of magmatism, exemplified by the pre-folding Great Bear magmatic suite, evolves as larger quantities of subduction-related mafic magma rise into and heat the crust. This results in magmas that are more homogeneous, siliceous, and explosive with time, ultimately leading to overturn and fractionation of the continental crust.     

The geochemistry and petrogenesis of the volcanic rocks of Carriacou,Grenadine Islands,West Indies

Carriacou is small volcanic island located near the southern end of the Lesser Antillean chain. Field relationships, petrography and geochemistry of the Tertiary lavas, outcropping in the southern half of the island, are used to identify the rocks present and to determine their petrogenesis and assess their significance within the island arc.Six main volcanic units are present. From oldest to youngest, these are the clinopyroxene-phyric basalt (CPB) sequence, the amphibole-phyric andesite (APA) sequence, the clinopyroxene-megaphyric basalt (CMB) sequence, the olivine-microphyric basalt (OMB) sequence, the clinopyroxene phyric andesite (CPA) sequence, and the amphibole-megaphyric andesite (AMA) sequence. Volcaniclastic deposits are associated with the APA, CMB, and AMA sequences. The APA sequence is calcalkaline, whereas the other five sequences are tholeiitic.Sr isotope and rare earth element (REE) data suggest that these volcanic rocks were derived from partial melts of garnet-peridotite generated deep within the mantle. The OMB lavas have the highest temperature assemblages of intratelluric minerals and the least evolved chemical characteristics, and are considered to be closest in composition to a parental melt. Phenocryst assemblages and chemical variation suggest that the andesite sequences have been derived from the mafic melts by low pressure fractional crystallization of approximately 20% clinopyroxene and 20% olivine, plus smaller amounts of plagioclase and amphibole. The high concentrations of incompatible and compatible elements and the high⁸⁷Sr/⁸⁶Sr ratios may indicate that subduction is slower in the southern part of the arc, and fluids released during slab dehydration rich in Incompatible trace elements, in Radiogenic strontium, and in Silica (IRS), have modified the parental melts.     

The global distribution of long-term total ozone variations during the period 1957–1975

Total ozone observations in the international network have been used as a basis for the analysis of the mean monthly ozone distribution over the globe for the period 1957–75. It has been found that during the period 1961–70 the total ozone amount increased in the Northern Hemisphere by about 12 percent and that this increase seems to be significant at all latitudes. Although the data were sparse for the Southern Hemisphere, there did not appear to be any significant ozone changes during the 10 year period. Relatively large geographic variations were found in the ozone trends and it is suggested that these variations are related to large scale changes in the atmospheric circular pattern.     

On the applicability of a universal elastic trench profile

Using thin elastic plate theory and neglecting horizontal applied forces, a universal deflection profile applicable to many oceanic trenches is derived. This theoretical profile is compared with bathymetric profiles from the central Aleutian, Kuril, Bonin, and Mariana trench-outer rise regions. The profiles were corrected for sediment thickness and age variation of the lithosphere. Good agreement between theory and observation is found. The distance from the first point of zero deflection seaward of the trench to the point of maximum height of the outer rise is directly related to the flexural rigidity of the lithosphere. The thickness of the elastic lithosphere is found to vary between 20 and 29 km for the trench profiles considered. The good agreement obtained shows that horizontal forces may be neglected and that the bending lithosphere behaves elastically in the cases considered. The analysis shows that only unreasonably large horizontal forces would affect the universal deflection curve. It is concluded that although the near-surface lithosphere may be subject to brittle fracture, the deeper lithosphere is capable of transmitting elastic stresses as high as 9 kbar.     

Stable isotope geochemistry of deep sea cherts

Seventy four samples of DSDP recovered cherts of Jurassic to Miocene age from varying locations, and 27 samples of on-land exposed cherts were analyzed for the isotopic composition of their oxygen and hydrogen. These studies were accompanied by mineralogical analyses and some isotopic analyses of the coexisting carbonates. δ¹⁸O of chert ranges between 27 and 39%. relative to SMOW, δ¹⁸O of porcellanite—between 30 and 42%.. The consistent enrichment of opal-CT in porcellanites in ¹⁸O with respect to coexisting microcrystalline quartz in chert is probably a reflection of a different temperature (depth) of diagenesis of the two phases.δ¹⁸O of deep sea cherts generally decrease with increasing age, indicating an overall cpoling of the ocean bottom during the last 150 m.y. A comparison of this trend with that recorded by benthonic foraminifera (Douglas and Savin, 1975) indicates the possibility of δ¹⁸O in deep sea cherts not being frozen in until several tens of millions of years after deposition. Cherts of any Age show a spread of δ¹⁸O values, increasing diagenesis being reflected in a lowering of δ¹⁸O. Drusy quartz has the lowest δ¹⁸O values.On-land exposed cherts are consistently depleted in ¹⁸O in comparison to their deep sea time equivalent cherts.Water extracted from deep sea cherts ranges between 0.5 and 1.4 wt %. δD of this water ranges between ?78 and ?95%. and is not a function of δ¹⁸O of the cherts (or the temperature of their formation).     

Ultraviolet observations of Mars made by the orbiting astronomical observatory

Ultraviolet albedos of Mars in the region γγ2000–3600 Å are discussed. When the reflectivity due to the known amount of CO₂ on Mars is accounted for, the remaining reflectivity may be used to set an upper limit for the surface albedo. The result disagrees qualitatively with published ultraviolet reflectivities of limonite and carbon suboxide. An alternate interpretation of the observations leads to the conclusion that CO₂ comprises at least 60% of the molecular atmosphere of Mars, assuming the remainder to be argon. A comparison of the OAO results with 1969 Mariner ultraviolet data reveals some important areas of conflict.Attempts to detect Mars at wavelengths less than γ2000 Å were unsuccessful, with only very high upper limits being set.     

Planetary nebulae in planetary and binary systems

The problem of the survival of a low-mass secondary orbiting a primary that becomes a planetary nebula is studied. The values of the mass of the primary are 1.0, 1.5, and 2.0M ; the values of the mass of the secondary 0.001M , 0.01M and 0.1M . The orbital decay and mass of the secondary due to accretion and gravitational drag in the common envelope are presented. The possible application of the results to V471 Tau, UU Sge, WZ Sge and the Sun-Jupiter system are discussed.