Multiple cosmogenic nuclides document complex Pleistocene exposure history of glacial drifts in Terra Nova Bay (northern Victoria Land, Antarctica)

Geomorphological and glacial geological surveys and multiple cosmogenic nuclide analyses (¹⁰Be, ²⁶Al, and ²¹Ne) allowed us to reconstruct the chronology of variations prior to the last glacial maximum of the East Antarctic Ice Sheet (EAIS) and valley glaciers in the Terra Nova Bay region. Glacially scoured coastal piedmonts with round-topped mountains occur below the highest local erosional trimline. They represent relict landscape features eroded by extensive ice overriding the whole coastal area before at least 6 Ma (pre-dating the build-up of the Mt. Melbourne volcanic field). Since then, summit surfaces were continuously exposed and well preserved under polar condition with negligible erosion rates on the order of 17 cm/Ma. Complex older drifts rest on deglaciated areas above the younger late-Pleistocene glacial drift and below the previously overridden summits. The combination of stable and radionuclide isotopes documents complex exposure histories with substantial periods of burial combined with minimal erosion. The areas below rounded summits were repeatedly exposed and buried by ice from local and outlet glaciers. The exposure ages of the older drift(s) indicate multiple Pleistocene glacial cycles, which did not significantly modify the pre-existing landscape.     

A case-study of complex gas–water–rock–pollutants interactions in shallow groundwater: Šalek Valley (Slovenia)

The complex geochemical interactions in the groundwater of the industrial area of Šalek Valley (Slovenia) between natural and anthropogenic fluids were studied by means of major (Ca, Mg, Na, K, HCO₃ ⁻, Cl⁻ and SO₄ ²⁻) and trace elements’ (As , Cd, Cu, Pb, Zn, Hg, Se and V) abundances, geochemical classification and statistical analysis of data. Cation abundances indicate mixing between a dolomitic end-member and an evaporitic or geothermal end-member. Anion abundances indicate mixing between bicarbonate waters and either sulphate-enriched waters (suggesting hydrothermalism) or chlorine-rich waters. Principal component analysis (PCA) allowed the extraction of seven factors, which describe, respectively: water–rock interaction mainly on dolomitic rocks; redox conditions of water; Cd–Zn enrichment in chlorine-rich waters (probably from industrial wastes); hydrothermal conditions in waters close to major faults; Pb and Cu pollution; V and K enrichments, indicating their common organic source; the role of partial pressure of CO₂ dissolved in water, which is highest in three wells with bubbling gases. Average underground discharge rates of solutes from the Valley range between 0.09 t/a (V) and 1.8 × 104 t/a (HCO₃ ⁻) and indicate how natural fluids can significantly contribute to the levels of elements in the environment, in addition to the amount of elements released by human activities.     

Photo's from Proceedings of the Third MicroQuasar Workshop; Granada Worshop on Galactic Relativistic Jet Sources – Granada,Spain, 11–13 September 2000

The X-Ray Spectroscopic Explorer (XRASE) has a unique combination of features that will make it possible to address many of NASA's scientific goals. These include how galaxy clusters form, the physics and chemistry of the ISM, the heating of stellar coronae, the amount and content of intergalactic baryonic matter, the mass of black holes and the formation of disks and jets in AGN and galactic binaries. XRASE has a thin foil, multilayered telescope with a large collecting area up to 10 keV, especially in the Fe K region (1100 cm²). Its microcalorimeter array combines high energy resolution (7 eV at 6 keV) and efficiency with a field-of-view of 26 arcmin² . A deep orbit allows for long, continuous observations. Monitoring instruments in the optical (WOM-X), UV (TAUVEX) and hard X-RAY (GRAM) bands will offer exceptional opportunities to make simultaneous multi-wavelength observations.     

The effects of source rocks and chemical weathering on the petrogenesis of siliciclastic sand from the Neto River (Calabria, Italy): implications for provenance studies

Plutonic and gneissic rocks of the Sila Massif in the uppermost portion of the Neto drainage basin (Calabria, Southern Italy) weather and erode under a humid Mediterranean climate. During the development of weathering profiles, a combination of chemical weathering and granular disintegration processes occurred. Chemical weathering involves a loss of both plagioclase (mainly during grus generation) and K-feldspar (mainly during soil formation). This loss is attributed to transformation of plagioclase to clay minerals and to leaching and dissolution of K-feldspar. Sand composition is quartzofeldspathic and nearly homogeneous along the main channel of the Neto River, even where the river cuts across a blanket of sedimentary cover. Thus, fluvial transport does not alter sand composition within the Neto drainage basin. Petrographic indices are effective in (1) discriminating between contributions from similar (granite and gneiss) source rocks (Qm/F); (2) relating the provenance of plutoniclastic and gneissiclastic sand found in the headwaters to grus horizons (Qm/F; Q/Rg); and (3) distinguishing between upstream first-cycle and downstream multicycle sand (Q/Rg). This last distinction is further emphasized by considering both aphanitic and phaneritic varieties of rock fragments (RgRmRs diagram). Chemical weathering is the main sand producer within the regolithic environment in northern Calabria. In addition, rapid erosion resulting from steep slopes removes weathered products, and rapid and short transport leads to minimal sediment maturation. In general, the F/Q index is climate and relief dependent; thus, it should be used in conjunction with palaeoclimatic and palaeophysiographic evidence for provenance interpretations of ancient quartzofeldspathic sandstones.     

