Electro-chemical mineralization of recalcitrant indole by platinum-coated titanium electrode: multi-response optimization,mechanistic and sludge disposal study

Indole is a highly recalcitrant aromatic heterocyclic organic compound consisting of a five-membered nitrogen-containing pyrrole ring fused to a six-membered benzene ring. This study presents the results of the electro-chemical mineralization of indole in an aqueous solution using platinum-coated titanium (Pt/Ti) electrode. A central composite design was used to investigate the effect of four parameters namely initial pH (pH_o), current density (j), conductivity (k) and treatment time (t) at 5 levels. Multiple responses namely chemical oxygen demand (COD) removal (Y ₁) and specific energy consumption (Y ₂) were simultaneously maximized and minimized, respectively, by optimizing the parameters affecting the mineralization of indole by using the desirability function approach. At the operating conditions of pH 8.6, j = 161 A/m², k = 6.7 mS/cm and t = 150 min, 83.8% COD removal with specific energy consumption of 36.3 kWh/kg of COD removed was observed. Ultra performance liquid chromatography, UV–visible spectroscopy, Fourier transform infrared spectroscopy and cyclic voltammetry of the indole solution were performed at the optimum condition of the treatment so as to report a plausible mechanism of indole degradation. Field emission scanning electron microscopy analysis of electrodes before and after treatment was performed for determining the changes on anode surface during the treatment. Thermal analysis of the solid residue (scum) obtained was also performed for exploring its disposal prospects. Present study shows that electro-chemical oxidation can be used for mineralization of nitrogenous heterocyclic compounds such as indole.     

Hypsometric analysis of the micro-watersheds with different management practices located on Shivalik foothills

In this paper, the hypsometric curves and integrals of four neighboring micro-watersheds draining into Patiala-Ki-Rao stream which is situated in the Shivalik foothills of district SAS Nagar in the Punjab state (India) has been presented to access and compare the erosion regimes under different management practices. Area-elevation ratio method has been used to compute hypsometric curve and integral values for each micro-watershed through ArcGIS 10.3 and Microsoft Excel. The 9-year data of runoff and sediment yield for all these micro-watersheds under different management practices has been analyzed for their effect on land cover and soil quality. Thus, the results of present study are very useful for comparing, planning, implementing, and controlling soil erosion in similar watersheds.     

Geothermal energy potential of Tulsishyam thermal springs of Gujarat,India

Tulsishyam thermal springs are located in the Saurashtra region of Gujarat, India with discharge temperatures varying from 39 to 42 °C. The pH of these thermal springs varies from 7.1 to 7.4, indicating neutral character. Though these thermal springs propagate through the near surface layer of Deccan basalt, detailed geochemical analysis of the thermal waters using Piper diagram suggests that the water is interacting with the granitic basement rock. Silica and cation geothermometry estimates have reservoir temperature in the range of 138 to 207 °C categorizing it into a low to moderate enthalpy geothermal system. Furthermore, the area has high heat flow values of 53–90 mW/m² because of shallow Moho depth. The prevailing conditions suggest that the geothermal energy can potentially be exploited through an enhanced geothermal system (EGS). The study also indicates different mineral phases that may precipitate out of water during exploitation of geothermal energy and it should be taken into account while designing an EGS for the area.     

A Preliminary Evaluation on the Prospects of Hydrocarbon Potential in the Carbonaceous Shales of Spiti and Chikkim Formations,Tethys Himalaya,India

In the present investigation, an attempt has been made to explore the possibility of hydrocarbon prospects in the carbonaceous shale deposits of Spiti and Chikkim formations exposed in the Spiti valley of the Tethys Himalaya. Twenty samples, collected from successive levels of these litho-units, have been subjected to maceral analysis, Rock-Eval Pyrolysis and six samples to Fourier Transform Infra-red Spectroscopy (FTIR) and nuclear magnetic resonance (NMR) analyses. The study reveals the presence of mainly kerogen-III type of organic matter but some of the shale samples have shown a good amount of total organic carbon (TOC) to the tune of 3.19% which is sufficient to produce hydrocarbon. The results indicate the presence of methane occurring as free and fixed hydrocarbon in the shale samples. Few levels are especially rich in hydrocarbon. They have shown encouraging results with potential for generating liquid as well as lighter hydrocarbon. The data is also supported by the FTIR and NMR studies.     

