Temporal Variability of Major and Trace Element Concentrations in the Groundwaters of Mt. Etna (Italy): Effects of Transient Input of Magmatic Fluids Highlighted by Means of Cluster Analysis

Data for major, minor and trace elements in groundwaters from Mt. Etna volcano collected in 1994, 1995 and 1997 were analyzed using Cluster Analysis (CA). Two groups of sampling sites were identified (named clusters A and B), mainly on the basis of their different salinity and content of dissolved CO₂. The highest levels of both of these parameters were observed in the sites of cluster A, located in the lower south-western and central eastern flanks of the volcano. For both of the statistical groups CA was repeated, taking into account the mean values of each parameter in time, and the results allowed us to recognize four distinct groups of parameters for each group of sites on the basis of their temporal patterns. Four different types of temporal patterns were recognized: concave, convex, increasing, decreasing. The observed changes were basically interpreted as a result of the different response of dissolved chemical elements to changes in the aqueous environment and/or in their solubility/mobility in water due to different rates of input of magmatic gases to Etna’s aquifers. The main changes occurred in 1995, when Etna’s volcanic activity resumed after a two-year period of rest. The temporal changes of the majority of the studied parameters (water temperature, water conductivity, Eh, pH, Al, Mg, B, Ca, Cl⁻, Hg, Mn, Mo, Na, Ni, Se, Si, Sr, Cr Zn and pCO₂) were not cluster-dependent, therefore they were not apparently affected by differences in water salinity between the two groups of sampling sites. A limited number of parameters (Ti, K, Li, HCO₃⁻, As, Fe, SO₄²⁻, Cu and V), however, manifested different behaviors, depending on the cluster of sites to which they belonged, thus suggesting their apparent dependency on water salinity.     

Entropy production and coarse graining of the climate fields in a general circulation model

We extend the analysis of the thermodynamics of the climate system by investigating the role played by processes taking place at various spatial and temporal scales through a procedure of coarse graining. We show that the coarser is the graining of the climatic fields, the lower is the resulting estimate of the material entropy production. In other terms, all the spatial and temporal scales of variability of the thermodynamic fields provide a positive contribution to the material entropy production. This may be interpreted also as that, at all scales, the temperature fields and the heating fields resulting from the convergence of turbulent fluxes have a negative correlation, while the opposite holds between the temperature fields and the radiative heating fields. Moreover, we obtain that the latter correlations are stronger, which confirms that radiation acts as primary driver for the climatic processes, while the material fluxes dampen the resulting fluctuations through dissipative processes. We also show, using specific coarse-graining procedures, how one can separate the various contributions to the material entropy production coming from the dissipation of kinetic energy, the vertical sensible and latent heat fluxes, and the large scale horizontal fluxes, without resorting to the full three-dimensional time dependent fields. We find that most of the entropy production is associated to irreversible exchanges occurring along the vertical direction, and that neglecting the horizontal and time variability of the fields has a relatively small impact on the estimate of the material entropy production. The approach presented here seems promising for testing climate models, for assessing the impact of changing their parametrizations and their resolution, as well as for investigating the atmosphere of exoplanets, because it allows for evaluating the error in the estimate of their thermodynamical properties due to the lack of high-resolution data. The findings on the impact of coarse graining on the thermodynamic fields on the estimate of the material entropy production deserve to be explored in a more general context, because they provide a way for understanding the relationship between forced fluctuations and dissipative processes in continuum systems.     

“Failed” eruptions revealed by pattern classification analysis of gas emission and volcanic tremor data at Mt. Etna,Italy

During the spring of 2007, paroxysmal activity occurred at the Southeast Crater of Mt. Etna, always associated with sharp rises in the amplitude of the volcanic tremor. Activity ranged from strong Strombolian explosions to lava fountains coupled with copious emission of lava flows and tephra. During inter-eruptive periods, recurrent seismic unrest episodes were observed in the form of temporary enhancements of the volcanic tremor amplitude, but they did not culminate in eruptive activity. Here, we present the results of an analysis of these inter-eruptive periods by integrating seismic volcanic tremor, in-soil radon, plume SO₂ flux, and thermal data. SO₂ flux and thermal radiation are envisaged as the “smoking gun,” and certifying that changes in seismic or radon data can be considered as volcanogenic. Short-term changes were investigated by pattern classification based on Kohonen maps and fuzzy clustering on volcanic tremor, radon, and ambient parameters (pressure and temperature). Our results unveil “failed” eruptions between February and April 2007 that are explained as ascending magma batches, which triggered repeated episodes of gas pulses and rock fracturing, but that failed to reach the surface.     

