Experiments on the kinetics of partial melting of a leucogranite at 200 MPa H<Subscript>2</Subscript>O and 690–800°C: compositional variability of melts during the onset of H<Subscript>2</Subscript>O-saturated crustal anatexis

We have experimentally investigated the kinetics of melting of an aplitic leucogranite (quartz+sodic plagioclase of ≈Ab₉₀+K-feldspar+traces of biotite) at 690, 740, and 800°C, all at 200 MPa H₂O. Leucogranite cylinders, 3.5 mm in diameter and 7 mm in length, were run in the presence of excess H₂O using cold-seal pressure vessels for 11–2,925 h. At 690 and 740°C and any experimental time, and 800°C and short run times, silicate glass (melt at run conditions) occurs as interconnected films along most of the mineral boundaries and in fractures, with the predominant volume occurring along quartz/feldspars boundaries and quartz/plagioclase/K-feldspar triple junctions. Glass film thickness is roughly constant throughout a given experimental charge and increases with experimental temperature and run duration. The results indicate that H₂O-saturated partial melting of a quartzo-feldspathic protolith will produce an interconnected melt phase even at very low degrees (<5 vol%) of partial melting. Crystal grain boundaries are therefore completely occluded with melt films even at the lowest degrees of partial melting, resulting in a change in the mechanism of mass transport through the rock from advection of aqueous vapor to diffusion through silicate melt. At 690 and 740°C the compositions of glasses are homogeneous and (at both temperatures) close to, but not on, the H₂O-saturated 200 MPa haplogranite eutectic; glass compositions do not change with run duration. At 800°C glasses are heterogeneous and plot away from the minimum, although their molar ratios ASI (=mol Al₂O₃/CaO+Na₂O+K₂O) and Al/Na are constant throughout the entire charge at any experimental time. Glass compositions within individual 800°C experiments form linear trends in (wt%) normative quartz–albite–orthoclase space. The linear trends are oriented perpendicular to the 200 MPa H₂O haplogranite cotectic line, reflecting nearly constant albite/orthoclase ratio versus variable quartz/feldspar ratio, and have endpoints between the 800°C isotherms on the quartz and feldspar liquidus surfaces. With increasing experimental duration the trends migrate from the potassic side of the minimum toward the bulk rock composition located on the sodic side, due to more rapid (and complete) dissolution of K-feldspar relative to plagioclase. The results indicate that partial melting at or slightly above the solidus (690–740°C) is interface reaction-controlled, and produces disequilibrium melts of near-minimum composition that persist metastably for up to at least 3 months. Relict feldspars show no change in composition or texture, and equilibration between melt and feldspars might take from a few to tens of millions of years. Partial melting at temperatures well above the solidus (800°C) produces heterogeneous, disequilibrium liquids whose compositions are determined by the diffusive transport properties of the melt and local equilibrium with neighboring mineral phases. Feldspars recrystallize and change composition rapidly. Partial melting and equilibration between liquids and feldspars might take from a few to tens of years (H₂O-saturated conditions) at these temperatures well above the solidus.     

Geochemical and O-isotope constraints on the evolution of lithospheric mantle in the Ross Sea rift area (Antarctica)

