Geological settings and metallogenesis of high-grade iron deposits in China

The predominant types of high-grade iron deposits in China include skarn, sedimentary metamorphic(banded ironformation, BIF-type), continental/submarine volcanic-hosted and magmatic Fe-Ti-Voxide deposits. Based on a comprehensive review of current studies on these deposits, this paper suggests that the oxygen concentration in atmosphere played an important role for the formation of BIFs, whereas the tectonic setting and deep magmatic differentiation processes are more important for the other types. Notably, both high temperature and high pressure experiments and melt inclusion studies indicate that during the differentiation, high temperature magmas could develop iron-rich magma via liquid immiscibility but not pure oxide melt("iron ore magma"). Fe-P melt could be generated directly by liquid immiscibility under hydrous and oxidized condition. The formation of high-grade iron deposits is mostly associated with the processes related to multiple stages of superimposition, e.g., desiliconization and iron enrichment, removal of impurity, and remobilization and re-precipitation of iron. According to the temporal evolution, the high-grade iron deposit could be divided into multi-episode superimposition type(temporally discontinuous mineralization) and multi-stage superimposition type(temporally continuous mineralization). The former is represented by the sedimentary metamorphic iron deposit, and the latter includes those related to magmatic-hydrothermal fluids(e.g., skarn,volcanic-hosted and magmatic types).     

滇西凤庆地区箐头山花岗岩的特征 ——古特提斯洋碰撞汇聚向伸展转换的证据

笔者等在野外调查的基础上,对出露于滇西临沧岩浆弧北部凤庆箐头山地区原1:25万凤庆县幅划分的二叠纪糜棱岩化黑云二长花岗岩进行了系统的年代学、岩石学和地球化学研究.该花岗岩体中,锆石具典型的振荡环带,Th/U值均大于0.2,为岩浆成因,其LA-ICP-MS U-Pb年龄为213±5 Ma,应当为岩浆结晶年龄,表明该岩体形...     

地震相和测井相联合预测火山岩相分布特征研究

以火山岩的基本地质特征、测井特征与测井相及其地震相特征与地震相分类为基础,依据测井相所建立的火山岩相模式,时地震相进行标定,形成由火山岩相、测井相和地震相组成的"三相"技术.该技术建立起"三相"之间的对应关系,以揭示火山岩相空间展布规律及变化特征.将"三相"技术应用于某盆地北部地区的营城组火山岩相研究.把营城组一段的地震相转换成火山岩相,得到火山岩相的平面分布,有效地预测出某盆地北部地区营城组一段火山岩的空间展布规律和火山岩储层有利相带.钻井证实:火山岩相之通道相岩石的物性最好,侵出相和爆发相次之,火山沉积相最差;火山岩相以火山颈岩物性最好,溢流相顶部次之.     

Eclogite and carpholite-bearing metasedimentary rocks in the North Qilian suture zone, NW China: implications for Early Palaeozoic cold oceanic subduction and water transport into mantle

Low‐temperature eclogite and eclogite facies metapelite together with serpentinite and marble occur as blocks within foliated blueschist that was originated from greywacke matrix; they formed a high‐pressure low‐temperature (HPLT) subduction complex (mélange) in the North Qilian oceanic‐type suture zone, NW China. Phengite–eclogite (type I) and epidote–eclogite (type II) were recognized on the basis of mineral assemblage. Relic lawsonite and lawsonite pseudomorphs occur as inclusions in garnet from both types of eclogite. Garnet–omphacite–phengite geothermobarometry yields metamorphic conditions of 460–510 °C and 2.20–2.60 GPa for weakly deformed eclogite, and 475–500 °C and 1.75–1.95 GPa for strongly foliated eclogite. Eclogite facies metasediments include garnet–omphacite–phengite–glaucophane schist and various chloritoid‐bearing schists. Mg‐carpholite was identified in some high‐Mg chloritoid schists. P–T estimates yield 2.60–2.15 GPa and 495–540 °C for Grt–Omp–Phn–Gln schist, and 2.45–2.50 GPa and 525–530 °C for the Mg‐carpholite schist. Mineral assemblages and P–T estimates, together with isotopic ages, suggest that the oceanic lithosphere as well as pelagic to semi‐pelagic sediments have been subducted to the mantle depths (≥75 km) before 460 Ma. Blueschist facies retrogression occurred at c. 454–446 Ma and led to eclogite deformation and dehydration of lawsonite during exhumation. The peak P–Tconditions for eclogite and metapelite in the North Qilian suture zone demonstrate the existence of cold subduction‐zone gradients (6–7 °C km^?1), and this cold subduction brought a large amount of H₂O to the deep mantle in the Early Palaeozoic times.     