Prediction of fog/visibility over India using NWP Model

Frequent occurrence of fog in different parts of northern India is common during the winter months of December and January. Low visibility conditions due to fog disrupt normal public life. Visibility conditions heavily affect both surface and air transport. A number of flights are either diverted or cancelled every year during the winter season due to low visibility conditions, experienced at different airports of north India. Thus, fog and visibility forecasts over plains of north India become very important during winter months. This study aims to understand the ability of a NWP model (NCMRWF, Unified Model, NCUM) with a diagnostic visibility scheme to forecast visibility over plains of north India. The present study verifies visibility forecasts obtained from NCUM against the INSAT-3D fog images and visibility observations from the METAR reports of different stations in the plains of north India. The study shows that the visibility forecast obtained from NCUM can provide reasonably good indication of the spatial extent of fog in advance of one day. The fog intensity is also predicted fairly well. The study also verifies the simple diagnostic model for fog which is driven by NWP model forecast of surface relative humidity and wind speed. The performance of NWP model forecast of visibility is found comparable to that from simple fog model driven by NWP forecast of relative humidity and wind speed.     

Ecological model analysis of respiratory health risk factors by ambient air pollution in Lucknow,the capital City of Uttar Pradesh,India

Ambient air pollution, particularly in the urban environment of developing countries, has turned out to be a major health risk factor. We explore the compounded impact of age sensitivity, exposure, poverty, co-morbidity, etc., along with composite air pollution in determining morbidity and health burden of people in Lucknow, India. This cross-sectional study is confined to analyse respiratory health status across different socio-economic and geographic locations using n = 140 in-depth questionnaire method. We used mean daily ambient air pollution data of PM₁₀, PM_2.5, SO_2, and NO₂ for the 2008–2018 period. We used the ecological model framework to assess the risk at different hierarchical levels and compounded severity on a spatial scale. We also used Logistic regression model with log odds and odds ratio to analyze the association of risks outcomes with composite air pollution scores calculated using the principal component analysis method. There is a strong association of location-specific respiratory disease prevalence with an overall 32 percent prevalence. The prevalence of ecological model 1 (individual domain) is 4.3 percent, while ecological model 2 (community domain) has the highest prevalence at 32.4 percent. The logistic regression model shows that respiratory disease load is positively associated with age sensitivity (P < .001) and composite pollution level (P < .001). For another model with suffocation as the outcome variable, composite pollution level (P < .001) and exposure (P < .001) are positively associated. Optimum interventions are required at Ecological models 1, 2, and 3 levels for better respiratory health outcomes.

     

Applicability of Critical State Concept in Determination of Triaxial Strength of Non-Persistent Jointed Rock

Geotechnical and Geological Engineering - Rocks encountered in civil and mining engineering structures are generally intersected by discontinuities. The triaxial strength behaviour of a jointed...     

Documentation of shock features in impactites from the Dhala impact structure,India

The fundamental approach for the confirmation of any terrestrial meteorite impact structure is the identification of diagnostic shock metamorphic features, together with the physical and chemical characterization of impactites and target lithologies. However, for many of the approximately 200 confirmed impact structures known on Earth to date, multiple scale‐independent tell‐tale impact signatures have not been recorded. Especially some of the pre‐Paleozoic impact structures reported so far have yielded limited shock diagnostic evidence. The rocks of the Dhala structure in India, a deeply eroded Paleoproterozoic impact structure, exhibit a range of diagnostic shock features, and there is even evidence for traces of the impactor. This study provides a detailed look at shocked samples from the Dhala structure, and the shock metamorphic evidence recorded within them. It also includes a first report of shatter cones that form in the shock pressure range from ~2 to 30 GPa, data on feather features (FFs), crystallographic indexing of planar deformation features, first‐ever electron backscatter diffraction data for ballen quartz, and further analysis of shocked zircon. The discovery of FFs in quartz from a sample of the MCB‐10 drill core (497.50 m depth) provides a comparatively lower estimate of shock pressure (~7–10 GPa), whereas melting of a basement granitoid infers at least 50–60 GPa shock pressure. Thus, the Dhala impactites register a strongly heterogeneous shock pressure distribution between <2 and >60 GPa. The present comprehensive review of impact effects should lay to rest the nonimpact genesis of the Dhala structure proposed by some earlier workers from India.     

Repercussions of solar high energy protons on ozone layer during super storms

We are very aware of the importance of the ozone layer, without which life on the Earth would not have evolved in the way it has. Solar storms carry energetic protons into the Earth's upper atmosphere,where they boost production of nitrogen oxides which are known as ozone killers and which ultimately increase ultraviolet(UV) radiations. In the present study, we estimate the effects of solar energetic protons during super storms(Dst index -300 nT) over the total ozone column for the last 32 yr. We select a total of seven super storm events that occurred during solar cycles 22–24(for the last 32 yr) having Dst index -300 nT. To that end, we apply superposed epoch analysis(SEA) to verify the impact of storm events on the quantitative variation of total ozone column and on UV radiations during super storm events.After completing the empirical analysis, we conclude that the ozone column gets depleted significantly(22±6.8%) as proton density increases during super storm events and this decrement in the ozone level is further responsible for a substantial increase(26±11.2%) in peak UV radiation intensities.