Peridotite xenoliths found in Cenozoic alkali basalts of northern Victoria Land, Antarctica, vary from fertile spinel-lherzolite to harzburgite. They often contain glass-bearing pockets formed after primary pyroxenes and spinel. Few samples are composite and consist of depleted spinel lherzolite crosscut by amphibole veins and/or lherzolite in contact with poikilitic wehrlite. Peridotite xenoliths are characterized by negative Al₂O₃–Mg# and TiO₂–Mg# covariations of clino- and orthopyroxenes, low to intermediate HREE concentrations in clinopyroxene, negative Cr–Al trend in spinel, suggesting variable degrees of partial melting. Metasomatic overprint is evidenced by trace element enrichment in clinopyroxene and sporadic increase of Ti–Fe_tot. Preferential Nb, Zr, Sr enrichments in clinopyroxene associated with high Ti–Fe_tot contents constrain the metasomatic agent to be an alkaline basic melt. In composite xenoliths, clinopyroxene REE contents increase next to the veins suggesting metasomatic diffusion of incompatible element. Oxygen isotope data indicate disequilibrium conditions among clinopyroxene, olivine and orthopyroxene. The highest δ¹⁸O values are observed in minerals of the amphibole-bearing xenolith. The δ¹⁸O_cpx correlations with clinopyroxene modal abundance and geochemical parameters (e.g. Mg# and Cr#) suggest a possible influence of partial melting on oxygen isotope composition. Thermobarometric estimates define a geotherm of 80°C/GPa for the refractory lithosphere of NVL, in a pressure range between 1 and 2.5 GPa. Clinopyroxene microlites of melt pockets provide P–T data close to the anhydrous peridotite solidus and confirm that they originated from heating and decompression during transport in the host magma. All these geothermometric data constrain the mantle potential temperature to values of 1250–1350°C, consistent with the occurrence of mantle decompressional melting in a transtensive tectonic regime for the Ross Sea region.     

Evaluation of an ensemble of Arctic regional climate models: spatiotemporal fields during the SHEBA year

Simulations of eight different regional climate models (RCMs) have been performed for the period September 1997–September 1998, which coincides with the Surface Heat Budget of the Arctic Ocean (SHEBA) project period. Each of the models employed approximately the same domain covering the western Arctic, the same horizontal resolution of 50 km, and the same boundary forcing. The models differ in their vertical resolution as well as in the treatments of dynamics and physical parameterizations. Both the common features and differences of the simulated spatiotemporal patterns of geopotential, temperature, cloud cover, and long-/shortwave downward radiation between the individual model simulations are investigated. With this work, we quantify the scatter among the models and therefore the magnitude of disagreement and unreliability of current Arctic RCM simulations. Even with the relatively constrained experimental design we notice a considerable scatter among the different RCMs. We found the largest across-model scatter in the 2 m temperature over land, in the surface radiation fluxes, and in the cloud cover which implies a reduced confidence level for these variables. An erratum to this article can be found at     

利用遥感技术建立墨西哥热带地上生物量模型(英文)

Spatially-explicit estimation of aboveground biomass(AGB) plays an important role to generate action policies focused in climate change mitigation,since carbon(C) retained in the biomass is vital for regulating Earth’s temperature.This work estimates AGB using both chlorophyll(red,near infrared) and moisture(middle infrared) based normalized vegetation indices constructed with MCD43A4 MODerate-resolution Imaging Spectroradiometer(MODIS) and MOD44B vegetation continuous fields(VCF) data.The study area is located in San Luis Potosí,Mexico,a region that comprises a part of the upper limit of the intertropical zone.AGB estimations were made using both individual tree data from the National Forest Inventory of Mexico and allometric equations reported in scientific literature.Linear and nonlinear(expo-nential) models were fitted to find their predictive potential when using satellite spectral data as explanatory variables.Highly-significant correlations(p = 0.01) were found between all the explaining variables tested.NDVI62,linked to chlorophyll content and moisture stress,showed the highest correlation.The best model(nonlinear) showed an index of fit(Pseudo-r2) equal to 0.77 and a root mean square error equal to 26.00 Mg/ha using NDVI62 and VCF as explanatory variables.Validation correlation coefficients were similar for both models:lin-ear(r = 0.87**) and nonlinear(r = 0.86**).     