High-temperature rapid pyrometamorphism induced by a charcoal pit burning: The case of Ricetto,central Italy

Bulk chemistry and mineralogy of the peculiar rock of Ricetto (Carseolani Mts., Central Apennines, Italy) was studied to resolve its controversial origin: igneous dyke or anthropic product. This hybrid rock consists of a colorless, felsic component made up of glass plus quartz, and a brown, femic component made up of fans and spherulites of diopside, calcic plagioclase, wollastonite, and melilite. Textural relationships indicate very rapid cooling and immiscibility phenomena. The bulk chemistry of the rock is the same as that of the surrounding siliciclastic sandstone. The ¹⁴C analysis of a coal fragment from bottom of the body yields the conventional age of 227(±50) years. The Ricetto occurrence is an example of pyrometamorphism of a siliceous limestone induced by a charcoal pit burning. The small size of the heat source at Ricetto caused an intense but short-lived melting of the country rock. Prograde metamorphism caused a temperature increase up to 1,000–1,100 °C when melilite crystallization conditions were reached at appreciable P(CO₂) and high f(O₂). Melting occurred in a close system represented by the simplified equation: 3Cal+16.5Qtz+Ms+BtMel+Melt+2H₂O+3CO₂+0.5O₂. Diopside+calcic plagioclase+wollastonite formed by melilite breakdown during rapid cooling, through the reaction: 6Mel+6Qtz+0.5O₂3Di+2An+7Wo. Liquid immiscibility caused the separation between the felsic melt component and the femic melilite-bearing component. Immiscibility was characterized by different fractionation of alumina and alkalies between these two phases. Differences in bulk, glass, and mineral chemistry between the Ricetto and other melilite-bearing pyrometamorphic rocks can be attributed mainly to different protoliths.An erratum to this article can be found at     

The Balance Between Capturing Phosphorus from Manure and Wastewater and the Demand for Crop Fertilizer in Italy

Phosphorus (P) is an essential nutrient required for plant growth and at the same time a costly pollutant, which can cause eutrophication of water bodies. Modern agriculture relies heavily on mineral fertilisers, which contain phosphorus derived from phosphate rock, because, without regular applications, crop yields would be limited. Since phosphate rock is a non-renewable resource, there are growing concerns regarding future phosphorus scarcity and the sustainability of modern agriculture. For many farmers, animal manure was once a means of maintaining soil fertility, but now it presents a major operational problem. This study evaluated the possibility of recycling phosphorus on a national and regional scale in Italy, using major sources of manure and wastewater. These results were successively compared with an estimate of the agricultural demand for phosphorus. Considering the quantity of phosphorus fertilizer that was applied to the soil–plant system, for the years 2001–2010, the annual phosphorus requirement of Italian crops was about 101,000 t of P. Therefore, the phosphorus source comprising animal manure and civil/industrial waste (117,500 t of P and 40,000 t of P, respectively) could potentially satisfy the average annual agronomic phosphorus demand. Regarding the geographical distribution of phosphorus supply and demand on a regional scale, areas with a large deficit of phosphorus included Calabria, Puglia and Marche. However, when only livestock waste was considered, Sicily, Umbria and Friuli could also be considered to be regions experiencing a phosphorus deficit.

     

Ground deformation modeling of flank dynamics prior to the 2002 eruption of Mt. Etna

On 22 September 2002, 1 month before the beginning of the flank eruption on the NE Rift, an M-3.7 earthquake struck the northeastern part of Mt. Etna, on the westernmost part of the Pernicana fault. In order to investigate the ground deformation pattern associated with this event, a multi-disciplinary approach is presented here. Just after the earthquake, specific GPS surveys were carried out on two small sub-networks, aimed at monitoring the eastern part of the Pernicana fault, and some baselines belonging to the northeastern EDM monitoring network of Mt. Etna were measured. The leveling route on the northeastern flank of the volcano was also surveyed. Furthermore, an investigation using SAR interferometry was performed and also the continuous tilt data recorded at a high precision sensor close to the epicenter were analyzed to constrain the coseismic deformation. The results of the geodetic surveys show a ground deformation pattern that affects the entire northeastern flank of the volcano, clearly shaped by the Pernicana fault, but too strong and wide to be related only to an M-3.7 earthquake. Leveling and DInSAR data highlight a local strong subsidence, up to 7 cm, close to the Pernicana fault. Significant displacements, up to 2 cm, were also detected on the upper part of the NE Rift and in the summit craters area, while the displacements decrease at lower altitude, suggesting that the dislocation did not continue further eastward. Three-dimensional GPS data inversions have been attempted in order to model the ground deformation source and its relationship with the volcano plumbing system. The model has also been constrained by vertical displacements measured by the leveling survey and by the deformation map obtained by SAR interferometry.