黔西南水银洞金矿床流体包裹体研究

水银洞金矿床是黔西南典型的特大型卡林型金矿床之一。但其成矿流体来源尚有争议。通过对水银洞金矿床脉石英和方解石中流体包裹体的温度与压力、盐度与密度、包裹体成分和包裹体H和O同位素等方面的研究,指出水银洞卡林型金矿床成矿流体属中低温(96.7~220℃)、低盐度(NaCl)0.635%~9.861%,平均值为4.282%±2.260%、中等密度(0.725~0.977 g/cm3,平均值为0.910±0.061 g/cm3);脉石英阶段流体水化学类型属Cl--Na+型或SO42--Cl-Na+型,方解石阶段属SO42--Cl--Ca2+型。成矿流体压力可能为高-超高压(160±40 MPa);成矿流体主要是大气降水形成的地下热水,可能有部分岩浆热液的掺入。     

陕西汉中梁山二叠系乐平统底部吴家坪组王坡页岩新认识

陕西汉中梁山瓜德鲁普统—乐平统界线(GLB)附近的吴家坪组底部王坡页岩段长期以来被认为是古风化壳沉积,代表了茅口期后暴露于地表风化剥蚀的产物。最近对该地层进行了重新研究,采集了系列岩石和化石样品,进行了X射线衍射、古生物学、岩相学和岩石学分析。X射线衍射分析表明该粘土层主要矿物成分为蒙脱石71%,片沸石23%,石英6%,暗示其物质来源于火山玻璃。岩相学分析显示岩石主要由蚀变矿物组成,具有蚀变残留玻屑凝灰质结构,其中蒙脱石、片沸石保留了原岩中的玻屑的塑性形态。粘土层中大量腕足动物化石暗示其为海相环境。研究结果表明王坡页岩是典型的斑脱岩,并非风化壳和长期剥蚀的产物,而是峨眉山大火成岩省火山喷发时火山灰在海相环境下沉积、蚀变的产物。火山灰在正常浅海沉积时对海洋生态系统造成严重破坏,导致了包括腕足动物在内的海洋生物的生存危机。     

黑河流域典型景观植被带陆面过程同步观测研究

为了解内陆河流域不同尺度内与水循环及生态过程有关的水分、热量分布规律,在黑河流域上中下游选取3个典型植被景观带建立观测场,并布设环境观测系统(ENVIS)进行环境要素的同步观测.结果表明,山区森林草地灌丛复合生态区陆面是冷性湿润的下垫面,中游绿洲荒漠接触带是干性、较湿润的下垫面,下游荒漠河岸林景观带是干热性的下垫面.     

基于化学热力学的饱和指数模型求解方法的改进

饱和指数SI是反映水环境中矿物溶解/沉淀状态的重要参数,而水溶液中络合物的存在对SI值有很大的影响,因此正确计算络合物的含量,可提高水-岩作用SI模型的计算精度。依据化学热力学的基本理论,作者扩展了活度系数计算方程、优化了阀值的选取、并改进了输出结果。结合某工程实例,与传统算法做了比较,证明该模型的算法具有更好的稳定性和计算精度,结果亦与实际情况更相符。     

基于航空客流的中国城市层级结构分析

基于1995、2000和2003三个年份的航空客运统计数据,分析中国城际航空客流的结构,并以优势流(dominant flow)方法为主,辅以距离平方和聚类法,分析中国主要城市在国内客运航空网络中的层级及其变化。研究表明,通过航空客运方式产生的空间联系主要集中于东部地区,中部地区在航空网络的重要性方面落后于西部,北京、上海、广-深3个顶点组成全国航空网络的主干;从主导航空客流角度观察,自1995至2003年,一个高度集中的城市层级在3个全国性中心的控制下形成和发展,航空客运网络层级体系中的顶层结构业已清晰,而以下各层次的结构尚处于分化发展之中。