The influence of upper-crust lithology on topographic development in the central Coast Ranges of California

A fundamental geological tenet is that as landscapes evolve over graded to geologic time, geologic structures control patterns of topographic distribution in mountainous areas such that terrain underlain by competent rock will be higher than terrain underlain by incompetent rock. This paper shows that in active orogens where markedly weak and markedly strong rocks are juxtaposed along contacts that parallel regional structures, relatively high topography can form where strain is localized in the weak rock. Such a relationship is illustrated by the topography of the central Coast Ranges between the Pacific coastline and the San Andreas fault zone (SAFZ), and along the length of the Gabilan Mesa (the “Gabilan Mesa segment” of the central Coast Ranges). Within the Gabilan Mesa segment, the granitic upper crust of the Salinian terrane is in contact with the accretionary-prism mélange upper crust of the Nacimiento terrane along the inactive Nacimiento fault zone. A prominent topographic lineament is present along most of this lithologic boundary, approximately 50 to 65 km southwest of the SAFZ, with the higher topography formed in the mélange on the southwest side of the Nacimiento fault.This paper investigates factors influencing the pattern of topographic development in the Gabilan Mesa segment of the central Coast Ranges by correlating shortening magnitude with the upper-crust compositions of the Salinian and Nacimiento terranes. The fluvial geomorphology of two valleys in the Gabilan Mesa, which is within the Salinian terrane, and alluvial geochronology based on optically-stimulated luminescence (OSL) age estimates, reveal that the magnitude of shortening accommodated by down-to-the-southwest tilting of the mesa since 400 ka is less than 1 to 2 m. Our results, combined with those of previous studies, indicate that at least 63% to 78% of late-Cenozoic, northeast-southwest directed, upper-crustal shortening across the Gabilan Mesa segment has been accommodated within the Nacimiento terrane. This is significant because perpendicular to orogenic strike the Nacimiento terrane constitutes less than ¼ of the distance between the coast and the SAFZ, and the other ¾ (or greater) of the distance between the coast and the SAFZ is underlain by the granitic upper crust of the Salinian terrane. We propose that strain and mountain building are localized within the Nacimiento terrane because it consists predominantly of the relatively weak Franciscan Complex mélange, and because the upper crust of the Salinian terrane is composed of relatively strong granitic rocks. Our hypothesis is supported by the distribution of post-seismic surface uplift associated with the 2003, 6.5 M_W San Simeon earthquake, which mimics the topography of the southwestern part of the Gabilan Mesa segment of the central Coast Ranges.     

Climatic variability in the Late Copper Age: stable isotope fluctuation of prehistoric Unio pictorum (Unionidae) shells from Lake Balaton (Hungary)

Geochemical records of bivalve shells have been increasingly studied in the last decade to obtain information on climate conditions. In this paper we present stable isotope compositions of living and prehistoric shells of freshwater mussels (Unionidae) and their relationships with climate conditions in a shallow lake environment of Lake Balaton, West-Central Hungary. Physical conditions and stable oxygen isotope compositions of lake water samples were monitored where living bivalves were collected. Comparisons between seasonal variations in ambient temperature, water composition and within-shell isotopic variations indicate that the shells of Unio pictorum do reflect local changes at high resolution and thus can be used to study past conditions. Additionally, shells covering the last two decades were gathered at several locations along the lake in order to determine spatial and temporal variations in the shells’ isotopic compositions as a function of weather conditions. As an application, prehistoric shells collected in archaeological excavations were analysed in order to study past environmental variations. Climate variations during the Late Copper Age (5460–4870 cal. yr BP) have been assumed on the basis of geomorphological and archaeozoological observations at the site Balatonkeresztúr-Réti-dűlő (south of Lake Balaton), that suggested increasing humidity as a cause of changes in settlement location and domestic livestock husbandry. Stable carbon and oxygen isotope compositions of prehistoric bivalve shells were analyzed from excavations representing five archaeological subphases (Boleráz subphase, 5460–5310 cal. yr BP; two transitional subphases around 5310 cal. yr BP; Early Classic subphase, 5310–5060 cal. yr BP; Late Classic subphase, 5040–4870 cal. yr BP). The analyses revealed significant negative C and O isotope shifts in the transitional subphases relative to the earlier and later subphases. The isotopic variations indicate that the local climate became relatively wet and possibly cold around 5310 cal. yr BP, then it returned to drier (and likely warmer) conditions during the Classic subphases. This interpretation is in agreement with previous studies on climate changes related to the “5.3 ky event” in the European continental area and the North Atlantic Region, indicating an Atlantic influence in the Carpathian Basin.     