Soil CO2 degassing on Mt Etna (Sicily) during the period 1989–1993: discrimination between climatic and volcanic influences

Wide variations were measured in the diffuse CO₂ flux through the soils in three selected areas of Mt Etna between August 1989 and March 1993. Degassing of CO₂ from the area of Zafferana Etnea-S. Venerina, on the eastern slope of the volcano, has been determined to be more strongly influenced by meteorological parameters than the other areas. The seasonal component found in the data from this area has been excluded using a filtering algorithm based on the best fitting equation calculated from the correlation between CO₂ flux values and those of air temperature. The filtered data appear to have variations temporally coincident with those from the other areas, thus suggesting a common and probably deep source of gas. The highest fluxes measured in the two most peripheral areas may correlate well with other geophysical and volcanological anomalous signals that preceded the strong eruption of 1991–1993 and that were interpreted as deep pressure increases. Anomalous decreases in CO₂ fluxes accompanied the onset and the evolution of that eruption and have been interpreted as a sign of upward migration of the gas source. The variations of CO₂ flux at the 1989 SE fracture have also given interesting information on the timing of the magmatic intrusion that has then fed the 1991–1993 eruption.     

Scaling characteristics of spatial patterns of soil moisture from distributed modelling

Characterizing the spatial dynamics of soil moisture fields is a key issue in hydrology, offering an avenue to improve our understanding of complex land surface–atmosphere interactions. In this paper, the statistical structure of soil moisture patterns is examined using modelled soil moisture obtained from the North American Land Data Assimilation System (NLDAS) at 0.125° resolution. The study focuses on the vertically averaged soil moisture in the top 10 cm and 100 cm layers. The two variables display a weak dependence for lower values of surface soil moisture, with the strength of the relationship increasing with the water content of the top layer. In both cases, the variance of the soil moisture follows a power law decay as a function of the averaging area. The superficial layer shows a lower degree of spatial organization and higher temporal variability, which is reflected in rapid changes in time of the slope of the scaling functions of the soil moisture variance. Conversely, the soil moisture in the top 100 cm has lower variability in time and larger spatial correlation. The scaling of these patterns was found to be controlled by the changes in the soil water content. Results have implications for the downscaling of soil moisture to prevent model bias.     

Assessing seasonal variations and aquifer vulnerability in coastal aquifers of semi-arid regions using a multi-tracer isotopic approach: the case of Grombalia (Tunisia)

The Grombalia aquifer (NE Tunisia) is an example of an important source of water supply for regional and national development, where the weak controls over abstraction, fertilizer application and waste disposal, coupled with limited knowledge of aquifer dynamics, is causing aquifer over-exploitation and water quality degradation. Assessing the key role of groundwater in water-resources security is therefore of paramount importance to support new actions to preserve water quality and quantity in the long-run. This study presents one of the first investigations targeted at a complete assessment of aquifer dynamics in the Grombalia aquifer. A multi-tracer hydrogeochemical and isotopic (δ²H, δ¹⁸O and ³H) approach was used to study the influence of seasonal variation on piezometric levels, chemical and isotopic compositions, and groundwater recharge. A total of 116 samples were collected from private wells and boreholes during three periods in a 1 year monitoring campaign (February–March 2014, September 2014 and February 2015). Results revealed the overall unsuitability of groundwater for drinking and irrigation purposes (NO₃?>?50 mg/L in 51% of the wells; EC >1,000 μS/cm in 99% of the wells). Isotopic balance coupled to piezometric investigation indicated the contribution of the shallow aquifer to deep groundwater recharge. The study also revealed the weakness of ‘business as usual’ management practices, highlighting possible solutions to tackle water-related challenges in the Grombalia region, where climate change, population growth and intensive agricultural activities have generated a large gap between demand and available water reserves, hence becoming a possible driver for social insecurity.     

A resampling strategy based on bootstrap to reduce the effect of large blunders in GPS absolute positioning

In the absence of obstacles, a GPS device is generally able to provide continuous and accurate estimates of position, while in urban scenarios buildings can generate multipath and echo-only phenomena that severely affect the continuity and the accuracy of the provided estimates. Receiver autonomous integrity monitoring (RAIM) techniques are able to reduce the negative consequences of large blunders in urban scenarios, but require both a good redundancy and a low contamination to be effective. In this paper a resampling strategy based on bootstrap is proposed as an alternative to RAIM, in order to estimate accurately position in case of low redundancy and multiple blunders: starting with the pseudorange measurement model, at each epoch the available measurements are bootstrapped—that is random sampled with replacement—and the generated a posteriori empirical distribution is exploited to derive the final position. Compared to standard bootstrap, in this paper the sampling probabilities are not uniform, but vary according to an indicator of the measurement quality. The proposed method has been compared with two different RAIM techniques on a data set collected in critical conditions, resulting in a clear improvement on all considered figures of merit.     

Regional thermo-rheological field related to granite emplacement in the upper crust: implications for the Larderello area (Tuscany,Italy)

We modelled thermo-rheological perturbations, related to the emplacement of a magmatic body in the upper crust. This approach was considered relevant for the areas characterized by elevated surface heat flow and chiefly for the geothermal fields. The numerical conductive thermal model applied to the Larderello geothermal area in Tuscany, allowed to constrain size, depth and timing of emplacement of the pluton. We inferred that the emplacement of a magmatic body, at a minimum depth of 3 km, having a horizontal extension of 14 km and a maximum thickness of 8 km, can reasonably reproduce the observed regional surface heat flow anomaly of the Larderello area, when 300 (± 100) kyr are elapsed from the magma emplacement. Even assuming an incremental growth, the first magma injection should not be older than 1 ± 0.3 Ma.

Results of the thermal model were used to set up a rheological model and to simulate the drifting of the brittle-ductile transition during the cooling of the pluton. A comparison with the K-horizon profile, a prominent seismic reflector in the Larderello area, was then performed. It was found that the K-horizon approximately corresponds with the pluton roof and with the current location of the brittle-ductile transition.