Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.     

CQK-50型车载化钻机的研制

在分析研究小型地质车载钻机的形式、功能与特点的基础上，提出了钻机车载化的新思路。根据地质调查工作现状，结合国内现有小型地质取样钻机，研制了CQK-50型全液压多功能车载取样钻机，并在野外物化探遥感异常验证钻探中取得了良好效果。     

粉煤灰垫层与夯扩灌注桩联合处理高层建筑地基

利用夯扩灌注桩对桩端持力层的加密作用，可解决水下填筑问题，利用粉煤灰的可压密性和夯扩灌注桩承载力高的特点，可大幅提高复合地基承载力，减少工程投资。以河南洛阳某高层建筑为例，介绍了粉煤灰垫层和夯扩灌注桩组成的刚性桩复合地基在高层建筑地基中的应用。     

辽东栎萌生个体的地上生物量及其构件分配与生长参数的关系

选择岷江上游海拔2100-2300m地段的辽东栎萌生株个体69株，测定了每株生长参数（年龄、高度、基径、冠幅）、各器官生物量及地上总生物量，分析了各器官生物量及构件分配与生长参数的相互关系。结果表明，辽东栎萌生株构件分配的大小排序为：茎干〉枝〉皮〉叶：随径级增大。茎干、大枝生物量所占总生物量比例上升，其他器官所占比例减小。辽东栎年龄与高度呈S曲线关系，其他均表现出很好的幂指数函数关系；各构件器官生物量与生长参数大多也呈幂指数函数W=aD^h（D为基径）关系。基径为估测辽东栎萌生株地上各器官生物量及总生物量的最佳因子。     

楼观台森林公园深层生态旅游开发的模式探讨

提出了深层生态旅游开发的概念,构建了一个“两翼对接”模式。在广泛野外调查的基础上,依据上述理念和开发模型,针对楼观台国家森林公园的景观资源特征,对其深层生态旅游开发进行了系统设计。具体而言,重点突出了自然山水、生物景观和道教文化三方面设计,揭示了三大类60个景物的生态文化主题,设计了相应的开发展示模式和游客生态体验方式。其目的在于,提高森林公园生态文化的展示水平和加深旅游者的生态体验。     

阻燃级氢氧化镁制备过程中表面有机化改性

文章通过论述阻燃剂型氢氧化镁制备过程中的表面有机化改性,对改性剂、作用机理和改性工艺等进行了探讨,说明了对阻燃剂型氢氧化镁表面有机化改性的重要性,及在氢氧化镁制备过程中综合分析、系统研究的必要性。     

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.     

中国大气本底观测发展概述

中国早期的大气本底观测网建设起步于上世纪80年代初，并于10a后基本建成。目前，中国气象局、中国科学院在原有观测站的基础上各自建设和发展着自己下属的大气本底观测网络。全球大气观测网给出了一整套开展大气本底观测的技术标准，各国均予以严格遵循。20多年来，中国大气本底观测工作在基础数据积累以及观测标准制定等方面取得了较大进展，与此相关的科学研究也取得了长足进步。最后对中国大气本底观测发展过程中存在的一些问题进行了探讨。     

ArcMap在中学地理教学中的应用

本文就地理信息系统(GIS)工具软件之一———ArcMap在中学地理教学中应用分析的基础上,探讨了GIS工具软件在中学地理教学中的作用,表明GIS技术在地理教学中有广泛的应用前景。同时对GIS的发展提出建议和希望。