Radiometric dating of recent sediments: beyond the boundary conditions

Most mathematical models for radiometric dating of recent sediments are particular solutions of a unique physical problem: the advective?Cdiffusive transport of a particle-bound radiotracer within a sediment profile that undergoes accretion. Regardless of the particular assumptions about fluxes, sedimentation rates and the diffusion term, all models assume ideal deposition as a boundary condition at the sediment water interface, i.e. new radioactive input will be deposited above the previously existing material. In sediments with very high porosities, this assumption may be unrealistic, because a fraction of the incoming flux may penetrate rapidly through the connected pore spaces. This process will be referred to as non-ideal deposition. This paper reviews evidence from literature data, discusses the basic processes involved, and establishes the mathematical basis to incorporate non-ideal deposition into one-phase radiometric dating models, as depth-distributed local sources. Through analytical and numerical solutions, this work demonstrates that such penetration patterns can explain excess ²¹⁰Pb subsurface maxima, often observed in sediment cores, as well as penetration of ¹³⁷Cs to depths greater than expected from sedimentation rates and diffusion. These ideas are illustrated using examples from the literature in which sediment porosities were >90?%. Implications for radiometric dating include: (1) spurious accelerations in sedimentation rate inferred when applying the constant rate of supply model, and (2) erroneous chronologies, developed when using the maximum depth at which ¹³⁷Cs can be measured as a chronostratigraphic marker.     

Environmental changes in northern New Zealand since the Middle Holocene inferred from stable isotope records (δ15N, δ13C) of Lake Pupuke

Maar lakes in the Auckland Volcanic Field are important high-resolution archives of Holocene environmental change in the Southern Hemisphere mid-latitudes. Stable carbon and nitrogen isotope analyses were applied on bulk organic matter and the green alga Botryococcus from a sediment core from Lake Pupuke (Auckland, North Island, New Zealand) spanning the period since 7,165?cal.?year BP. The origin of organic matter was established using total-organic?Ccarbon-to-nitrogen ratios (TOC/TN) as well as organic carbon (??¹³C_OM) and nitrogen (??¹⁵N) isotope composition of potential modern sources. This approach demonstrated that the contribution of allochthonous organic matter to the lake sediment was negligible for most of the record. The sedimentary TOC/TN ratios that are higher than Redfield ratio (i.e. >7) are attributed to N-limiting conditions throughout the record. Variations of nitrogen and carbon isotopes during the last 7,165?years are interpreted as changes in the dominant processes in the lake. While epilimnetic primary productivity controlled isotope composition before 6,600?cal.?year BP, microbial processes, especially denitrification and methane oxidation, caused overall shifts of the ??¹⁵N and ??¹³C values since the Mid-Holocene. Comparisons with climate reconstructions from the Northern Island suggest that changes in the wind-induced lake overturn and a shift to more pronounced seasonality were the most likely causes for lake-internal changes since 6,600?cal.?year BP.     

The new national climate change documents of Mexico: what do the regional climate change scenarios represent?

This paper presents a review of the methodology applied for generating the regional climate change scenarios utilized in important National Documents of Mexico, such as the Fourth National Communication to the United Nations Framework Convention on Climate Change, the Fourth National Report to the Convention on Biological Diversity and The Economics of Climate Change in Mexico. It is shown that these regional climate change scenarios, which are one of the main inputs to support the assessments presented in these documents, are an example of the erroneous use of statistical downscaling techniques. The arguments presented here imply that the work based on such scenarios should be revised and therefore, these documents are inadequate for supporting national decision- making.